N,N'-二苯基丙烷-1,2-二胺 | 15717-40-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N'-二苯基丙烷-1,2-二胺
• 英文名称: 1,2-Di-(phenylamino)-propane
• 英文别名: 1,2-dianilinopropane；1,2-bis-(phenylamino)propane；(+/-)-1-methyl-N¹,N²-diphenyl-ethanediyldiamine; (+/-)-N,N'-diphenyl-propylenediamine；(+/-)-1-methyl-N¹,N²-diphenyl-ethanediyldiamine；(+/-)-1-Methyl-N¹,N²-diphenyl-aethandiyldiamin；(+/-)-1-Methyl-N¹,N²-diphenyl-aethandiyldiamin; (+/-)-N,N'-Diphenyl-propylendiamin；N,N'-Diphenylpropane-1,2-diamine；1-N,2-N-diphenylpropane-1,2-diamine
• CAS: 15717-40-5
• 化学式: C₁₅H₁₈N₂
• 分子量: 226.321
• InChiKey: BBRHQNMMUUMVDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  N,N'-二苯基丙烷-1,2-二胺 在 D(+)-10-樟脑磺酸 、 (1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-ylmethanesulfonate 作用下， 生成 1-methyl-N¹,N²-diphenyl-ethanediyldiamine
  参考文献：
  名称：

  Kipping; Pope, Journal of the Chemical Society, 1924, vol. 125, p. 2398

  摘要：

  DOI：
• 作为产物：
  描述：

  3-氯丙烯 以29%的产率得到
  参考文献：
  名称：

  MAGERRAMOV, M. N.;XALILOVA, R. A.;LYUTFALIEV, A. G.;GUSIEV, N. X., VINITI 5765-83

  摘要：

  DOI：

文献信息

• 4-Formyl amino-n-methylpiperidine derivatives, the use thereof as stabilisers and organic material stabilised therewith
  申请人：——

  公开号：US20030083406A1

  公开（公告）日：2003-05-01

  The present invention relates to 4-formylamino-N-methylpiperidine derivatives of the formula (I) 1 where the variables are as defined in the Description, to a process for preparing these piperidine derivatives, to the use of these piperidine derivatives of the invention, or prepared according to the invention, for stabilizing organic material, in particular for stabilizing plastics or coating materials, and also to the use of these piperidine derivatives of the invention, or prepared according to the invention, as light stabilizers or stabilizers for wood surfaces. The present invention further relates to stabilized organic material which comprises these piperidine derivatives of the invention or prepared according to the invention.

  本发明涉及通式(I)的4-甲酰氨基-N-甲基哌啶衍生物 1 其中变量如说明书中所定义，涉及制备这些哌啶衍生物的方法，涉及这些本发明的哌啶衍生物或按照本发明制备的哌啶衍生物用于稳定有机材料，特别是用于稳定塑料或涂料材料，还涉及这些本发明的哌啶衍生物或按照本发明制备的哌啶衍生物作为光稳定剂或木材表面的稳定剂的使用。 本发明还涉及包含这些本发明的哌啶衍生物或按照本发明制备的哌啶衍生物的稳定有机材料。
• Thioimidazolidine derivatives as light stabilizers for polymers
  申请人：——

  公开号：US20030109609A1

  公开（公告）日：2003-06-12

  A compound of the formula (I) wherein G 1 , G 2 , G 3 and G 4 are independently of one another C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl or the radicals G 1 and G 2 and the radicals G 3 and G 4 form independently of one another, together with the carbon atom they are attached to, C 5 -C 12 cycloalkyl; R is hydrogen, C 1 -C 18 alkyl, oxyl, —OH, —CH 2 CN, C 3 -C 6 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 phenylalkyl unsubstituted or substituted on the phenyl radical by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; C 1 -C 8 acyl, C 1 -C 18 alkoxy, C 1 -C 18 hydroxyalkoxy, C 2 -C 18 alkenyloxy, C 5 -C 12 cycloalkoxy, C 7 -C 12 phenylalkoxy unsubstituted or substituted on the phenyl radical by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy: C 1 -C 18 alkanoyloxy, (C 1 -C 18 alkoxy)carbonyl, glycidyl or a group —CH 2 CH(OH)(G) with G being hydrogen, methyl or phenyl; n is 1, 2, 3 or 4; and X is an organic radical of a valency equal to n; and when n is 2, 3 or 4, each of the radicals G 1 , G 2 , G 3 , G 4 and R can have the same or a different meaning in the units of the formula (II), is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.

  式（I）的化合物，其中G1、G2、G3和G4彼此独立地是C1-C18烷基或C5-C12环烷基，或者基团G1和G2以及基团G3和G4彼此独立地与它们附着的碳原子一起形成C5-C12环烷基；R是氢、C1-C18烷基、氧基、—OH、—CH2CN、C3-C6烯基、C3-C8炔基、C7-C12苯基烷基，未取代或通过C1-C4烷基和/或C1-C4烷氧基取代苯基上的苯基基团；C1-C8酰基、C1-C18烷氧基、C1-C18羟基烷氧基、C2-C18烯氧基、C5-C12环烷氧基，未取代或通过C1-C4烷基和/或C1-C4烷氧基取代苯基上的C7-C12苯基氧基；C1-C18烷酰氧基、（C1-C18烷氧基）羰基、环氧乙基或一个基团—CH2CH(OH)(G)，其中G是氢、甲基或苯基；n为1、2、3或4；X是价数等于n的有机基团；当n为2、3或4时，式（II）的各单元中的G1、G2、G3、G4和R的每一个可以具有相同或不同的含义，对于抵抗光、热或氧化引起的有机材料降解具有稳定作用。
• Imidazolidinone derivatives
  申请人：——

  公开号：US20030073835A1

  公开（公告）日：2003-04-17

  A compound of the formula (IA) or (IB) 1 wherein G 1 , G 2 , G 3 and G 4 are independently of one another C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl or the radicals G 1 and G 2 and the radicals G 3 and G 4 form independently of one another, together with the carbon atom they are attached to, C 5 -C 12 cycloalkyl; R is hydrogen C 1 -C 18 alkyl, C 1 -C 18 hydroxyalkyl, C 2 -C 18 alkenyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl unsubstituted or substituted on the phenyl radical by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; or C 1 -C 18 alkanoyl; R* is hydrogen, C 1 -C 18 alkyl, oxyl, —OH, —CH 2 CN, C 3 -C 6 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 phenylalkyl unsubstituted or substituted on the phenyl radical by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; C 1 -C 8 acyl, C 1 -C 18 alkoxy, C 1 -C 18 hydroxyalkoxy, C 2 -C 18 alkenyloxy, C 5 -C 12 cycloalkoxy, C 7 -C 12 phenylalkoxy unsubstituted or substituted on the phenyl radical by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy; C 1 -C 18 alkanoyloxy, (C 1 -C 18 alkoxy)carbonyl, glycidyl or a group —CH 2 CH(OH)(G) with G being hydrogen, methyl or phenyl; n is 1, 2, 3 or 4; n* is 1, 2 or 3; X is an organic radical of a valency equal to n; and X* is a triazinic radical with a valency equal to n*; with the proviso that when n is 1, R is methyl, ethyl, propyl, C 1 -C 18 hydroxyalkyl, C 2 -C 18 alkenyl, C 5 -C 12 cycloalkyl or C 1 -C 18 alkanoyl. The compounds described above are useful for stabilizing an organic material against degradation induced by light, heat or oxidation.

  式（IA）或（IB）的化合物 其中 G 1 ，G 2 ，G 3 和G 4 分别独立地为C 1 -C 18 烷基或C 5 -C 12 环烷基，或基团G 1 和G 2 以及基团G 3 和G 4 独立地形成，与它们连接的碳原子一起，为C 5 -C 12 环烷基； R为氢C 1 -C 18 烷基，C 1 -C 18 羟基烷基，C 2 -C 18 烯基，C 5 -C 12 环烷基，C 7 -C 12 苯基烷基未取代或通过C 1 -C 4 烷基和/或C 1 -C 4 烷氧基取代苯基上的苯基基团；或C 1 -C 18 酰基； R*为氢，C 1 -C 18 烷基，氧基，—OH，—CH 2 CN，C 3 -C 6 烯基，C 3 -C 8 炔基，C 7 -C 12 苯基烷基未取代或通过C 1 -C 4 烷基和/或C 1 -C 4 烷氧基取代苯基上的苯基基团；C 1 -C 8 酰基，C 1 -C 18 烷氧基，C 1 -C 18 羟基烷氧基，C 2 -C 18 烯氧基，C 5 -C 12 环烷氧基，C 7 -C 12 苯基烷氧基未取代或通过C 1 -C 4 烷基和/或C 1 -C 4 烷氧基取代苯基上的苯基基团；C 1 -C 18 酰氧基，（C 1 -C 18 烷氧基）羰基，环氧乙烷或一个基团—CH 2 CH(OH)(G)，其中G为氢，甲基或苯基； n为1、2、3或 4； n*为1、2或3； X为价数等于n的有机基团；和 X*为价数等于n*的三嗪基团； 但是当n为1时，R为甲基、乙基、丙基、C 1 -C 18 羟基烷基、C 2 -C 18 烯基、C 5 -C 12 环烷基或C 1 -C 18 酰基。 上述描述的化合物对于稳定有机材料抵抗光、热或氧化引起的降解是有用的。
• [EN] WATER COMPATIBLE STERICALLY HINDERED ALKOXYAMINES AND HYDROXY SUBSTITUTED ALKOXYAMINES<br/>[FR] ALCOXYAMINES STERIQUEMENT ENCOMBREES ET ALCOXYAMINES HYDROXY SUBSTITUEES HYDROCOMPATIBLES
  申请人：CIBA SC HOLDING AG

  公开号：WO2004076419A1

  公开（公告）日：2004-09-10

  Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula where for example E and E’ are 2-hydroxycydohexyloxy, 2-hydroxy-2-methylpropoxy, benzyloxy, methoxy, propoxy, hexyloxy, heptyloxy, oclyloxy or cyclohexyloxy, Rx is for example -NH2+CH2CH20H Cl-, -NH3+ -OAc, =NOH, -NHCH(CH3)COO-K+,- NHCH2CH2NH(CH3)2+ -OAC, -NHCH2CH2SO3-K+, -NHCH(COO- K+)CH2CH2SCH3, -NHCH2COO- K+, -OCH(CH3)COO-K+, -OCH2CH2NH(CH3)2+ -OAC, -OCH2CH2SO3-K+, -OCH(COO- K+)CH2CH2SCH3 or -OCH2COO-K+, and where R5 comprises repeating units of -(OCH2CH2)-, -(OCH2CH2(CH3))-,-(CH2CHCOOH)-, -(CH2C(CH3)COOH)-, -(CH2CHCOOCH3)-, -(NHCH2CH2)-, -(CH2CHOH)-, -(CH2CHCONH2)-or -(CH2CH(NHCOH))-. These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous inkjet media and photocured aqueous systems.

  通过具有亲水性的特定骨架，使具有立体位阻的烷氧胺和羟基取代的烷氧胺稳定剂化合物与水相容。其中，立体位阻胺的示例为以下公式，其中 E 和 E’ 为 2-羟基环己氧基、2-羟基-2-甲基丙氧基、苄氧基、甲氧基、丙氧基、己氧基、庚氧基、辛氧基或环己氧基，Rx 为例如 -NH2+CH2CH20H Cl-, -NH3+ -OAc, =NOH, -NHCH(CH3)COO-K+,- NHCH2CH2NH(CH3)2+ -OAC, -NHCH2CH2SO3-K+, -NHCH(COO- K+)CH2CH2SCH3, -NHCH2COO- K+, -OCH(CH3)COO-K+, -OCH2CH2NH(CH3)2+ -OAC, -OCH2CH2SO3-K+, -OCH(COO- K+)CH2CH2SCH3 或 -OCH2COO-K+，R5 包括重复单元 -(OCH2CH2)-, -(OCH2CH2(CH3))-,-(CH2CHCOOH)-, -(CH2C(CH3)COOH)-, -(CH2CHCOOCH3)-, -(NHCH2CH2)-, -(CH2CHOH)-, -(CH2CHCONH2)- 或 -(CH2CH(NHCOH))-. 这些化合物在稳定水性聚合物体系抵抗氧化、热和光辐射的有害影响方面特别有效。这些化合物例如在稳定水性涂料、水性油墨、水性喷墨介质和光固化水性系统方面非常有效。
• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。