2,10-di-tert-butyl-dipyrido[1,2-c:2',1'-e]imidazolium-6-carboxylate | 1449571-33-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,10-di-tert-butyl-dipyrido[1,2-c:2',1'-e]imidazolium-6-carboxylate
• 英文别名: 4,12-Ditert-butyl-9-aza-7-azoniatricyclo[7.4.0.02,7]trideca-1,3,5,7,10,12-hexaene-8-carboxylate；4,12-ditert-butyl-9-aza-7-azoniatricyclo[7.4.0.02,7]trideca-1,3,5,7,10,12-hexaene-8-carboxylate
• CAS: 1449571-33-8
• 化学式: C₂₀H₂₄N₂O₂
• 分子量: 324.423
• InChiKey: KUFLTPNFXAHUPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  48.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二氧化碳 、 2,10-di-tert butyldipyrido[1,2-c:2',1'-e]imidazolium tetrafluoroborate 以 乙腈 为溶剂， 以84%的产率得到2,10-di-tert-butyl-dipyrido[1,2-c:2',1'-e]imidazolium-6-carboxylate
  参考文献：
  名称：

  Electrosynthesis of Imidazolium Carboxylates

  摘要：

  Synthesis of imidazolium carboxylate compounds was efficiently achieved by electrochemical reduction of imidazolium precursors under very mild conditions.

  DOI：

  10.1021/ol401949f

文献信息

• Synthesis and use of biobased imidazolium carboxylates
  申请人：Université de Bourgogne

  公开号：EP2963155A1

  公开（公告）日：2016-01-06

  The present invention relates to a new method for preparation of biobased imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenooxalate. The present invention also relates to uses of imidazolium hydrogenooxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II):

  本发明涉及一种制备生物基咪唑鎓盐及其衍生物的新方法，特别是制备咪唑鎓草酸盐的新方法。本发明还涉及咪唑鎓草酸盐的用途，特别是作为咪唑鎓羧酸盐化合物的前体。本发明还涉及一种提供咪唑鎓化合物，特别是咪唑鎓羧酸盐化合物的绿色电化学工艺。特别是，本发明涉及一种单室电化学电池及其在制备式（II）咪唑鎓羧酸盐化合物中的应用：
• SYNTHESIS AND USE OF BIO-BASED IMIDAZOLIUM CARBOXYLATES
  申请人：Université de Bourgogne

  公开号：EP3164527A1

  公开（公告）日：2017-05-10
• SYNTHESIS AND USE OF BIOBASED IMIDAZOLIUM CARBOXYLATES
  申请人：UNIVERSITÉ DE BOURGOGNE

  公开号：US20160002796A1

  公开（公告）日：2016-01-07

  The present invention relates to a new method for preparation of biobased imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenooxalate. The present invention also relates to uses of imidazolium hydrogenooxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II):
• US9863048B2
  申请人：——

  公开号：US9863048B2

  公开（公告）日：2018-01-09
• [EN] SYNTHESIS AND USE OF BIO-BASED IMIDAZOLIUM CARBOXYLATES<br/>[FR] SYNTHÈSE ET UTILISATION DE CARBOXYLATES D'IMIDAZOLIUM À BASE BIOLOGIQUE
  申请人：UNIVERSITÉ DE BOURGOGNE

  公开号：WO2016001436A1

  公开（公告）日：2016-01-07

  The present invention relates to a new method for preparation of bio-based imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenoxalate. The present invention also relates to uses of imidazolium hydrogenoxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II).