tris-(4-tolylbiphenyl)amine | 138689-62-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris-(4-tolylbiphenyl)amine
• 英文别名: tris-(m-tolylbiphenyl)amine；4-(4-methylphenyl)-N,N-bis[4-(4-methylphenyl)phenyl]aniline
• CAS: 138689-62-0
• 化学式: C₃₉H₃₃N
• 分子量: 515.698
• InChiKey: JRWKKBDCXGZCBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三(4-碘苯)胺 、 三对甲苯基铋 在 potassium acetate 、 palladium diacetate 、 二环己胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以75%的产率得到tris-(4-tolylbiphenyl)amine
  参考文献：
  名称：

  Pd-catalyzed coupling of aryl iodides with triarylbismuths as atom-economic multi-coupling organometallic nucleophiles under mild conditions

  摘要：

  The facile cross-coupling reactivity of triarylbismuth compounds with aryl iodides was achieved under mild heating conditions. The established catalytic protocol using Pd(OAc)(2)(Cy2NH)(2) system exhibited high coupling reactivity with a variety of triarylbismuth and aryl iodide compounds under mild conditions. These coupling reactions were completed in short reaction time affording good to high yields of functionalized biaryl products. The studies of multi-coupling reactions with tris(4-iodophenyl)amine, 8 also furnished moderate to good yields of coupled products, 8a-8f. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.053

文献信息

• Organic EL Device
  申请人：TDK Corporation

  公开号：EP1342769B1

  公开（公告）日：2010-01-27
• EP1992672A1
  申请人：——

  公开号：EP1992672A1

  公开（公告）日：2008-11-19
• Organic electroluminescent device
  申请人：Nariyuki Fumito

  公开号：US20070015004A1

  公开（公告）日：2007-01-18

  The invention provides an organic electroluminescent device having at least a light-emitting layer containing a light-emitting material and a host material, a hole injection-promoting layer, and a hole-transporting layer containing a hole-transporting material in this order between a pair of electrodes, in which the hole injection-promoting layer contains a hole-transporting material and has a thickness of 0.1 nm to 0.3 nm, and the relationship Ip1
• US7923128B2
  申请人：——

  公开号：US7923128B2

  公开（公告）日：2011-04-12