methacrylic acid-(4-isothiocyanato-phenyl ester) | 68448-63-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: methacrylic acid-(4-isothiocyanato-phenyl ester)
• 英文别名: Methacrylsaeure-(4-isothiocyanato-phenylester)；(4-Isothiocyanatophenyl) 2-methylprop-2-enoate
• CAS: 68448-63-5
• 化学式: C₁₁H₉NO₂S
• 分子量: 219.264
• InChiKey: ABWSSZSBBABDGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  70.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  methacrylic acid-(4-isothiocyanato-phenyl ester) 、 氨 以83%的产率得到
  参考文献：
  名称：

  BARBA, N. A.;VLAD, V. P.;VLAD, L. A., METALLXELATY I IX SVOJSTVA: VOPR. XIMII I XIM. TEXNOL., KISHINEV, 1985, 7+

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基丙烯酸酐 、 4-异硫氰酸基-苯酚 生成 methacrylic acid-(4-isothiocyanato-phenyl ester)
  参考文献：
  名称：

  Unsaturated esters of hydroxy isothiocyanates

  摘要：

  公开号：

  US02866804A1

文献信息

• RESIN AND SURFACE PROTECTION PLATE OR AUTOMOTIVE MATERIAL
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：EP3327052A1

  公开（公告）日：2018-05-30

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.

  本发明提供了一种树脂，该树脂包括衍生自末端具有碳碳双键的单体的结构单元和衍生自聚二十六烷化合物的结构单元，其中聚二十六烷化合物是被(甲基)丙烯酰基或含有(甲基)丙烯酰基的基团取代的化合物，聚二十六烷包括任选取代的环糊精、呈串状凝集在任选取代的环糊精中的线性分子以及用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状凝集在任选取代的环糊精中的线性分子的末端、和用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状包覆在任选取代的环糊精中的线性分子的末端，且呈串状包覆在任选取代的环糊精中的线性分子的重量平均分子量大于或等于 21000，小于或等于 500000。
• Resin and surface protective plate or automotive material
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US10647784B2

  公开（公告）日：2020-05-12

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.

  本发明提供了一种树脂，该树脂包括衍生自末端具有碳碳双键的单体的结构单元和衍生自聚二十六烷化合物的结构单元，其中聚二十六烷化合物是被(甲基)丙烯酰基或含有(甲基)丙烯酰基的基团取代的化合物，聚二十六烷包括任选取代的环糊精、呈串状凝集在任选取代的环糊精中的线性分子以及用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状凝集在任选取代的环糊精中的线性分子的末端、和用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状包覆在任选取代的环糊精中的线性分子的末端，且呈串状包覆在任选取代的环糊精中的线性分子的重量平均分子量大于或等于 21000，小于或等于 500000。
• RESIN AND SURFACE PROTECTIVE PLATE OR AUTOMOTIVE MATERIAL
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20180215837A1

  公开（公告）日：2018-08-02

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.
• US4914159A
  申请人：——

  公开号：US4914159A

  公开（公告）日：1990-04-03
• US4937000A
  申请人：——

  公开号：US4937000A

  公开（公告）日：1990-06-26