anthracene radical anion | 115826-04-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthracene radical anion
• 英文别名: Anthracen-Radikalanion；Anthracen-Anionradikal；9H-anthracen-9-ide
• CAS: 115826-04-5
• 化学式: C₁₄H₉
• 分子量: 177.225
• InChiKey: WNLLYTVBIYFFBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  anthracene radical anion 在 四丁基溴化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 9,9'-bianthryl dianion
  参考文献：
  名称：

  Experimental study of dimerization of radical anions of aromatic carbonyl compounds

  摘要：

  The rate constants of dimerization (k1) of radical anions of acetophenone, 1-acetylnaphthalene, 9-acetylanthracene, 9-formylanthracene, and anthracene in DMF containing 0.02 M tetrabutylammonium bromide were determined by differential cyclic voltammetry. It was shown that the values of k1 of the radical anions investigated are correlated with the values of the boundary electron density on the reaction sites, which in turn increase symbatically with an increase in the size of the aryl fragment or on incorporation of electron-acceptor functional groups in the anthracene nucleus.

  DOI：

  10.1007/bf01172253

文献信息

• Niyazymbetov, Murat E.; Rongfeng, Zhou; Evans, Dennis H., Journal of the Chemical Society. Perkin transactions II, 1996, # 9, p. 1957 - 1962
  作者：Niyazymbetov, Murat E.、Rongfeng, Zhou、Evans, Dennis H.

  DOI：——

  日期：——