N-(2,6-dimethylphenyl)-2,3,4,5,6-pentamethylaniline | 1446695-54-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,6-dimethylphenyl)-2,3,4,5,6-pentamethylaniline
• CAS: 1446695-54-0
• 化学式: C₁₉H₂₅N
• 分子量: 267.414
• InChiKey: LPPVHQICLKLZPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴五甲基苯 、 2,6-二甲基苯胺 在 [Pd(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(cinnamyl)Cl] 、 potassium 2-methylbutan-2-olate 作用下， 以 neat (no solvent) 为溶剂， 反应 24.08h， 以66%的产率得到N-(2,6-dimethylphenyl)-2,3,4,5,6-pentamethylaniline
  参考文献：
  名称：

  [Pd（NHC）]配合物催化的无溶剂芳基化†

  摘要：

  描述了一种用于未活化的芳基氯的布赫瓦尔德-哈特维格胺胺化的高效无溶剂方案。研究了各种[Pd（NHC）]预催化剂体系对反应活性的影响。据报道[Pd（IPr *）（cin）Cl]是转化的选择复合物。

  DOI：

  10.1039/c3ra40386f

文献信息

• COMPOSITION FOR ANODE BUFFER LAYER, HIGH-MOLECULAR WEIGHT COMPOUND FOR ANODE BUFFER LAYER, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND PRODUCTION PROCESS AND USES OF THE SAME
  申请人：Osako Haruka

  公开号：US20120217491A1

  公开（公告）日：2012-08-30

  There is provided a material for an anode buffer layer which permits the use of an organic solvent as a solvent of an anode buffer layer-forming solution, and is capable of forming an anode buffer layer that does not dissolve even when coated with a luminescent layer-forming material solution containing an organic solvent as a solvent, and which is capable of producing an organic EL element having high electrical power efficiency and long life. The composition for an anode buffer layer includes an electron-accepting compound and a high-molecular weight compound having a structural unit represented by the following formula (1) or the following formula (2) and having a weight average molecular weight of 20,000 to 1,000,000 as measured by GPC: wherein in each of the formulae (1) and (2), plural R a s are each a hydrogen atom or an alkyl group, with at least one R a being the alkyl group, plural R b s are each a hydrogen atom or an alkyl group, plural R c S are each a hydrogen atom, an alkyl group or the like, X is a single bond or the like, Y is a structure derived from a vinyl group and the like, and p is 0, 1 or 2.
• US9644048B2
  申请人：——

  公开号：US9644048B2

  公开（公告）日：2017-05-09
• Solvent-free aryl amination catalysed by [Pd(NHC)] complexes
  作者：Anthony Chartoire、Arnaud Boreux、Anthony R. Martin、Steven P. Nolan

  DOI：10.1039/c3ra40386f

  日期：——

  A highly effective solvent-free protocol for the Buchwald–Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd(NHC)] pre-catalyst systems on the reactivity has been studied. [Pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.

  描述了一种用于未活化的芳基氯的布赫瓦尔德-哈特维格胺胺化的高效无溶剂方案。研究了各种[Pd（NHC）]预催化剂体系对反应活性的影响。据报道[Pd（IPr *）（cin）Cl]是转化的选择复合物。