2-methylpyrido[1,2-c]imidazolium-3-carboxylate | 1449571-32-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: 2-methylpyrido[1,2-c]imidazolium-3-carboxylate
• 英文别名: 2-Methylimidazo[1,5-a]pyridin-2-ium-3-carboxylate；2-methylimidazo[1,5-a]pyridin-2-ium-3-carboxylate
• CAS: 1449571-32-7
• 化学式: C₉H₈N₂O₂
• 分子量: 176.175
• InChiKey: XJVQFCCMKXTKEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  48.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  咪唑并[1,5-a]吡啶 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 2-methylpyrido[1,2-c]imidazolium-3-carboxylate
  参考文献：
  名称：

  Electrosynthesis of Imidazolium Carboxylates

  摘要：

  Synthesis of imidazolium carboxylate compounds was efficiently achieved by electrochemical reduction of imidazolium precursors under very mild conditions.

  DOI：

  10.1021/ol401949f

文献信息

• Synthesis and use of biobased imidazolium carboxylates
  申请人：Université de Bourgogne

  公开号：EP2963155A1

  公开（公告）日：2016-01-06

  The present invention relates to a new method for preparation of biobased imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenooxalate. The present invention also relates to uses of imidazolium hydrogenooxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II):

  本发明涉及一种制备生物基咪唑鎓盐及其衍生物的新方法，特别是制备咪唑鎓草酸盐的新方法。本发明还涉及咪唑鎓草酸盐的用途，特别是作为咪唑鎓羧酸盐化合物的前体。本发明还涉及一种提供咪唑鎓化合物，特别是咪唑鎓羧酸盐化合物的绿色电化学工艺。特别是，本发明涉及一种单室电化学电池及其在制备式（II）咪唑鎓羧酸盐化合物中的应用：
• SYNTHESIS AND USE OF BIO-BASED IMIDAZOLIUM CARBOXYLATES
  申请人：Université de Bourgogne

  公开号：EP3164527A1

  公开（公告）日：2017-05-10
• SYNTHESIS AND USE OF BIOBASED IMIDAZOLIUM CARBOXYLATES
  申请人：UNIVERSITÉ DE BOURGOGNE

  公开号：US20160002796A1

  公开（公告）日：2016-01-07

  The present invention relates to a new method for preparation of biobased imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenooxalate. The present invention also relates to uses of imidazolium hydrogenooxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II):
• US9863048B2
  申请人：——

  公开号：US9863048B2

  公开（公告）日：2018-01-09
• [EN] SYNTHESIS AND USE OF BIO-BASED IMIDAZOLIUM CARBOXYLATES<br/>[FR] SYNTHÈSE ET UTILISATION DE CARBOXYLATES D'IMIDAZOLIUM À BASE BIOLOGIQUE
  申请人：UNIVERSITÉ DE BOURGOGNE

  公开号：WO2016001436A1

  公开（公告）日：2016-01-07

  The present invention relates to a new method for preparation of bio-based imidazolium salts and derivatives thereof; in particular, for the preparation of imidazolium hydrogenoxalate. The present invention also relates to uses of imidazolium hydrogenoxalate salts, especially as a precursor of imidazolium carboxylate compounds. The present invention also refers to a green electrochemical process providing imidazolium compounds, especially imidazolium carboxylate compounds. Especially, the invention refers to a one-compartment electrochemical cell and its use for the preparation of imidazolium carboxylate compounds of formula (II).