1-methyl-3-phenyl-pyridinium chloride | 123934-18-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-methyl-3-phenyl-pyridinium chloride
• 英文别名: N-methyl-3-phenylpyridinium chloride；chlorure de 1-methyl-3-phenylpyridinium；1-Methyl-3-phenylpyridin-1-ium;chloride
• CAS: 123934-18-9
• 化学式: C₁₂H₁₂N*Cl
• 分子量: 205.687
• InChiKey: KFZAJIZHTDMXBL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.82
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methyl-3-phenyl-pyridinium chloride 在 palladium on activated charcoal 水 、 氢气 、 溴 、 三乙胺 作用下， 以 甲醇 为溶剂， 反应 21.25h， 生成 (RS) 1-methyl-2-phenylpyrrolidine-2-carbaldehyde
  参考文献：
  名称：

  Plaquevent, Jean-Christophe; Chichaoui, Ilhame, Bulletin de la Societe Chimique de France, 1996, vol. 133, # 4, p. 369 - 379

  摘要：

  DOI：
• 作为产物：
  描述：

  3-苯基吡啶 在 silver(I) chloride 作用下， 以 甲醇 为溶剂， 反应 5.0h， 生成 1-methyl-3-phenyl-pyridinium chloride
  参考文献：
  名称：

  Plaquevent, Jean-Christophe; Chichaoui, Ilhame, Bulletin de la Societe Chimique de France, 1996, vol. 133, # 4, p. 369 - 379

  摘要：

  DOI：

文献信息

• TRANSITION METAL CATALYSTS AND PROCESSES FOR PRODUCING $g(a)-OLEFIN AND VINYL COMPOUND POLYMER
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1136122A1

  公开（公告）日：2001-09-26

  A catalyst comprising (a) a complex of Group 8 to 10 transition metal of the Periodic Table, (b) clay, clay mineral or a ion-exchangeable layered compound, and (c) an amine compound or its adduct with Brφnsted acid; a catalyst comprising (a) a chelate complex of Group 4 to 6 transition metal of the Periodic Table or a complex of Group 8 to 10 transition metal of the Periodic Table, (b) clay, clay mineral or a ion-exchangeable layered compound, and (c) a quaternary ammonium salt; and a catalyst comprising (a) a complex of Group 4 to 6 transition metal of the Periodic Table or a complex of Group 8 to 10 transition metal of the Periodic Table and a co-catalyst component produced by contacting (b) clay, clay mineral or a ion-exchangeable layered compound, (c) an amine compound, its adduct with Brφnsted acid or a quaternary ammonium salt, and (d) an organosilane compound. Since these catalysts show high oligomerization activity of ethylene, α-olefins can be efficiently produced with low costs from ethylene. By using the catalysts, vinyl-terminated, linear α-olefins (oligomers) having a molecular weight of 10000 or less or polyolefins having a molecular weight exceeding 10000 can be also produced efficiently with low costs.

  一种催化剂，包括(a)元素周期表第 8 至 10 族过渡金属的络合物，(b)粘土、粘土矿物或可离子交换的层状化合物，和(c)胺化合物或其与 Brφnsted 酸的加合物；一种催化剂，包括(a)元素周期表第 4 至 6 族过渡金属的螯合物或元素周期表第 8 至 10 族过渡金属的络合物，(b)粘土、粘土矿物或可离子交换的层状化合物，和(c)季铵盐；以及一种催化剂，包括(a)元素周期表中第 4 至 6 族过渡金属的络合物或元素周期表中第 8 至 10 族过渡金属的络合物，以及通过接触(b)粘土、粘土矿物或可离子交换的层状化合物、(c)胺化合物、其与溴化锍酸或季铵盐的加合物和(d)有机硅化合物而产生的助催化剂组分。由于这些催化剂对乙烯具有很高的低聚活性，因此可以低成本、高效率地利用乙烯生产 α-烯烃。通过使用这些催化剂，还可以低成本高效率地生产出分子量在 10000 或以下的乙烯基封端线性 α-烯烃（低聚物）或分子量超过 10000 的聚烯烃。
• CATALYST FOR VINYL COMPOUND POLYMERIZATION AND PROCESS FOR PRODUCING VINYL POLYMER
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1270602A1

  公开（公告）日：2003-01-02

  The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing α-olefins according to the present invention comprises (A') a complex of Group 8 to 10 transition metal of the Periodic Table, (B') an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (C') at least one aluminoxy compound represented by Formula (2): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.

  根据本发明的乙烯基化合物聚合催化剂包括(A)元素周期表中第 4 至 10 族过渡金属的络合物，(B)粘土、粘土矿物或可离子交换的层状化合物，和(C)至少一种由式(1)表示的铝氧化合物： 其中多个 R 基团各自独立地为 C1-10 烃基，且至少一个 R 基团为具有 2 个或更多碳原子的烃基；以及 x 为 2 或更多的整数。通过将第 4 至第 10 族过渡金属络合物和粘土、粘土矿物或可离子交换的层状化合物与特定的铝氧化合物结合使用，可高效生产乙烯基聚合物。另外，根据本发明生产 α-烯烃的催化剂包括（A'）元素周期表中第 8 至 10 族过渡金属的络合物，（B'）有机化合物改性的粘土、粘土矿物或离子交换层状化合物，以及（C'）至少一种由式（2）表示的铝氧化合物： 由于有机化合物改性的粘土、粘土矿物或可离子交换的层状化合物会吸收其层间的其他催化剂组分，因此可有效防止催化剂组分洗脱到液相中，从而促进催化剂与反应产物的分离。
• Catalyst for vinyl compounds and process for production of vinyl polymers
  申请人：——

  公开号：US20030027716A1

  公开（公告）日：2003-02-06

  The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): 1 wherein a plurality of R groups are each independently C 1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing &agr;-olefins according to the present invention comprises (A′) a complex of Group 8 to 10 transition metal of the Periodic Table, (B′) an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (C′) at least one aluminoxy compound represented by Formula (2): 2 wherein a plurality of R groups are each independently C 1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.

  根据本发明的乙烯基化合物聚合催化剂包括：(A) 元素周期表中第 4 至第 10 族过渡金属的络合物；(B) 粘土、粘土矿物或可离子交换的层状化合物；(C) 至少一种由式(1)表示的铝氧化合物： 1 其中多个 R 基团各自独立地为 C 1-10 烃基，且至少一个 R 基团是具有 2 个或更多碳原子的烃基；以及 x 是 2 或更多的整数。将第 4 至第 10 族过渡金属络合物和粘土、粘土矿物或可离子交换的层状化合物与特定的铝氧化合物结合使用，可高效生产乙烯基聚合物。另外，根据本发明生产&agr;-烯烃的催化剂包括(A′)元素周期表中第8至10族过渡金属的络合物，(B′)有机化合物改性的粘土、粘土矿物或离子交换层状化合物，和(C′)至少一种由式(2)表示的铝氧化合物： 2 其中多个 R 基团各自独立地为 C 1-10 由于有机化合物改性粘土、粘土矿物或可离子交换的层状化合物会吸收其层间的其它催化剂组分，因此可有效防止催化剂组分洗脱到液相中，从而促进催化剂与反应产物的分离。
• Catalyst for vinyl compound polymerization and process for producing vinyl polymer
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：US20040259720A1

  公开（公告）日：2004-12-23

  The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): 1 wherein a plurality of R groups are each independently C 1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing &agr;-olefins according to the present invention comprises (A′) a complex of Group 8 to 10 transition metal of the Periodic Table, (B′) an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (C′) at least one aluminoxy compound represented by Formula (2): 2 wherein a plurality of R groups are each independently C 1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.

  根据本发明的乙烯基化合物聚合催化剂包括：(A) 元素周期表中第 4 至第 10 族过渡金属的络合物；(B) 粘土、粘土矿物或可离子交换的层状化合物；(C) 至少一种由式(1)表示的铝氧化合物： 1 其中多个 R 基团各自独立地为 C 1-10 烃基，且至少一个 R 基团是具有 2 个或更多碳原子的烃基；以及 x 是 2 或更多的整数。将第 4 至第 10 族过渡金属络合物和粘土、粘土矿物或可离子交换的层状化合物与特定的铝氧化合物结合使用，可高效生产乙烯基聚合物。另外，根据本发明生产&agr;-烯烃的催化剂包括(A′)元素周期表中第8至10族过渡金属的络合物，(B′)有机化合物改性的粘土、粘土矿物或离子交换层状化合物，和(C′)至少一种由式(2)表示的铝氧化合物： 2 其中多个 R 基团各自独立地为 C 1-10 由于有机化合物改性粘土、粘土矿物或可离子交换的层状化合物会吸收其层间的其它催化剂组分，因此可有效防止催化剂组分洗脱到液相中，从而促进催化剂与反应产物的分离。
• Nitromethylenation of N-methylpyridinium salts
  作者：Dick J. Buurman、Albertus Van Veldhuizen、Henk C. Van der Plas

  DOI：10.1021/jo00289a071

  日期：1990.1