SHIMAO, ICHIRO, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1985, N 8, 1556-1559
作者:SHIMAO, ICHIRO
DOI:——
日期:——
Synthesis of Unsymmetrical Azoxyarenes via Copper‐Catalyzed Aerobic Oxidative Dehydrogenative Coupling of Anilines with Nitrosoarenes
作者:Chongyang Shi、Boxia Xu、Xiaolan Fang、Xiaochun Yu、Huile Jin、Shun Wang
DOI:10.1002/adsc.202001526
日期:2021.3.29
A copper‐catalyzed oxidative dehydrogenativecoupling of nitrosobenzenes with anilines for the synthesis of unsymmetrical azoxybenzenes was developed. This approach uses O2 as the oxidant. The reaction products are diverse unsymmetrical azoxybenzenes rather than azobenzenes, which are obtained in the Mills reaction. The use of an inexpensive copper catalyst, a broad substrate scope, and mild reaction