3,8-dimethoxynaphtho[1,8-cd]-1,2-ditellurole | 1314930-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3,8-dimethoxynaphtho[1,8-cd]-1,2-ditellurole
• 英文别名: 5,11-Dimethoxy-2,3-ditelluratricyclo[6.3.1.04,12]dodeca-1(11),4,6,8(12),9-pentaene；5,11-dimethoxy-2,3-ditelluratricyclo[6.3.1.04,12]dodeca-1(11),4,6,8(12),9-pentaene
• CAS: 1314930-40-9
• 化学式: C₁₂H₁₀O₂Te₂
• 分子量: 441.41
• InChiKey: QCJTVYUNAMAEHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.44
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,8-dimethoxynaphtho[1,8-cd]-1,2-ditellurole 、 7,7,8,8-四氰基对苯二醌二甲烷 以 乙腈 为溶剂， 生成 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile compound with 3,8-dimethoxynaphtho[1,8-cd][1,2]ditellurole (1:1)
  参考文献：
  名称：

  Charge transfer complexes of electron-rich naphthalene peri-dichalcogenides with TCNQ

  摘要：

  The electronic structures of several highly electron-rich 2,7-dimethoxynaphthalene peri-dichalcogenides were evaluated using optical and electrochemical methods, as well as by DFT calculations. Charge transfer complexes were formed with tetracyanoquinodimethane and resulted in absorption features that span from 300 nm to 1600 nm and HOMO-LUMO energy gaps as low as 0.8 eV. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.01.068
• 作为产物：
  描述：

  2,7-二甲氧基萘 在 吡啶 、 N-溴代丁二酰亚胺(NBS) 、 正丁基锂 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 反应 10.5h， 生成 3,8-dimethoxynaphtho[1,8-cd]-1,2-ditellurole
  参考文献：
  名称：

  Enhanced Glutathione Peroxidase Activity of Conformationally Restricted Naphthaleneperi-Dichalcogenides

  摘要：

  Conformationally restricted naphthalene peri-diselenides function as glutathione peroxidase mimetics with superior catalytic activity to that displayed by typical acyclic diaryl diselenides. Their activity was increased by electron-donating methoxy substituents, while a further 100-fold increase was observed with the corresponding ditelluride.

  DOI：

  10.1021/ol201617t
• 作为试剂：
  描述：

  苄硫醇 在 3,8-dimethoxynaphtho[1,8-cd]-1,2-ditellurole 、 双氧水 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 二苄基二硫
  参考文献：
  名称：

  Enhanced Glutathione Peroxidase Activity of Conformationally Restricted Naphthaleneperi-Dichalcogenides

  摘要：

  Conformationally restricted naphthalene peri-diselenides function as glutathione peroxidase mimetics with superior catalytic activity to that displayed by typical acyclic diaryl diselenides. Their activity was increased by electron-donating methoxy substituents, while a further 100-fold increase was observed with the corresponding ditelluride.

  DOI：

  10.1021/ol201617t

文献信息

• Enhanced Glutathione Peroxidase Activity of Conformationally Restricted Naphthalene<i>peri</i>-Dichalcogenides
  作者：David J. Press、Thomas G. Back

  DOI：10.1021/ol201617t

  日期：2011.8.5

  Conformationally restricted naphthalene peri-diselenides function as glutathione peroxidase mimetics with superior catalytic activity to that displayed by typical acyclic diaryl diselenides. Their activity was increased by electron-donating methoxy substituents, while a further 100-fold increase was observed with the corresponding ditelluride.
• Charge transfer complexes of electron-rich naphthalene peri-dichalcogenides with TCNQ
  作者：David J. Press、Thomas G. Back、Todd C. Sutherland

  DOI：10.1016/j.tetlet.2012.01.068

  日期：2012.3

  The electronic structures of several highly electron-rich 2,7-dimethoxynaphthalene peri-dichalcogenides were evaluated using optical and electrochemical methods, as well as by DFT calculations. Charge transfer complexes were formed with tetracyanoquinodimethane and resulted in absorption features that span from 300 nm to 1600 nm and HOMO-LUMO energy gaps as low as 0.8 eV. (C) 2012 Elsevier Ltd. All rights reserved.