5-isopropyl-2-(p-methoxyphenyl)-1,3-benzoxaphosphole | 1220997-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-isopropyl-2-(p-methoxyphenyl)-1,3-benzoxaphosphole
• 英文别名: 2-(4-Methoxyphenyl)-5-propan-2-yl-1,3-benzoxaphosphole；2-(4-methoxyphenyl)-5-propan-2-yl-1,3-benzoxaphosphole
• CAS: 1220997-27-2
• 化学式: C₁₇H₁₇O₂P
• 分子量: 284.295
• InChiKey: JTOSRCKCFVHXLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  22.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-isopropyl-2-phosphinophenol 、 N-(4-methoxyphenyl)benzimidoyl chloride 以 四氢呋喃 为溶剂， 反应 36.0h， 以60%的产率得到5-isopropyl-2-(p-methoxyphenyl)-1,3-benzoxaphosphole
  参考文献：
  名称：

  Phosphorus Can Also Be a “Photocopy”

  摘要：

  The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P=C p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus "photocopy" the properties of other conjugated organic molecules.

  DOI：

  10.1021/ja1009426

文献信息

• Phosphorus Can Also Be a “Photocopy”
  作者：Marlena P. Washington、Vittal B. Gudimetla、Feng L. Laughlin、Nihal Deligonul、Susan He、John L. Payton、M. Cather Simpson、John D. Protasiewicz

  DOI：10.1021/ja1009426

  日期：2010.4.7

  The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P=C p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus "photocopy" the properties of other conjugated organic molecules.