苯乙酸（钙盐）

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯乙酸（钙盐）
• 中文别名: 1H-苯并咪唑-2-甲胺,1-苯基-；2-苯乙酸钙
• 英文名称: Calciumphenylacetate
• 英文别名: calcium;2-phenylacetate
• 化学式: C16H14CaO4
• 分子量: 310.36
• InChiKey: XWSRCZGIHKNZFL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.42
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Processes for producing optically active 2-amino-1-phenylethanol derivatives
  申请人：Daicel Chemical Industries, Ltd.

  公开号：US20030143701A1

  公开（公告）日：2003-07-31

  An (R)-2-amino-1-phenylethanol derivative shown by the general formula (IIa) 1 wherein R 1 and R 5 represent a hydrogen atom, etc.; R 2 , R 3 and R 4 independently represent a halogen atom, etc., or a salt thereof, can readily be produced (1) by permitting a microorganism belonging to the genus Rhodosporidium, the genus Comamonas or the like to act on a mixture of corresponding (R)-form and (S)-form to asymmetrically utilize, or (2) by permitting a microorganism belonging to the genus Lodderomyces, the genus Pilimelia or the like to act on a corresponding aminoketone derivative to asymmetrically reduce. An (R,R)-1-phenyl-2-[(2-phenyl-1-alkylethyl)amino]ethanol derivative having a high optical purity can easily be obtained from the compound of the formula (IIa) or a salt thereof. Said derivative is useful as an intermediate for producing an anti-obesity agent and so on.

  通式（IIa）所示的（R）-2-氨基-1-苯乙醇衍生物，其中R1和R5代表氢原子等；R2、R3和R4分别独立地表示卤素原子等，或其盐，可以通过（1）让属于红孢霉属、普通小杆菌属或类似菌属的微生物作用于相应（R）-型和（S）-型的混合物以不对称利用，或（2）让属于洛德罗霉属、皮利米利亚属或类似菌属的微生物作用于相应的氨基酮衍生物以不对称还原而轻松制备。可以从式（IIa）化合物或其盐中轻松获得具有高光学纯度的（R，R）-1-苯基-2-［（2-苯基-1-烷基乙基）氨基］乙醇衍生物。所述衍生物可用作生产抗肥胖剂等中间体。
• Polyphenylene sulfide resin compositions
  申请人：Kojima Akira

  公开号：US20070021549A1

  公开（公告）日：2007-01-25

  A polyphenylene sulfide resin composition which comprises 100 parts by weight of a polyphenylene sulfide resin (A) and, compounded therewith, 1 to 100 parts by weight of glass fibers (B) having a single-fiber diameter of 12 μm or lager and has a crystallization temperature during cooling of 205° C. or lower. Also provided is a polyphenylene sulfide resin composition which comprises 100 parts by weight of a polyphenylene sulfide resin (A) and, compounded therewith, 1 to 100 parts by weight of glass fibers (B) having a single-fiber diameter of 10 to 12 μm, excluding 12 μm, has a crystallization temperature during cooling of 205° C. or lower and a chloroform-extractable content of 0.5 wt. % or lower, and gives a 2 mm-thick molded product which has a transmittance of 15% or higher for laser beam having a wavelength of 940 nm and a heat distortion temperature of 230° C. or higher under a load of 1.82 MPa.

  一种聚苯硫醚树脂组合物，包括100重量份的聚苯硫醚树脂（A），并与之混合1至100重量份的玻璃纤维（B），其单纤维直径为12μm或更大，并在冷却时具有205℃或更低的结晶温度。另外，还提供一种聚苯硫醚树脂组合物，包括100重量份的聚苯硫醚树脂（A），并与之混合1至100重量份的玻璃纤维（B），其单纤维直径为10至12μm，不包括12μm，并在冷却时具有205℃或更低的结晶温度，氯仿可提取物含量为0.5重量％或更低，并且在1.82 MPa的负载下具有940 nm波长的激光束的透射率为15％或更高，以及230℃或更高的热变形温度的2毫米厚模制品。
• POLYPHENYLENE SULFIDE RESIN COMPOSITIONS
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1630201A1

  公开（公告）日：2006-03-01

  A polyphenylene sulfide resin composition which comprises 100 parts by weight of a polyphenylene sulfide resin (A) and, compounded therewith, 1 to 100 parts by weight of glass fibers (B) having a single-fiber diameter of 12 µm or lager and has a crystallization temperature during cooling of 205°C or lower. Also provided is a polyphenylene sulfide resin composition which comprises 100 parts by weight of a polyphenylene sulfide resin (A) and, compounded therewith, 1 to 100 parts by weight of glass fibers (B) having a single-fiber diameter of 10 to 12 µm, excluding 12 µm, has a crystallization temperature during cooling of 205°C or lower and a chloroform-extractable content of 0.5 wt.% or lower, and gives a 2 mm-thick molded product which has a transmittance of 15% or higher for laser beam having a wavelength of 940 nm and a heat distortion temperature of 230°C or higher under a load of 1.82 MPa.

  一种聚苯硫醚树脂组合物，它由 100 份（按重量计）聚苯硫醚树脂（A）和 1 至 100 份（按重量计）单纤维直径为 12 微米或更小的玻璃纤维（B）复合而成，冷却时的结晶温度为 205°C 或更低。还提供了一种聚苯硫醚树脂组合物，它由 100 重量份的聚苯硫醚树脂 (A) 和 1 至 100 重量份的玻璃纤维 (B) 复合而成，玻璃纤维 (B) 的单纤维直径为 10 至 12 微米（不包括 12 微米），冷却时的结晶温度为 205°C 或更低，氯仿萃取含量为 0.5 wt.%或更低，并能得到 2 毫米厚的模制产品，该产品在波长为 940 纳米的激光束下的透射率为 15%或更高，在 1.82 兆帕的载荷下的热变形温度为 230°C 或更高。
• Optically active 1-phenyl-2-substituted propane derivatives and methods of producing the same
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0627397B1

  公开（公告）日：1997-01-02
• US4100160A
  申请人：——

  公开号：US4100160A

  公开（公告）日：1978-07-11