1,4-bis[2,2-bis(4-i-propoxyphenyl)vinyl]benzene | 1244044-77-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,4-bis[2,2-bis(4-i-propoxyphenyl)vinyl]benzene
• 英文别名: 1,4-Bis[2,2-bis(4-propan-2-yloxyphenyl)ethenyl]benzene；1,4-bis[2,2-bis(4-propan-2-yloxyphenyl)ethenyl]benzene
• CAS: 1244044-77-6
• 化学式: C₄₆H₅₀O₄
• 分子量: 666.901
• InChiKey: GWNXBVMTCNSVMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  50
• 可旋转键数：
  14
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-溴-4-异丙氧基苯 、 1,4-苯二乙酸二乙酯 在 叔丁基锂 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 以80%的产率得到1,4-bis[2,2-bis(4-i-propoxyphenyl)vinyl]benzene
  参考文献：
  名称：

  Synthesis of 1,4-Bis[2,2-bis(4-alkoxyphenyl)vinyl]benzenes and Side Chain Modulation of Their Solid-State Emission

  摘要：

  A series of 1,4-bis[2,2-bis(4-alkoxyphenyl)vinyl]benzene molecules with aggregation-induced emission (AIE) activity were synthesized. The conformations and packing arrangements of these molecules in the solid state can be adjusted by changing the side chains, which subsequently modulates their solid-state emission. The fluorescence quantum yield of 1e with the n-C(6)H(13) side chain in the solid state could reach up to 60.3% in the solid state.

  DOI：

  10.1021/ol101847w

文献信息

• Synthesis of 1,4-Bis[2,2-bis(4-alkoxyphenyl)vinyl]benzenes and Side Chain Modulation of Their Solid-State Emission
  作者：Peng An、Zi-Fa Shi、Wei Dou、Xiao-Ping Cao、Hao-Li Zhang

  DOI：10.1021/ol101847w

  日期：2010.10.1

  A series of 1,4-bis[2,2-bis(4-alkoxyphenyl)vinyl]benzene molecules with aggregation-induced emission (AIE) activity were synthesized. The conformations and packing arrangements of these molecules in the solid state can be adjusted by changing the side chains, which subsequently modulates their solid-state emission. The fluorescence quantum yield of 1e with the n-C(6)H(13) side chain in the solid state could reach up to 60.3% in the solid state.