(3-pentamethylphenylpropyl)diphenylphosphine | 365246-87-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-pentamethylphenylpropyl)diphenylphosphine
• 英文别名: 3-(2,3,4,5,6-Pentamethylphenyl)propyl-diphenylphosphane
• CAS: 365246-87-3
• 化学式: C₂₆H₃₁P
• 分子量: 374.506
• InChiKey: VNSJOENCQVFCQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  di-μ-chloro-bis{chloro(η6-methyl-o-toluate)}ruthenium(II) 、 二氯甲烷 、 (3-pentamethylphenylpropyl)diphenylphosphine 以 二氯甲烷 为溶剂， 以98%的产率得到[RuCl2(η6-methyl o-toluate)((3-pentamethylphenylpropyl)diphenylphosphine)]*0.2(dichloromethane)
  参考文献：
  名称：

  Synthesis, structure and redox behaviour of tethered arene–ruthenium(II) complexes

  摘要：

  Tethered arene-ruthenium complexes [RuCl2{eta (1):eta (6)-Me2P(CH2)(3)C6H5}], [RuCl2{eta (1):eta (6)-Ph2PCH2SiMe2C6H5}] and [RuCl2{eta (1):eta (6)-Ph2P(CH2)(3)(aryl)}] (aryl = 2,4,6-C6H2Me3 C6Me5) have been prepared by thermal displacement of methyl o-toluate from the appropriate P-donor derivatives of [RuCl2(eta (6)-1,2-MeC6H4CO2Me)](2) and their structures determined by X-ray studies. The tethered complexes undergo reversible one-electron oxidation by cyclic voltammetry; the half-wave potentials are in the range 1.10-1.34 V versus Ag / AgCl and decrease with increasing methyl substitution on the arene. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00801-4
• 作为产物：
  描述：

  溴五甲基苯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 22.5h， 生成 (3-pentamethylphenylpropyl)diphenylphosphine
  参考文献：
  名称：

  Synthesis, structure and redox behaviour of tethered arene–ruthenium(II) complexes

  摘要：

  Tethered arene-ruthenium complexes [RuCl2{eta (1):eta (6)-Me2P(CH2)(3)C6H5}], [RuCl2{eta (1):eta (6)-Ph2PCH2SiMe2C6H5}] and [RuCl2{eta (1):eta (6)-Ph2P(CH2)(3)(aryl)}] (aryl = 2,4,6-C6H2Me3 C6Me5) have been prepared by thermal displacement of methyl o-toluate from the appropriate P-donor derivatives of [RuCl2(eta (6)-1,2-MeC6H4CO2Me)](2) and their structures determined by X-ray studies. The tethered complexes undergo reversible one-electron oxidation by cyclic voltammetry; the half-wave potentials are in the range 1.10-1.34 V versus Ag / AgCl and decrease with increasing methyl substitution on the arene. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00801-4

文献信息

• Synthesis, structure and redox behaviour of tethered arene–ruthenium(II) complexes
  作者：Martin A. Bennett、Alison J. Edwards、Joanne R. Harper、Tetyana Khimyak、Anthony C. Willis

  DOI：10.1016/s0022-328x(01)00801-4

  日期：2001.6

  Tethered arene-ruthenium complexes [RuCl2eta (1):eta (6)-Me2P(CH2)(3)C6H5}], [RuCl2eta (1):eta (6)-Ph2PCH2SiMe2C6H5}] and [RuCl2eta (1):eta (6)-Ph2P(CH2)(3)(aryl)}] (aryl = 2,4,6-C6H2Me3 C6Me5) have been prepared by thermal displacement of methyl o-toluate from the appropriate P-donor derivatives of [RuCl2(eta (6)-1,2-MeC6H4CO2Me)](2) and their structures determined by X-ray studies. The tethered complexes undergo reversible one-electron oxidation by cyclic voltammetry; the half-wave potentials are in the range 1.10-1.34 V versus Ag / AgCl and decrease with increasing methyl substitution on the arene. (C) 2001 Elsevier Science B.V. All rights reserved.