2,3,4,5-Tetrachlorobenzolthiol | 4706-91-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 2,3,4,5-Tetrachlorobenzolthiol
• 英文别名: 2,3,4,6-Tetrachlor-thiophenol；2,3,4,5-Tetrachlorthiophenol；2,3,4,5-Tetrachlorothiophenol；2,3,4,5-tetrachlorobenzenethiol
• CAS: 4706-91-6
• 化学式: C₆H₂Cl₄S
• 分子量: 247.96
• InChiKey: RQRZJGHZAPYDCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,3,4,5-Tetrachlorobenzolthiol 、 重氮甲烷 生成 2,3,4,5-tetrachlorothioanisole
  参考文献：
  名称：

  SCHWARTZ, H.;CHU, I.;VILLENEUVE, D. C.;BENOIT, F. M., CHEMOSPHERE, 16,(1987) N 10-12, 2467-2478

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2,3,4-四氯-5-氟苯 在 吡啶 、 sodium hydrogensulfide 作用下， 生成 2,3,4,5-Tetrachlorobenzolthiol
  参考文献：
  名称：

  Kobrina,L.S.; Yakobson,G.G., Journal of general chemistry of the USSR, 1965, vol. 35, p. 2046 - 2052

  摘要：

  DOI：

文献信息

• Compositions for use in golf balls
  申请人：Bulpett A. David

  公开号：US20050245652A1

  公开（公告）日：2005-11-03

  A golf ball comprises a core, an outer cover layer, and, optionally, an intermediate layer disposed between the core and the outer cover layer. The outer cover layer may comprise a polyurethane or polyurea composition. At least one portion of the golf ball comprises a composition that enhances physical properties and/or performance characteristics (e.g., coefficient of restitution) of the golf ball. Preferably, the coefficient of restitution of the core is 0.8 or greater.

  高尔夫球由内核、外覆盖层和可选的中间层组成，外覆盖层可以包括聚氨酯或聚脲组成。高尔夫球的至少一部分包含一种增强物理特性和/或性能特征（例如反弹系数）的组合物。最好，内核的反弹系数为0.8或更高。
• COMPOSITIONS FOR USE IN GOLF BALLS
  申请人：Bulpett David A.

  公开号：US20080261722A1

  公开（公告）日：2008-10-23

  A golf ball including a core and at least one cover layer disposed about the core, wherein the core or the cover layer is formed from a composition comprising a base polymer, a crosslink initiator, and at least one additive comprising phenothiazine or a perhaloalkyl additive having a structure of: where R 1 or R 5 are —SZ, at least one of R 1 to R 5 is a perhaloalkyl, perhalocycloalkyl, or perhaloaryl substituent; the remainder of R 1 to R 5 are the same or different organic substituents or hydrogen; Z is a non-metal cation comprising quaternary ammonium, quaternary pyridinium, quaternary quinolinium, (organo)phosphonium, (organo)sulfonium, (organo)oxonium, (organo)iodonium, or (organo)azonium; and n is an integer of 1 or greater.

  一颗高尔夫球，包括一个核心和至少一层覆盖层，其中核心或覆盖层是由包含基础聚合物、交联引发剂和至少一种添加剂的组成物形成的，该添加剂包括苯并噻吩或具有以下结构的卤代烷基添加剂：其中R1或R5是—SZ，R1到R5中至少有一个是卤代烷基、卤代环烷基或卤代芳基取代基；R1到R5的其余部分是相同或不同的有机取代基或氢原子；Z是非金属阳离子，包括季铵盐、季吡啶盐、季喹啉盐、（有机）磷盐、（有机）硫盐、（有机）氧盐、（有机）碘盐或（有机）偶氮盐；n是大于等于1的整数。
• Compositions for Use in Golf Balls
  申请人：Bulpett David A.

  公开号：US20080176678A1

  公开（公告）日：2008-07-24

  A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core or the layer is formed from a composition comprising a base polymer, a crosslink initiator, and an additive comprising an aromatic iodonium compound or an aromatic iodonium salt.

  一颗高尔夫球包括一个核心和至少一层沿核心排列的材料，其中核心或层中的至少一个是由包含基础聚合物、交联引发剂和添加剂的组合物形成的，该添加剂包括芳香碘化物或芳香碘化盐。
• A process for preparing a polyarylene thioether
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0281036A2

  公开（公告）日：1988-09-07

  A process for preparing a polyarylene thioether, which comprises polymerizing a thiophenol having the formula (I) and/or a diphenyldisulfide having the formula (II) wherein R are substituents selected from the group consisting of hydrogen atoms, lower alkyl groups, halogen atoms and lower alkoxy, the groups R may be different from or identical with each other, in the presence of a Lewis acid as a catalyst.

  一种制备聚芳基硫醚的工艺，包括在路易斯酸作为催化剂的存在下，聚合具有式（I）的噻吩酚和/或具有式（II）的二苯基二硫醚，其中 R 是选自氢原子、低级烷基、卤素原子和低级烷氧基组成的组的取代基，基团 R 可以彼此不同或相同。
• Multi-layer cover golf ball having a high acid casing layer
  申请人：Acushnet Company

  公开号：US10029151B2

  公开（公告）日：2018-07-24

  A golf ball includes a single core having an outer surface and a geometric center. The core is formed from a substantially homogenous rubber composition. An inner cover layer is disposed about the core, the inner cover including a high-acid ionomer and having a material hardness of about 66 to 75 Shore D. The high-acid ionomer has an acid content of about 16% or greater. An outer cover layer is disposed about the inner cover layer, the outer cover including a polyurethane and having a material hardness of about 38 Shore D to about 56 Shore D. The core surface hardness is from 0 Shore C to 15 Shore C lower than the geometric center hardness to define a hardness gradient.

  高尔夫球包括一个具有外表面和几何中心的球芯。球芯由基本均匀的橡胶成分形成。内包层围绕球芯设置，内包层包括高酸离子聚合物，材料硬度约为 66 至 75 邵氏硬度 D，高酸离子聚合物的酸含量约为 16% 或更高。核心表面硬度比几何中心硬度低 0 至 15 肖氏硬度，从而形成硬度梯度。