2,3,5,5-Tetraphenyl-isoxazolidin | 25116-92-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,5,5-Tetraphenyl-isoxazolidin
• 英文别名: 2,3,5,5-Tetraphenyl-1,2-oxazolidine
• CAS: 25116-92-1
• 化学式: C₂₇H₂₃NO
• 分子量: 377.486
• InChiKey: LRQOELVRXRSPHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3,5,5-tetraphenyl-2-isoxazolinium tetrafluoroborate 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 生成 2,3,5,5-Tetraphenyl-isoxazolidin
  参考文献：
  名称：

  通过 1,1,2,2-四取代环丙烷与 NOBF4 反应形成 2-取代 2-异恶唑啉盐

  摘要：

  1,1,2,2-四苯基-和1-甲基-1,2,2-三苯基环丙烷与NOBF4反应，通过苯基从3-苯基-2-迁移得到2-苯基-2-异恶唑啉鎓四氟硼酸盐异恶唑啉鎓或 1-异恶唑啉鎓中间体。

  DOI：

  10.1246/cl.1989.457

文献信息

• Addition polymer composition containing isoxazolidine compounds
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0767203A1

  公开（公告）日：1997-04-09

  A resin composition is provided containing a resin (preferably a thermoplastic resin) and an isoxazolidine. The composition exhibits enhanced melt stability and colour stability. The composition is useful for making thermoplastic articles such as extruded sheet and film. Preferably the thermoplastic resin is a polyolefin such as polypropylene. A method for stabilizing thermoplastic polymers is also provided.

  一种树脂组合物含有一种树脂（最好是热塑性树脂）和一种异噁唑烷。该组合物具有更强的熔融稳定性和颜色稳定性。该组合物可用于制造挤出板材和薄膜等热塑性物品。热塑性树脂最好是聚烯烃，如聚丙烯。还提供了一种稳定热塑性聚合物的方法。
• Insertion of nitrogen oxide and nitrosonium ion into the cyclopropane ring: a new route to 2-isoxazolines and its mechanistic studies
  作者：Kazuhiko Mizuno、Nobuyuki Ichinose、Toshiyuki Tamai、Yoshio Otsuji

  DOI：10.1021/jo00043a026

  日期：1992.8

  The 9,10-dicyanoanthracene (DCA)-sensitized photoreaction of 1,2-diarylcyclopropanes 1a-d in nitrogen oxide (NO)-saturated CH3CN afforded 3,5-diaryl-2-isoxazolines 2a-d in excellent yields. The reaction of 1a-d with NOBF4 or with a mixture of NO and O2 in CH3CN also afforded 2a-d or 2a-b. These reactions proceed via the attack of NO on the radical cation of 1, which is formed by electron transfer from 1 to 1DCA* or NO+. The reaction of 1-alkyl-2-arylcyclopropanes with NOBF4 afforded mixtures of 3-alkyl-5-aryl-2-isoxazolines and 4-alkyl-5-aryl-2-isoxazolines via the direct attack of NO+ on the cyclopropane rings. The reaction of 1,1,2,2-tetraphenylcyclopropane with NOBF4 afforded 2,3,5,5-tetraphenyl-2-isoxazolinium tetrafluoroborate via the migration of the phenyl group to nitrogen.
• Cum,G. et al., Gazzetta Chimica Italiana, 1968, vol. 98, p. 782 - 794
  作者：Cum,G. et al.

  DOI：——

  日期：——
• ICHINOSE, NOBUYUKI;MIZUNO, KAZUHIKO;OTSUJI, YOSHIO, CHEM. LETT.,(1989) N, C. 457-458
  作者：ICHINOSE, NOBUYUKI、MIZUNO, KAZUHIKO、OTSUJI, YOSHIO

  DOI：——

  日期：——
• JPH09176372A
  申请人：——

  公开号：JPH09176372A

  公开（公告）日：1997-07-08