N'-(furan-2-ylmethyl)-N-phenylbenzenecarboximidamide | 1555666-02-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'-(furan-2-ylmethyl)-N-phenylbenzenecarboximidamide
• CAS: 1555666-02-8；329904-35-0
• 化学式: C₁₈H₁₆N₂O
• 分子量: 276.338
• InChiKey: CVVDBZNYLIDZDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  37.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis(dimethylamido)titanium(IV) 、 N'-(furan-2-ylmethyl)-N-phenylbenzenecarboximidamide 以 甲苯 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Titanium Bis(amidinates) Bearing Electron Donating Pendant Arms as Catalysts for Stereospecific Polymerization of Propylene

  摘要：

  A series of titanium bis(amidinate) complexes containing pendant arms as one of the amidinate N substituents have been prepared and studied in the polymerization of propylene after their activation with MAO and other cocatalysts. The type of pendant arm greatly influences the reactivity and stereospecificity of the resulting polymers. The effect of the cocatalyst nature, its amount, and the time of the reaction have a dramatic effect on the reactivity of a titanium bis(amidinate) bis(dimethylamido) precatalyst containing a furyl group at the pendant arm.

  DOI：

  10.1021/om401165g
• 作为产物：
  描述：

  苯甲酰氯 在 盐酸 、 氯化亚砜 作用下， 以 二氯甲烷 为溶剂， 生成 N'-(furan-2-ylmethyl)-N-phenylbenzenecarboximidamide
  参考文献：
  名称：

  Titanium Bis(amidinates) Bearing Electron Donating Pendant Arms as Catalysts for Stereospecific Polymerization of Propylene

  摘要：

  A series of titanium bis(amidinate) complexes containing pendant arms as one of the amidinate N substituents have been prepared and studied in the polymerization of propylene after their activation with MAO and other cocatalysts. The type of pendant arm greatly influences the reactivity and stereospecificity of the resulting polymers. The effect of the cocatalyst nature, its amount, and the time of the reaction have a dramatic effect on the reactivity of a titanium bis(amidinate) bis(dimethylamido) precatalyst containing a furyl group at the pendant arm.

  DOI：

  10.1021/om401165g

文献信息

• Titanium Bis(amidinates) Bearing Electron Donating Pendant Arms as Catalysts for Stereospecific Polymerization of Propylene
  作者：Tatyana Elkin、Mark Botoshansky、Robert M. Waymouth、Moris S. Eisen

  DOI：10.1021/om401165g

  日期：2014.2.24

  A series of titanium bis(amidinate) complexes containing pendant arms as one of the amidinate N substituents have been prepared and studied in the polymerization of propylene after their activation with MAO and other cocatalysts. The type of pendant arm greatly influences the reactivity and stereospecificity of the resulting polymers. The effect of the cocatalyst nature, its amount, and the time of the reaction have a dramatic effect on the reactivity of a titanium bis(amidinate) bis(dimethylamido) precatalyst containing a furyl group at the pendant arm.