S-((2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl) 4,4,5,5,6,6,7,7,7-nonafluoroheptanethioate | 1333236-76-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: S-((2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl) 4,4,5,5,6,6,7,7,7-nonafluoroheptanethioate
• 英文别名: 4,4,5,5,6,6,7,7,7-Nonafluoroheptanethioic acid S-(5,6-dihydro-2-thia-4-oxa-7-thia-2H-indene-6-ylmethyl) ester；S-(2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-ylmethyl) 4,4,5,5,6,6,7,7,7-nonafluoroheptanethioate
• CAS: 1333236-76-2
• 化学式: C₁₄H₁₁F₉O₂S₃
• 分子量: 478.424
• InChiKey: QAJUKSAUTQBVOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  (2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)methanethiol 、 4,4,5,5,6,6,7,7,7-九氟庚酸 在 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.5h， 以35%的产率得到S-((2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl) 4,4,5,5,6,6,7,7,7-nonafluoroheptanethioate
  参考文献：
  名称：

  Superhydrophobic Fiber Mats by Electrodeposition of Fluorinated Poly(3,4-ethyleneoxythiathiophene)

  摘要：

  The control of surface morphology and wettability is crucial in the development of superhydrophobic surfaces, which implies new strategy and molecular design. In this Article, we report the synthesis, characterization, and electrochemical properties of original 3,4-ethyleneoxythiathiophenes (EOTT) as platform molecules and its derivatives bearing a semifluorinated chain of various length (F-octyl, F-hexyl, F-butyl, and F-ethyl). We report the influence of the fluorinated chain length as well as the presence of sulfur atoms in the monomer on the surface construction and nonwetting properties of the corresponding electrodeposited polymer films. Surprisingly, these films exhibit the possibility to obtain extremely long polymer fibers with a possible control of their length by a careful choice in the monomer structure. We show that the presence of sulfur atoms in the monomer structure seems to be necessary to modulate the formation of extremely long polymer fibers by aggregation of smaller polymer fibrils. In this Article, the formation of superhydrophobic material (contact angle above 150 degrees) for four, six, and eight fluoromethylene units but also highly hydrophobic surfaces (contact angle above 125 degrees) from extremely short chains (two fluoromethylene units) is also demonstrated.

  DOI：

  10.1021/ja205283b

文献信息

• SUPEROLEOPHOBIC AND/OR SUPERHYDROPHOBIC MATERIAL, PROCESS FOR PREPARING SAME AND APPLICATIONS THEREOF
  申请人：UNIVERSITE NICE SOPHIA ANTIPOLIS

  公开号：US20160096845A1

  公开（公告）日：2016-04-07

  The invention relates to a multilayer superoleophobic and/or superhydrophobic material comprising: on the one hand, a first constituent that is a conductive substrate or a substrate that has previously been rendered conductive (1): the surface of which is modified by chemical and/or physical treatment (2) and that incorporates a first adhesion-promoting conductive layer (3); or that incorporates a first adhesion-promoting conductive layer (3); and, on the other hand, at least one other constituent that is a superoleophobic and/or superhydrophobic polymer or copolymer layer (4, 5 or 6) composed of one or more monomers based on an aromatic or heteroaromatic ring substituted by one or more fluorocarbon and/or hydrocarbon chains. It is characterized in that the various constituents of said material comply with an increasing hydrophobicity gradient between the first layer deposited on the conductive substrate or substrate previously rendered conductive (1) and the last layer of said material.

  该发明涉及一种多层超疏水和/或超疏油材料，包括：一方面，第一组分是导电基底或已经被处理为导电的基底（1）：其表面经过化学和/或物理处理（2）并且包含第一粘附促进导电层（3）；或者包含第一粘附促进导电层（3）；另一方面，至少另一组分是由一个或多个以芳香或杂芳环为基础的单体构成的超疏水和/或超疏油聚合物或共聚物层（4、5或6），这些单体被一个或多个氟碳和/或烃链取代。其特征在于所述材料的各组分在导电基底或先前被处理为导电的基底（1）上沉积的第一层与所述材料的最后一层之间遵守逐渐增加的疏水性梯度。
• MATERIAU SUPEROLEOPHOBE ET/OU SUPERHYDROPHOBE, SON PROCEDE DE PREPARATION ET SES APPLICATIONS
  申请人：CNRS (Centre National de la Recherche Scientifique)

  公开号：EP2999703B1

  公开（公告）日：2018-10-24
• US9981982B2
  申请人：——

  公开号：US9981982B2

  公开（公告）日：2018-05-29
• Superhydrophobic Fiber Mats by Electrodeposition of Fluorinated Poly(3,4-ethyleneoxythiathiophene)
  作者：Thierry Darmanin、Frédéric Guittard

  DOI：10.1021/ja205283b

  日期：2011.10.5

  The control of surface morphology and wettability is crucial in the development of superhydrophobic surfaces, which implies new strategy and molecular design. In this Article, we report the synthesis, characterization, and electrochemical properties of original 3,4-ethyleneoxythiathiophenes (EOTT) as platform molecules and its derivatives bearing a semifluorinated chain of various length (F-octyl, F-hexyl, F-butyl, and F-ethyl). We report the influence of the fluorinated chain length as well as the presence of sulfur atoms in the monomer on the surface construction and nonwetting properties of the corresponding electrodeposited polymer films. Surprisingly, these films exhibit the possibility to obtain extremely long polymer fibers with a possible control of their length by a careful choice in the monomer structure. We show that the presence of sulfur atoms in the monomer structure seems to be necessary to modulate the formation of extremely long polymer fibers by aggregation of smaller polymer fibrils. In this Article, the formation of superhydrophobic material (contact angle above 150 degrees) for four, six, and eight fluoromethylene units but also highly hydrophobic surfaces (contact angle above 125 degrees) from extremely short chains (two fluoromethylene units) is also demonstrated.