1-Fluoro-9,10-bis(phenylethynyl)anthracene | 53134-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Fluoro-9,10-bis(phenylethynyl)anthracene
• 英文别名: 1-fluoro-9,10-bis(2-phenylethynyl)anthracene
• CAS: 53134-89-7
• 化学式: C₃₀H₁₇F
• 分子量: 396.5
• InChiKey: YCKSJJIBZGMBEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Novel N,N'-bis(trifluoromethylsulfonyl)oxamides, chemiluminescent compositions containing them and processes for generating chemiluminescence employing said compositions
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0010844A1

  公开（公告）日：1980-05-14

  Novel N,N'-bis(trifluoromethylsulfonyl)oxamides of the formula (I) wherein R and R' have the meaning given in the description (preferably chlorinated phenyl or pyridyl, nitrophenyl or methoxyethyl), when used in compositions comprising also an organic fluorescer such as 1-chloro-9,10-bis(phe- nylethynyl)-anthracene and a diluent such as dibutyl phthalate, will furnish chemiluminescent light with good light intensity and quantum efficiency upon reaction with a peroxide component such as hydrogen peroxide. The preparation of the compounds of the formula (I) is described; e.g. the particulary preferred compound N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis-trifluoromethylsulfonyl)-oxamide is prepared on the following way:

  新颖的 N,N'-双(三氟甲基磺酰基)草酰胺，其式为(I) 其中 R 和 R'具有说明中给出的含义（最好是氯化苯基或吡啶基、硝基苯基或甲氧基乙基），当用于包含以下成分的组合物中时 当与过氧化物成分（如过氧化氢）反应时，将产生光强度和量子效率良好的化学发光。例如，N,N'-双（2,4,5-三氯苯基）-N,N'-双三氟甲基磺酰基）-氧酰胺的制备方法如下：
• Enhanced aqueous chemiluminescent systems
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0096749A1

  公开（公告）日：1983-12-28

  Aqueous chemiluminescent systems are found to have improved chemiluminescence due to presence of surfactants in minor amounts.

  水性化学发光体系由于含有少量的表面活性剂，其化学发光效果有所改善。
• Use of water-soluble polymers in aqueous chemical light formulations
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0175889A1

  公开（公告）日：1986-04-02

  Aqueous chemiluminescent systems have been found to exhibit improved chemiluminescence due to the presence of minor amounts of a water-soluble polymer.

  研究发现，水性化学发光体系由于含有少量水溶性聚合物，其化学发光性能有所改善。
• Novel N,N'-bis(trifluoromethylsulfonyl)oxamides and chemiluminescent compositions containing the same
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0089487B1

  公开（公告）日：1987-06-16
• US4076645A
  申请人：——

  公开号：US4076645A

  公开（公告）日：1978-02-28