1,4-Dibenzoyl-2,3-dioxybenzol | 31709-42-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-Dibenzoyl-2,3-dioxybenzol
• 英文别名: 3,6-dibenzoylcatechol；3,6-dibenzoyl-pyrocatechol；3,6-Dibenzoyl-brenzcatechin；(4-Benzoyl-2,3-dihydroxyphenyl)-phenylmethanone
• CAS: 31709-42-9
• 化学式: C₂₀H₁₄O₄
• 分子量: 318.329
• InChiKey: HQZFRHAFDUAAFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-Dibenzoyl-2,3-dioxybenzol 在 羟胺 作用下， 生成 3,6-bis-(α-hydroxyimino-benzyl)-pyrocatechol
  参考文献：
  名称：

  Über Orthobenzotetraphenyldifurfuran

  摘要：

  DOI：

  10.1007/bf00897809
• 作为产物：
  描述：

  2,3-bis(benzoyloxy)-1,4-dibenzoylbenzene 在 硫酸 作用下， 生成 1,4-Dibenzoyl-2,3-dioxybenzol
  参考文献：
  名称：

  Reversible−Irreversible Approach to Schiff Base Macrocycles:  Access to Isomeric Macrocycles with Multiple Salphen Pockets

  摘要：

  We have developed methodology for the formation of a new family of metal-free Schiff base macrocycles utilizing the differential exchange rates of aldimines and ketimines. The more robust ketimine bond is kinetically inert under the milder conditions used for aldimine bond formation. In particular, this route enables access to the first conjugated macrocycles with four unsymmetrical N2O2 salphen-like pockets.

  DOI：

  10.1021/ol8001317

文献信息

• PROCESS FOR PREPARING POLYETHER ETHER KETONE MEMBRANE
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0796649A1

  公开（公告）日：1997-09-24

  The present invention is directed to a process for manufacturing a polyether ether ketone (PEEK) membrane which may be used for ultrafiltration or microfiltration at high temperatures. In this process for manufacturing a non-sulfonated PEEK membrane which comprises dissolving PEEK in a solvent to obtain a membrane forming stock solution, forming the stock solution into a desired shape and bringing the formed stock solution in contact with a coagulating liquid capable of coagulating PEEK, the key features involve using concentrated sulfuric acid as the solvent, dissolving PEEK therein to prepare the stock solution and keeping the stock solution at 15 degrees C or lower until initiation of membrane formation.

  本发明涉及一种聚醚醚酮（PEEK）膜的制造工艺，该膜可用于高温下的超滤或微滤。 在这种制造非磺化聚醚醚酮膜的工艺中，包括将聚醚醚酮溶解在溶剂中以获得膜形成的储备溶液，将储备溶液形成所需的形状，并使形成的储备溶液与能够使聚醚醚酮凝固的凝固液接触，其主要特征包括使用浓硫酸作为溶剂，在其中溶解聚醚醚酮以制备储备溶液，并将储备溶液保持在 15 摄氏度或更低的温度下，直到开始形成膜。
• �ber Orthobenzotetraphenyldifurfuran
  作者：O. Dischendorfer、W. Limontschew

  DOI：10.1007/bf00898374

  日期：——
• Reversible−Irreversible Approach to Schiff Base Macrocycles:  Access to Isomeric Macrocycles with Multiple Salphen Pockets
  作者：Peter D. Frischmann、Jian Jiang、Joseph K.-H. Hui、Joseph J. Grzybowski、Mark J. MacLachlan

  DOI：10.1021/ol8001317

  日期：2008.3.1

  We have developed methodology for the formation of a new family of metal-free Schiff base macrocycles utilizing the differential exchange rates of aldimines and ketimines. The more robust ketimine bond is kinetically inert under the milder conditions used for aldimine bond formation. In particular, this route enables access to the first conjugated macrocycles with four unsymmetrical N2O2 salphen-like pockets.
• Über Orthobenzotetraphenyldifurfuran
  作者：W. Limontschew、E. Wiesenberger

  DOI：10.1007/bf00897809

  日期：1952.1