Phenyl-ONN-azoxyphenylketon | 56751-21-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-ONN-azoxyphenylketon
• 英文别名: Benzoylimino-oxido-phenylazanium
• CAS: 56751-21-4
• 化学式: C₁₃H₁₀N₂O₂
• 分子量: 226.235
• InChiKey: RXFUPNKMPLVQGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (1Z)-2-((hydroxyimino)(phenyl)methyl)-1-phenyldiazene oxide 在 dinitrogen tetraoxide 作用下， 以 1,2-二氯乙烷 为溶剂， 以53%的产率得到Phenyl-ONN-azoxyphenylketon
  参考文献：
  名称：

  Aryl-ONN-azoxy-?,?-dinitroalkanes and some of their derivatives

  摘要：

  Previously unknown N'-dinitroalkyl-NNO-azoxybenzenes have been prepared (by nitration of N'-(alpha-hydroximino)alkyl-NNO-azoxybenzenes) and transformed to some derivatives.

  DOI：

  10.1007/bf00696317

文献信息

• Synthesis of Azoxy Compounds: from Copper Compounds to Mesoporous Silica‐Encaged Ultrasmall Copper Catalysts
  作者：Zhi‐Peng Han、Shiqi Wang、Qiming Sun、Xiao‐Ping Xu、Shun‐Jun Ji

  DOI：10.1002/cssc.202300477

  日期：2023.9.8

  A series of azoxy compounds were constructed via coupling reactions by using cost-effective N-methoxyformamide and nitroso compounds over Cu-based catalysts. The mesoporous silica nanosphere-encapsulated ultra-small Cu (Cu@MSN) catalyst was developed and exhibited remarkably enhanced catalytic activity and superior recycling stability.

  使用经济高效的N-甲氧基甲酰胺和亚硝基化合物在铜基催化剂上通过偶联反应构建了一系列氧化偶氮化合物。开发了介孔二氧化硅纳米球封装的超小铜（Cu@MSN）催化剂，并表现出显着增强的催化活性和优异的循环稳定性。
• Aryl-ONN-azoxy-?,?-dinitroalkanes and some of their derivatives
  作者：Yu. B. Salamonov、O. A. Luk'yanov、A. G. Bass、Yu. A. Strelenko

  DOI：10.1007/bf00696317

  日期：1994.11

  Previously unknown N'-dinitroalkyl-NNO-azoxybenzenes have been prepared (by nitration of N'-(alpha-hydroximino)alkyl-NNO-azoxybenzenes) and transformed to some derivatives.