2-(2-oxopropyl)phenyl acetate | 115144-87-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 2-(2-oxopropyl)phenyl acetate
• 英文别名: 1-(2-acetoxyphenyl)-2-propanone；(2-acetoxy-phenyl)-acetone；(2-Acetoxy-phenyl)-aceton；[2-(2-Oxopropyl)phenyl] acetate
• CAS: 115144-87-1
• 化学式: C₁₁H₁₂O₃
• 分子量: 192.214
• InChiKey: IBVQJULZGYTMCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-oxopropyl)phenyl acetate 在 溶剂黄146 作用下， 以 甲醇 、 乙二醇 为溶剂， 反应 0.25h， 生成 2-(3,5-Dimethyl-1-phenyl-1H-pyrazol-4-yl)-phenol
  参考文献：
  名称：

  Dzvinchuk, I. B.; Okolovskii, Yu. A.; Lozinskii, M. O., Russian Journal of Organic Chemistry, 1994, vol. 30, # 11.1, p. 1760 - 1764

  摘要：

  DOI：
• 作为产物：
  描述：

  2-丙烯基苯酚 在 过氧乙酸 、 乙酸乙酯 作用下， 生成 2-(2-oxopropyl)phenyl acetate
  参考文献：
  名称：

  Reaction of o-Alkenylphenols with Peracetic Acid

  摘要：

  DOI：

  10.1021/jo01091a007

文献信息

• Magnesium-Promoted Reductive Silylation and Acylation of Tropone and Tropone Acetal
  作者：Hirofumi Maekawa、Keisuke Nagakubo、Midori Nishi、Makoto Nishimura、Daisuke Nagahara

  DOI：10.1246/bcsj.20130156

  日期：2013.10.15

  Magnesium-promoted reductive coupling of chlorotrialkylsilanes and tropone or tropone acetal in DMF, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in benzene gives 2-trialkyl...

  镁促进的氯三烷基硅烷和托酮或托酮缩醛在 DMF 中的还原偶联，然后用 2,3-二氯-5,6-二氰基-1,4-苯醌在苯中氧化得到 2-三烷基...
• Pegylated carfilzomib compounds
  申请人：AMGEN INC.

  公开号：US11077198B2

  公开（公告）日：2021-08-03

  The present invention provides a method of treating multiple myeloma using polymeric pegylated carfilzomib compounds, and pharmaceutically acceptable salts thereof, of Formula I wherein R1, R2, linker, PEG, n and o are as defined herein.

  本发明提供了一种使用聚合物聚乙二醇化卡非佐米化合物及其药学上可接受的盐类治疗多发性骨髓瘤的方法，其式为 I 其中 R1、R2、连接剂、PEG、n 和 o 如本文所定义。
• Dzvinchuk, I. B.; Okolovskii, Yu. A.; Lozinskii, M. O., Russian Journal of Organic Chemistry, 1995, vol. 31, # 2, p. 218 - 220
  作者：Dzvinchuk, I. B.、Okolovskii, Yu. A.、Lozinskii, M. O.

  DOI：——

  日期：——
• ROBIN, YVES;CHAUSSARD, JACQUES;TROUPEL, MICHEL;GUITTON, PASCALE
  作者：ROBIN, YVES、CHAUSSARD, JACQUES、TROUPEL, MICHEL、GUITTON, PASCALE

  DOI：——

  日期：——
• Hybrid Energy Curable Solvent-Based Liquid Printing Inks
  申请人：Laksin Mikhail

  公开号：US20070263060A1

  公开（公告）日：2007-11-15

  The present invention provides a liquid printing ink that produces high quality flexographic or gravure printing images that have excellent solvent and abrasion resistance. In addition, the printing ink of the invention has high re-solubility, even after complete drying, upon contact with the liquid vehicle of the same ink, thereby preventing clogging of the printing plate, anilox or gravure cylinders over time. These characteristics of the printing ink are obtained by preparing a hybrid ink in which conventional organic solvent and/or water-based liquid inks are mixed with energy curable monomers and/or oligomers of resins and, optionally, a photoinitiator. After drying the ink, the printed images are exposed to an actinic radiation so that highly cross-linked polymers are formed in the printed images, which become water, chemical and abrasion-resistant.