dichloroiron;di(propan-2-yl)phosphanylmethyl-di(propan-2-yl)phosphane | 155113-67-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: dichloroiron;di(propan-2-yl)phosphanylmethyl-di(propan-2-yl)phosphane
• CAS: 155113-67-0
• 化学式: C₁₃H₃₀Cl₂FeP₂
• 分子量: 375.082
• InChiKey: RRQKDOTYTCAKED-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.92
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dichloroiron;di(propan-2-yl)phosphanylmethyl-di(propan-2-yl)phosphane 、 3-氯-2-甲基丙烯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以27%的产率得到
  参考文献：
  名称：

  之二的制备（η 3 -烯丙基）铁（II）络合物及其反应用的1,3-二烯

  摘要：

  The title compounds were prepared by treating Fe(PR(3))(2)Cl-2 or Fe(R(2)P(CH2)(n)PR(2))Cl-2 with allylmagnesium chloride. Some of them were also made by reaction of Fe(PR(3))(2)Cl-2 with isopropylmagnesium chloride, or with active-magnesium and allyl chloride, or by reaction between tris(eta(3)-allyl)iron and bis(dimethylphosphino)ethane. The new compounds were characterized by NMR spectroscopy and shown to be formed as a mixture of two isomers that differ in the mutual arrangement of the two allyl groups. The reactions of the bis(allyl)iron compounds with 1,3-dienes were studied: complexes containing eta(4)-1,3-C4H6, eta(4)-1-C3H5C4H5 or eta(5)-l-ethylcyclohexadienyl groups were isolated from the reaction with 1,3-butadiene. The reaction between (eta(3)-C3H5)(2)Fe((Pr2PC2H4PPr)-Pr-i-Pr-i(2)) and 1,3-cyclohexadiene gave (eta(5)-cyclohexadienyl)Fe((Pr2PC2H4PPr2)-Pr-i-Pr-i)H.

  DOI：

  10.1016/0022-328x(94)88046-8

文献信息

• Gabor, B.; Goddard, R.; Holle, S., Zeitschrift fur Naturforschung, B: Chemical Sciences
  作者：Gabor, B.、Goddard, R.、Holle, S.、Jolly, P. W.、Krueger, C.、et at.

  DOI：——

  日期：——
• The preparation of bis(η3-allyl)iron(II) complexes and their reactions with 1,3-dienes
  作者：B. Gabor、S. Holle、P.W. Jolly、R. Mynott

  DOI：10.1016/0022-328x(94)88046-8

  日期：1994.2

  The title compounds were prepared by treating Fe(PR(3))(2)Cl-2 or Fe(R(2)P(CH2)(n)PR(2))Cl-2 with allylmagnesium chloride. Some of them were also made by reaction of Fe(PR(3))(2)Cl-2 with isopropylmagnesium chloride, or with active-magnesium and allyl chloride, or by reaction between tris(eta(3)-allyl)iron and bis(dimethylphosphino)ethane. The new compounds were characterized by NMR spectroscopy and shown to be formed as a mixture of two isomers that differ in the mutual arrangement of the two allyl groups. The reactions of the bis(allyl)iron compounds with 1,3-dienes were studied: complexes containing eta(4)-1,3-C4H6, eta(4)-1-C3H5C4H5 or eta(5)-l-ethylcyclohexadienyl groups were isolated from the reaction with 1,3-butadiene. The reaction between (eta(3)-C3H5)(2)Fe((Pr2PC2H4PPr)-Pr-i-Pr-i(2)) and 1,3-cyclohexadiene gave (eta(5)-cyclohexadienyl)Fe((Pr2PC2H4PPr2)-Pr-i-Pr-i)H.