2-mercapto-2'-nitrobiphenyl | 99970-05-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-mercapto-2'-nitrobiphenyl
• 英文别名: 2-(2-Nitrophenyl)benzenethiol
• CAS: 99970-05-5
• 化学式: C₁₂H₉NO₂S
• 分子量: 231.275
• InChiKey: IZOBEKKYDQMJCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-碘茴香硫醚 在 Amberlyst 15 、 氯 、 铜 作用下， 以 甲醇 、 四氯化碳 为溶剂， 反应 17.0h， 生成 2-mercapto-2'-nitrobiphenyl
  参考文献：
  名称：

  Cylisation reactions of 2-substituted biphenyl-2′-yldiazonium salts leading to O-alkyldibenzofuranium and S-alkyl-dibenzothiophenium salts: modified meerwein reagents

  摘要：

  The preparation of 2-amino-2'-methoxybiphenyl and 2-amino-2-thiomethoxybiphenyl and analogues and their transformation into diazonium salts and hence into dibenzofuranium and dibenzothiophenium salts is described together with their use as alkylating agents.

  DOI：

  10.1016/s0040-4020(01)88480-5

文献信息

• [EN] METHODS FOR PRODUCING ARYLSULFUR PENTAFLUORIDES<br/>[FR] PROCÉDÉS DE PRODUCTION DE PENTAFLUORURES DE SOUFRE ARYLÉS
  申请人：IM & T RES INC

  公开号：WO2010014665A1

  公开（公告）日：2010-02-04

  Novel methods for preparing arylsulfur pentafluorides are disclosed. Arylsulfur halotetrafluoride is reacted with a fluoride source under hydrous conditions to form an arylsulfur pentafluoride. The purification method is also disclosed.

  揭示了制备芳基硫五氟化物的新方法。芳基硫卤四氟化物在湿润条件下与氟化物源反应，形成芳基硫五氟化物。还公开了纯化方法。
• PROCESS FOR PRODUCING ARYLSULFUR PENTAFLUORIDES
  申请人：UMEMOTO TERUO

  公开号：US20080234520A1

  公开（公告）日：2008-09-25

  Novel processes for preparing arylsulfur pentafluorides are disclosed. Processes include reacting at least one aryl sulfur compound with a halogen and a fluoro salt to form an arylsulfur halotetrafluoride. The arylsulfur halotetrafluoride is reacted with a fluoride source to form a target arylsulfur pentafluoride.

  揭示了制备芳基硫五氟化物的新工艺。该工艺包括将至少一种芳基硫化合物与卤素和氟盐反应，形成芳基硫卤四氟化物。然后将芳基硫卤四氟化物与氟化物源反应，形成目标芳基硫五氟化物。
• [EN] CARBOXYLIC DITHIOCARBAMIC ACID ANHYDRIDE COMPOUNDS AND COMPOSITIONS THEREOF<br/>[FR] COMPOSÉS D'ANHYDRIDE D'ACIDE DITHIOCARBAMIQUE CARBOXYLIQUE ET COMPOSITIONS DE CEUX-CI
  申请人：FUNDACIO INSTITUT CATALA DINVESTIGACIO QUIM ICIQ

  公开号：WO2021144395A1

  公开（公告）日：2021-07-22

  The present invention relates to certain carboxylic dithiocarbamic acid anhydride compounds compounds and their use as photoinitiators in living free-radical polymerization reactions. The invention also relates to curable or cross-linkable compositions comprising the carboxylic dithiocarbamic acid anhydride compounds of the invention.

  本发明涉及某些羧基二硫代氨基甲酸酐化合物以及它们在活性自由基聚合反应中作为光引发剂的用途。该发明还涉及包括本发明的羧基二硫代氨基甲酸酐化合物的可固化或可交联组合物。
• A method of producing alkali metal benzenesulfinates
  申请人：SEITETSU KAGAKU CO. LTD.

  公开号：EP0256486A1

  公开（公告）日：1988-02-24

  A method of producing alkali metal benzenesulfinates having the general formula of wherein M represents Na or K, which comprises: reacting nitrophenylphenyl sulfones having the general formula of wherein n is an integer of 1 or 2, with alkali metal thiophenolates having the general formula of in solvents. The reaction produces also nitrophenylphenyl sulfides as by-products in equimolar amounts to the alkali metal benzenesulfinates, and the oxidation of the sulfides provides the starting nitrophenylphenyl sulfones. A method of producing the nitrophenylphenyl sulfones is also provided wherein the sulfides are oxidized with hydrogen peroxide in the presence both of water-soluble tungstates or molybdates and of phase transfer catalysts in a two-phase heterogeneous solvent.

  一种生产通式为 其中 M 代表 Na 或 K 的碱金属苯磺酸盐的方法，包括：通式为 其中 n 为 1 或 2 的整数的硝基苯基砜与通式为 的碱金属噻吩酚酸盐在溶剂中反应。 反应还产生与碱金属苯磺酸盐等摩尔量的硝基苯基硫化物作为副产物，硫化物的氧化提供了起始的硝基苯基砜。 还提供了一种生产硝基苯基砜的方法，其中硫化物在水溶性钨酸盐或钼酸盐以及相转移催化剂的存在下，在两相异质溶剂中用过氧化氢氧化。
• Process for producing arylsulfur halotetrafluorides
  申请人：UBE Industries, Ltd.

  公开号：EP2468722A1

  公开（公告）日：2012-06-27

  Novel processes for preparing arylsulfur pentafluorides are disclosed. Processes include reacting at least one aryl sulfur compound with a halogen and a fluoro salt to form an arylsufur halotetrafluoride. The arylsulfur halotetrafluoride is reacted with a fluoride source to form a target arylsulfur pentafluoride.

  本发明公开了制备芳基五氟化硫的新工艺。该工艺包括将至少一种芳基硫化合物与卤素和氟盐反应生成芳基硫卤四氟化物。该芳基四氟化硫与氟化源反应生成目标芳基五氟化硫。