N-heptadecyl-phthalimide | 89423-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: N-heptadecyl-phthalimide
• 英文别名: N-Heptadecyl-phthalimid；2-Heptadecyl-1H-isoindole-1,3(2H)-dione；2-heptadecylisoindole-1,3-dione
• CAS: 89423-12-1
• 化学式: C₂₅H₃₉NO₂
• 分子量: 385.59
• InChiKey: XMOGPBIAULKRPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  28
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯酐 、 正十七胺 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.67h， 以90%的产率得到N-heptadecyl-phthalimide
  参考文献：
  名称：

  Comparison of microwave-assisted and conventional preparations of cyclic imides

  摘要：

  Microwave-assisted preparation of several cyclic imides was performed with four different cyclic anhydrides. All the reactions are significantly faster and the isolated yields are significantly higher compared to conventionally heated reactions. Furthermore, many of these reactions can be performed with a minimal amount of solvent, thereby enabling the synthetic chemist to obtain high quantities of pure cyclic imides in a matter of hours. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.092

文献信息

• Polyester compositions containing phthalimidoesters
  申请人：Monsanto Company

  公开号：EP0214112A2

  公开（公告）日：1987-03-11

  Certain phthalimidoesters are useful as plasticizers for polyethylene terephthalate, particularly for polyethylene terephthalate molding compositions containing a reinforcing agent and a nucleating agent.

  某些邻苯二甲酰亚胺酯可用作聚对苯二甲酸乙二醇酯的增塑剂，尤其适用于含有增强剂和成核剂的聚对苯二甲酸乙二醇酯模塑组合物。
• Wanag, Latvijas universitates raksti. Kimijas fakultates serija, 1938, vol. 4, p. 405,419
  作者：Wanag

  DOI：——

  日期：——
• US4639480A
  申请人：——

  公开号：US4639480A

  公开（公告）日：1987-01-27
• Comparison of microwave-assisted and conventional preparations of cyclic imides
  作者：Sunil K. Upadhyay、Subramanya R.K. Pingali、Branko S. Jursic

  DOI：10.1016/j.tetlet.2010.02.092

  日期：2010.4

  Microwave-assisted preparation of several cyclic imides was performed with four different cyclic anhydrides. All the reactions are significantly faster and the isolated yields are significantly higher compared to conventionally heated reactions. Furthermore, many of these reactions can be performed with a minimal amount of solvent, thereby enabling the synthetic chemist to obtain high quantities of pure cyclic imides in a matter of hours. (C) 2010 Elsevier Ltd. All rights reserved.