2,4-Bis(3-amino-anilino)-6-diphenylamino-1,3,5-triazin | 33933-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-Bis(3-amino-anilino)-6-diphenylamino-1,3,5-triazin
• 英文别名: 2,4-Bis-(m-aminoanilino)-6-diphenylamino-s-triazin；N',N''-bis-(3-amino-phenyl)-N,N-diphenyl-[1,3,5]triazine-2,4,6-triamine；1,3,5-Triazine-2,4,6-triamine, N',N''-bis(3-aminophenyl)-N,N-diphenyl-；4-N,6-N-bis(3-aminophenyl)-2-N,2-N-diphenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 33933-66-3
• 化学式: C₂₇H₂₄N₈
• 分子量: 460.541
• InChiKey: KZJQPJFIMOCZJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  35
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  118
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,4-Bis(3-amino-anilino)-6-diphenylamino-1,3,5-triazin 、 bis-(4,6-dichloro-[1,3,5]triazin-2-yl)-p-tolyl-amine 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 1.5h， 以34%的产率得到11,17-Dichlor-29-diphenylamino-14-(p-tolyl)-2,8,10,12,14,16,18,20,26,28,30,31,33,34-tetradecaazahexacyclo[25.3.1.1^3,7.1^9,13.1^15,19.1^21,25]pentatriaconta-1(31),3,5,7(35),9,11,13(34),15,17,19(33),21,23,25(32),27,29-pentadecaene
  参考文献：
  名称：

  Polyazacalix[5]arene - Synthese und NMR-Untersuchungen

  摘要：

  The polyazacalix[5]arenes 5a-f were easily prepared by cyclisation of cyanuric chloride derivatives 3a-d und 4a-b. These macrocycles contain two phenylene and three 1,3,5-triazine units. The derivatisation of reactive chlorine-containing macrocycles 5 with amines, diamines and methanol gave compounds 6a-e. The structures and conformations of these novel macrocyclic ring systems have been investigated by various NMR methods.

  DOI：

  10.1002/prac.19973390147

文献信息

• POLYIMIDE FILM, POLYIMIDE LAMINATE COMPRISING SAME, AND POLYIMIDE/METAL LAMINATE COMPRISING SAME
  申请人：Ube Industries, Ltd.

  公开号：EP2535367A1

  公开（公告）日：2012-12-19

  Disclosed is a polyimide film having improved adhesiveness to an adhesive and/or adherence to a metal layer. The polyimide film has at least a polyimide layer (b) and a polyimide layer (a) formed contacting the polyimide layer (b), wherein the polyimide layer (a) is a polyimide formed from a tetracarboxylic dianhydride component and a diamine component containing a diamine compound represented by general formula (1): wherein R1 denotes a hydrogen atom, an alkyl group having 1 to 12 carbon atoms or an aryl group, and R2 denotes an alkyl group having 1 to 12 carbon atoms or an aryl group.

  本发明公开了一种聚酰亚胺薄膜，其与粘合剂的粘合性和/或与金属层的粘合性均有所改善。该聚酰亚胺薄膜至少有一个聚酰亚胺层（b）和一个与聚酰亚胺层（b）接触形成的聚酰亚胺层（a），其中聚酰亚胺层（a）是由四羧酸二酐组分和含有通式（1）表示的二胺化合物的二胺组分形成的聚酰亚胺： 其中 R1 表示氢原子、具有 1 至 12 个碳原子的烷基或芳基，R2 表示具有 1 至 12 个碳原子的烷基或芳基。
• Polyimide precursor, polyimide, varnish, polyimide film, and substrate
  申请人：Ube Industries, Ltd.

  公开号：US10174166B2

  公开（公告）日：2019-01-08

  A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y1, Y2 and Y3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y4 represents hydrogen atom, or a monovalent organic group.

  一种聚酰亚胺前体，包含由以下化学式（1）表示的重复单元： 其中，A 是芳香族二胺或脂肪族二胺的二价基团，其中的氨基已被去除；X1 和 X2 各自独立地是氢、具有 1 至 6 个碳原子的烷基或具有 3 至 9 个碳原子的烷基硅基、 其中聚酰亚胺前体包括至少一种由化学式（1）表示的重复单元，其中 A 是由化学式（2）或（3）表示的基团： 其中 m 独立地代表 0 至 3，n 独立地代表 0 至 3；Y1、Y2 和 Y3 各自独立地代表至少一个选自氢原子、甲基和三氟甲基的基团；以及 Q 和 R 各自独立地代表直接键或 -NHCO-、-CONH-、-COO- 和 -OCO- 中的至少一种、 其中 Z 和 W 各自独立地代表具有 6 至 18 个碳原子的二价芳香基团；Y4 代表氢原子或一价有机基团。
• US20140255710A1
  申请人：——

  公开号：US20140255710A1

  公开（公告）日：2014-09-11
• POLYIMIDE PRECURSOR, POLYIMIDE, VARNISH, POLYIMIDE FILM, AND SUBSTRATE
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20150361222A1

  公开（公告）日：2015-12-17

  A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X 1 and X 2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y 1 , Y 2 and Y 3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y 4 represents hydrogen atom, or a monovalent organic group.
• US3943107A
  申请人：——

  公开号：US3943107A

  公开（公告）日：1976-03-09