N,N'-二(9-菲基)-N,N'-二苯基联苯胺 | 182507-83-1

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N'-二(9-菲基)-N,N'-二苯基联苯胺
• 中文别名: N,N’-双(菲-9-基)-N,N’-二苯基联苯胺；N,N'-双(菲-9-基)-N,N'-二苯基联苯胺
• 英文名称: N,N'-Bis(phenanthren-9-YL)-N,N'-diphenylbenzidine
• 英文别名: N-[4-[4-(N-phenanthren-9-ylanilino)phenyl]phenyl]-N-phenylphenanthren-9-amine
• CAS: 182507-83-1
• 化学式: C₅₂H₃₆N₂
• 分子量: 688.9
• InChiKey: LBFXFIPIIMAZPK-UHFFFAOYSA-N

物化性质

• 熔点：
  293 °C
• 密度：
  1.244±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  15
• 重原子数：
  54
• 可旋转键数：
  7
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• COMPOUND, LIGHT EMITTING MATERIAL, AND ORGANIC LIGHT EMITTING ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP2808323A1

  公开（公告）日：2014-12-03

  A compound represented by the general formula (1) is useful as a light-emitting material. In the general formula (1), Ar1 to Ar3 represent an aryl group, provided that at least one thereof represents an aryl group substituted by a group represented by the general formula (2). In the general formula (2), R1 to R8 represent a hydrogen atom or a substituent; Z represents O, S, O=C or Ar4-N; and Ar4 represents an aryl group.

  通式（1）所代表的化合物作为发光材料是有用的。在通式（1）中，Ar1至Ar3代表芳基，前提是其中至少一个代表被通式（2）所代表的基团取代的芳基。在通式（2）中，R1至R8代表氢原子或取代基；Z代表O、S、O=C或Ar4-N；Ar4代表芳基。
• Organometallic Complex, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using the Organometallic Complex
  申请人：Inoue Hideko

  公开号：US20080312437A1

  公开（公告）日：2008-12-18

  According to the present invention, a wider variation of organometallic complexes that can emit phosphorescence can be provided by applying, as a ligand, an organic compound from which a variety of derivatives can be easily synthesized. In particular, an organometallic complex having a sharp emission spectrum is provided. Further, an organometallic complex having high emission efficiency is provided. An organometallic complex represented by the general formula (G1) is provided. In the formula, Ar represents an aryl group, R represents an alkoxy group having 1 to 4 carbon atoms, and R 1 and R 2 individually represent either hydrogen or an alkyl group having 1 to 4 carbon atoms.

  根据本发明，通过应用一种作为配体的有机化合物，可以提供更广泛的能够发射磷光的有机金属配合物变体，从而可以轻松合成各种衍生物。特别地，提供了具有尖锐发射光谱的有机金属配合物。此外，提供了具有高发射效率的有机金属配合物。提供了由通式（G1）表示的有机金属配合物。在该式中，Ar代表芳基，R代表具有1至4个碳原子的烷氧基，R1和R2分别表示氢或具有1至4个碳原子的烷基。
• SUBSTITUTED CARBAZOLE DERIVATIVES AND USE THEREOF IN ORGANIC ELECTRONICS
  申请人：Langer Nicolle

  公开号：US20110266528A1

  公开（公告）日：2011-11-03

  An organic light-emitting diode, organic solar cell or switching element comprising at least one substituted carbazole derivative of the general formula (I), (II) or (III) in which X is NR 4 , O, S or PR 4 ; Y is NR 5 , O, S or PR 5 ; where at least one of the symbols X and Y is NR 4 or NR 5 ; substituted carbazole derivatives of the formula (I), (II) or (III); a light-emitting layer comprising at least one substituted carbazole derivative of the general formula (I), (II) or (III) and at least one emitter material; the use of substituted carbazole derivatives of the general formula (I), (II) or (Ill) as matrix material, hole/exciton blocker material and/or electron/exciton blocker material and/or hole injection material and/or electron injection material and/or hole conductor material and/or electron conductor material in an organic light-emitting diode, an organic solar cell or in a switching element, and a device selected from the group consisting of stationary visual display units, mobile visual display units, illumination units, keyboards, garments, furniture and wallpaper comprising at least one inventive organic light-emitting diode.

  一种有机发光二极管、有机太阳能电池或开关元件，包括至少一种通式（I）、（II）或（III）的取代咔唑衍生物，其中X为NR4、O、S或PR4；Y为NR5、O、S或PR5；其中至少一个符号X和Y为NR4或NR5；通式（I）、（II）或（III）的取代咔唑衍生物；包括至少一种通式（I）、（II）或（III）的取代咔唑衍生物和至少一种发射材料的发光层；使用通式（I）、（II）或（III）的取代咔唑衍生物作为基质材料、空穴/激子阻挡材料和/或电子/激子阻挡材料和/或空穴注入材料和/或电子注入材料和/或空穴导体材料和/或电子导体材料在有机发光二极管、有机太阳能电池或开关元件中的使用，以及选自固定视觉显示单元、移动视觉显示单元、照明单元、键盘、服装、家具和包括至少一种创新有机发光二极管的壁纸的设备。
• PHOSPHORESCENT METAL COMPLEX COMPOUND, METHOD FOR THE PRODUCTION THEREOF AND RADIATION EMITTING STRUCTURAL ELEMENT
  申请人：De Cola Luisa

  公开号：US20120169213A1

  公开（公告）日：2012-07-05

  A phosphorescent metal complex may include at least one metallic central atom M; and at least one ligand coordinated by the metallic central atom, wherein one ligand is bidentate with two uncharged coordination sites and comprises at least one carbene unit coordinated directly to the metal atom.

  一种磷光金属配合物可能包括至少一个金属中心原子M；以及至少一个由金属中心原子配位的配体，其中一个配体是双齿的，具有两个未带电的配位位点，并且包括至少一个卡宾基直接配位到金属原子。
• AROMATIC AMINE DERIVATIVES AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20070029927A1

  公开（公告）日：2007-02-08

  An aromatic amine derivative with a specific structure and an organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. The organic electroluminescence device which exhibits an enhanced current efficiency of light emission and emits blue light with a prolonged lifetime is realized.

  一种具有特定结构的芳香胺衍生物和一种有机电致发光器件，该器件至少包括一个有机薄膜层，其中包括夹在由阳极和阴极组成的一对电极之间的发光层，其中至少一个有机薄膜层包括该芳香胺衍生物单独或作为其混合组分。实现了一种具有增强的发光电流效率并且发出蓝光并具有延长寿命的有机电致发光器件。