9-hexyl-3,6-di(pyren-1-yl)carbazole | 1264004-32-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 9-hexyl-3,6-di(pyren-1-yl)carbazole
• 英文别名: 3,6-dipyrenyl-N-hexylcarbazole
• CAS: 1264004-32-1
• 化学式: C₅₀H₃₇N
• 分子量: 651.85
• InChiKey: SXTVXYFUAVDXSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.1
• 重原子数：
  51
• 可旋转键数：
  7
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,6-二溴9-己基-9H-咔唑 、 4,4,5,5-四甲基-2-(芘-1-基)-1,3,2-二噁唑环戊硼烷 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 36.0h， 以63%的产率得到9-hexyl-3,6-di(pyren-1-yl)carbazole
  参考文献：
  名称：

  Highly fluorescent intramolecular dimmers of two pyrenyl-substituted fluorenes bridged by 1,6-hexanyl: synthesis, spectroscopic, and self-organized properties

  摘要：

  Two intramolecular dimmers of 4-, 8-pyrenyl-substituted fluorenes budged by 1,6-hexanyl unit have been synthesized. They showed very strong fluorescent emission with the emission peak at around 450 nm and fluorescence efficiency as high as similar to 0 9. The absorption spectra also had high extinction coefficients. The cyclic voltammetric curves showed that they can be used as electron-donating materials. The DSC results suggested the dimmers have higher glass transition temperature. It was also found that these novel dimmers can self-organize into spherical particles from the solutions due to evaporation of the solvent. (C) 2010 Elsevier Ltd All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.12.136

文献信息

• Highly fluorescent intramolecular dimmers of two pyrenyl-substituted fluorenes bridged by 1,6-hexanyl: synthesis, spectroscopic, and self-organized properties
  作者：Chao He、Qingguo He、Qing Chen、Liqi Shi、Huimin Cao、Jiangong Cheng、Changmin Deng、Tong Lin

  DOI：10.1016/j.tetlet.2009.12.136

  日期：2010.3

  Two intramolecular dimmers of 4-, 8-pyrenyl-substituted fluorenes budged by 1,6-hexanyl unit have been synthesized. They showed very strong fluorescent emission with the emission peak at around 450 nm and fluorescence efficiency as high as similar to 0 9. The absorption spectra also had high extinction coefficients. The cyclic voltammetric curves showed that they can be used as electron-donating materials. The DSC results suggested the dimmers have higher glass transition temperature. It was also found that these novel dimmers can self-organize into spherical particles from the solutions due to evaporation of the solvent. (C) 2010 Elsevier Ltd All rights reserved.