(2R)-2-[2-[(2R)-oxolan-2-yl]propan-2-yl]oxolane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: (2R)-2-[2-[(2R)-oxolan-2-yl]propan-2-yl]oxolane
• 化学式: C₁₁H₂₀O₂
• 分子量: 184.27
• InChiKey: FZLHAQMQWDDWFI-NXEZZACHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Chelate-controlled diastereoselective hydrogenation with heterogeneous catalyst
  申请人：THOMAS SWAN & CO. LTD

  公开号：US10000460B2

  公开（公告）日：2018-06-19

  A hydrogenation catalyst, preferably palladium on a support, preferably alumina or activated charcoal support, is used in the presence of lithium salts, with salts such as the borates being preferred. This provides hydrogenation of precursors to give rise to a stereoselective, such as diastereoselective bias in the product of alkene hydrogenation using the catalyst.

  在锂盐存在的情况下，使用氢化催化剂，最好是载体（最好是氧化铝或活性炭载体）上的钯，硼酸盐等盐是首选。这样就可以对前体进行氢化，使使用该催化剂的烯氢化产物具有立体选择性，如非对映选择性。
• CHELATE-CONTROLLED DIASTEREOSELECTIVE HYDROGENATION WITH HETEROGENEOUS CATALYST
  申请人：Thomas Swan and Co. Ltd.

  公开号：EP3134203B1

  公开（公告）日：2018-04-04
• METHOD OF EPOXIDATION
  申请人：University of Durham

  公开号：US20220177693A1

  公开（公告）日：2022-06-09

  The present invention concerns block and/or tapered block copolymers comprising pendant hydrocarbyl, trisubstituted epoxide-containing moieties, and methods of preparing these and their precursors. The invention also concerns curable compositions comprising such copolymers as modified solution styrene butadiene rubbers and silica and/or carbon black and articles formed from curing these formulations. Such articles may be tyres.
• US9751848B2
  申请人：——

  公开号：US9751848B2

  公开（公告）日：2017-09-05
• [EN] CHELATE-CONTROLLED DIASTEREOSELECTIVE HYDROGENATION WITH HETEROGENEOUS CATALYST<br/>[FR] HYDROGÉNATION DIASTÉRÉOSÉLECTIVE COMMANDÉE PAR UN CHÉLATE AVEC CATALYSEUR HÉTÉROGÈNE
  申请人：SWAN THOMAS & CO LTD

  公开号：WO2016046575A1

  公开（公告）日：2016-03-31

  A catalyst,method of using, and use of a hydrogenation catalyst, preferably palladium on a support, preferably alumina or activated charcoal support. This in the presence of lithium salts, with salts such as theborates being preferred. This provides hydrogenation of precursors to give rise to a stereoselective, such as diastereoselectivebias in the product of alkene hydrogenation using the catalyst. This equation, using the preferred substrate, best illustratesthe invention: