n-Hexyl-maleinsaeureanhydrid | 90926-71-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氢呋喃
• 英文名称: n-Hexyl-maleinsaeureanhydrid
• 英文别名: hexyl-maleic acid anhydride；3-Hexylfuran-2,5-dione
• CAS: 90926-71-9
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: LTFYGVVALJIFTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  n-Hexyl-maleinsaeureanhydrid 在 溴 、 吡啶 作用下， 以 氯仿 为溶剂， 反应 1.83h， 生成 3-bromo-4-hexylmaleic anhydride
  参考文献：
  名称：

  Structure–activity relationship of brominated 3-alkyl-5-methylene-2(5H)-furanones and alkylmaleic anhydrides as inhibitors of Salmonella biofilm formation and quorum sensing regulated bioluminescence in Vibrio harveyi

  摘要：

  A library of 25 10-unsubstituted and 10-bromo or 10-acetoxy 3-alkyl-5-methylene-2(5H)-furanones and two 3-alkylmaleic anhydrides was synthesized using existing and new methods. This library was tested for the antagonistic effect against the biofilm formation by Salmonella Typhimurium and the quorum sensing regulated bioluminescence of Vibrio harveyi. The length of the 3-alkyl chain and the bromination pattern of the ring structure were found to have a major effect on the biological activity of the 10-unsubstituted furanones. Remarkably, the introduction of a bromine atom on the 10 position of the 3-alkyl chain did drastically enhance the activity of the furanones in both biological test systems. The introduction of an acetoxy function in this position did in general not improve the activity. Finally, the potential of the (bromo) alkylmaleic anhydrides as a new and chemically easily accessible class of biofilm and quorum sensing inhibitors was demonstrated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2010.05.055
• 作为产物：
  描述：

  1-辛炔 、 二氧化碳 、 一氧化碳 在 水 、 potassium iodide 、 palladium(II) iodide 作用下， 以 1,4-二氧六环 为溶剂， 80.0 ℃ 、6.18 MPa 条件下， 反应 40.0h， 生成 n-Hexyl-maleinsaeureanhydrid
  参考文献：
  名称：

  Structure–activity relationship of brominated 3-alkyl-5-methylene-2(5H)-furanones and alkylmaleic anhydrides as inhibitors of Salmonella biofilm formation and quorum sensing regulated bioluminescence in Vibrio harveyi

  摘要：

  A library of 25 10-unsubstituted and 10-bromo or 10-acetoxy 3-alkyl-5-methylene-2(5H)-furanones and two 3-alkylmaleic anhydrides was synthesized using existing and new methods. This library was tested for the antagonistic effect against the biofilm formation by Salmonella Typhimurium and the quorum sensing regulated bioluminescence of Vibrio harveyi. The length of the 3-alkyl chain and the bromination pattern of the ring structure were found to have a major effect on the biological activity of the 10-unsubstituted furanones. Remarkably, the introduction of a bromine atom on the 10 position of the 3-alkyl chain did drastically enhance the activity of the furanones in both biological test systems. The introduction of an acetoxy function in this position did in general not improve the activity. Finally, the potential of the (bromo) alkylmaleic anhydrides as a new and chemically easily accessible class of biofilm and quorum sensing inhibitors was demonstrated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2010.05.055

文献信息

• Liquid polyester
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0687698A2

  公开（公告）日：1995-12-20

  A liquid polyester obtainable by reacting a cyclic acid anhydride (A) comprising at least 10 mol% of one of specific alkyl or alkenyl substituted cyclic acid anhydrides with an epoxy compound (B) in a molar ratio of (A):(B) of 10:8 - 10:12, optionally in the presence of a dry or semi-dry partially saponified fat and oil having a saponification ratio of 5 to 90%. The liquid polyesters contain preferably ethylenical unsaturation and may be used in film-forming materials.

  一种液态聚酯，可通过使环酸酐（A）与环氧化合物（B）反应而获得，环酸酐（A）包含至少 10 摩尔%的特定烷基或烯基取代的环酸酐，（A）：（B）的摩尔比为 10:8 - 10:12，可选择在皂化率为 5 - 90% 的干或半干部分皂化油脂存在下进行反应。液态聚酯最好含有不饱和乙烯，可用于成膜材料。
• COMPOSITE RESIN AND USE THEREOF
  申请人：TOYO INK MFG. CO., LTD.

  公开号：EP1375558A1

  公开（公告）日：2004-01-02

  This invention discloses a composite resin prepared by reacting a monool (a) containing a C25-200 hydrocarbon group; a multifunctional compound (G) containing a functional group capable of reacting with a hydroxyl group of the monool (a); and a compound (H) having a functional group capable of reacting with the functional group in the multifunctional compound (G) , as well as uses thereof. The composite resin of the invention serves as an excellent interface modifier upon incorporation into a film-coating material such as ink or paint or into a molding material. The modifier can modify not only the interface between the film-forming material or the like and abase material but also the surf ace of the film-formingmaterial, that is, the interface between the film-forming material and the air.

  本发明公开了一种由含有 C25-200 碳氢基团的一元醇 (a)、含有能与一元醇 (a) 的羟基反应的官能团的多功能化合物 (G) 和具有能与多功能化合物 (G) 中的官能团反应的官能团的化合物 (H) 反应制备而成的复合树脂及其用途。本发明的复合树脂在加入油墨或涂料等涂膜材料或模塑材料中后，可作为极佳的界面改性剂。改性剂不仅可以改变成膜材料或类似材料与基底材料之间的界面，还可以改变成膜材料的表面，即成膜材料与空气之间的界面。
• Separator for rechargeable battery and rechargeable lithium battery including the same
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10707467B2

  公开（公告）日：2020-07-07

  A separator for a rechargeable battery includes a porous substrate and an adhesive layer on at least one surface thereof. The adhesive layer includes a first binder, a second binder, and a filler. The first binder includes a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene. The structural unit derived from hexafluoropropylene is included in an amount of about 10 wt % or less based on a total weight of the first binder. A weight average molecular weight of the first binder ranges from about 800,000 to about 1,500,000. The second binder includes a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene. The structural unit derived from hexafluoropropylene is included in an amount of 10 wt % or less based on a total weight of the second binder. A weight average molecular weight of the second binder is 600,000 or less.

  一种用于充电电池的隔膜包括多孔基材及其至少一个表面上的粘合剂层。粘合剂层包括第一粘合剂、第二粘合剂和填料。第一粘合剂包括源自偏氟乙烯的结构单元和源自六氟丙烯的结构单元。衍生自六氟丙烯的结构单元的含量约为第一粘合剂总重量的 10%或更少。第一粘合剂的重量平均分子量在约 800,000 到约 1,500,000 之间。第二粘合剂包括一个源自偏氟乙烯的结构单元和一个源自六氟丙烯的结构单元。衍生自六氟丙烯的结构单元的含量为第二粘合剂总重量的 10%或更少。第二粘合剂的重量平均分子量为 600,000 或更低。
• Coatings with wax-modified hyperbranched and flexible hyperbranched polyols
  申请人：BASF COATINGS GMBH

  公开号：US10689541B2

  公开（公告）日：2020-06-23

  Wax-modified hyperbranched polyols and wax-modified flexible hyperbranched polyols are described, as are coating compositions containing these polyols. These polyols provide excellent coatings, especially matte coatings, and allow for the exclusion of silica in coatings.

  介绍了蜡改性超支化多元醇和蜡改性柔性超支化多元醇，以及含有这些多元醇的涂料组合物。这些多元醇可提供出色的涂料，尤其是哑光涂料，并可在涂料中排除二氧化硅。
• Coatings with flexible hyperbranched polyols
  申请人：BASF Coatings GmbH

  公开号：US10883013B2

  公开（公告）日：2021-01-05

  A coating composition includes a flexible hyperbranched polyol preparable by (a) reacting a polyol comprising at least three hydroxyl groups with an aliphatic dicarboxylic acid having from 6 to 36 carbon atoms or an esterifiable derivative of the aliphatic dicarboxylic acid to form a hydroxyl-functional first intermediate product; (b) reacting the first intermediate product with a cyclic carboxylic acid anhydride to form a carboxylic acid-functional second intermediate product; and (c) reacting the second intermediate product with an epoxide-functional compound having one epoxide group to form the hyperbranched polyol. The coating composition may be cured to a coating layer having excellent flexibility.

  一种涂料组合物包括一种柔性超支化多元醇，可通过以下方法制备：(a) 使包含至少三个羟基的多元醇与具有 6 至 36 个碳原子的脂肪族二羧酸或脂肪族二羧酸的可酯化衍生物反应，形成羟基官能团的第一中间产物；(b) 将第一中间产物与环状羧酸酐反应，形成羧酸官能团第二中间产物；以及 (c) 将第二中间产物与具有一个环氧化物基团的环氧化物官能团化合物反应，形成超支化多元醇。涂层组合物可固化成具有优异柔韧性的涂层。