2-trifluoromethylthioxanthene sulfoxide | 135566-30-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻喃类
• 英文名称: 2-trifluoromethylthioxanthene sulfoxide
• 英文别名: 2-(trifluoromethyl)-9H-thioxanthene 10-oxide
• CAS: 135566-30-2
• 化学式: C₁₄H₉F₃OS
• 分子量: 282.286
• InChiKey: NHGADFPGFSVQOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-三氟甲基噻吨酮 在 硼烷 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 1.5h， 生成 2-trifluoromethylthioxanthene sulfoxide
  参考文献：
  名称：

  Mlotkowska, B. L.; Cushman, James A.; Harwood, J., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 3, p. 731 - 736

  摘要：

  DOI：

文献信息

• Photocurable composition and optical material
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10647819B2

  公开（公告）日：2020-05-12

  According to the present invention, it is possible to provide a photocurable composition which comprises a cyclic compound (a) represented by formula (1), an episulfide compound (b), and a photopolymerization initiator (c). In a preferred embodiment, the proportion of the cyclic compound (a) in the photocurable composition is 5-80 mass %, the proportion of the episulfide compound (b) is 20-95 mass %, and the proportion of the photopolymerization initiator (c) is 0.1-10 parts by mass per 100 parts by mass of the sum of the cyclic compound (a) and the episulfide compound (b). In the formula, C represents a carbon atom, X represents S, Se, or Te, and a to f are integers of 0-3, provided that 8≥(a+c+e)≥1, 8≥(b+d+f)≥2, and (b+d+f)≥(a+c+e).

  根据本发明，可以提供一种光固化组合物，该组合物包括由式（1）表示的环状化合物 （a）、环硫化合物（b）和光聚合引发剂（c）。在一个优选的实施方案中，环状化合物（a）在光固化组合物中的比例为 5-80 质量%，环硫化 合物（b）的比例为 20-95 质量%，光聚合引发剂（c）的比例为环状化合物（a）和环硫化 合物（b）之和每 100 质量份中占 0.1-10 质量份。式中，C 代表碳原子，X 代表 S、Se 或 Te，a 至 f 为 0-3 的整数，条件是 8≥(a+c+e)≥1，8≥(b+d+f)≥2，且 (b+d+f)≥(a+c+e)。
• Crosslinkable polymeric materials for dielectric layers in electronic devices
  申请人：ALTANA AG

  公开号：US11043643B2

  公开（公告）日：2021-06-22

  Compositions for providing a dielectric layer in an electronic device wherein the composition comprises a polymer which polymer contains one or more building blocks, wherein at least 25 mol % of the total number of building blocks in the polymer are of the general formula having olefinic oligo-dihydrodicyclopentadienyl functionalities.

  用于在电子设备中提供电介质层的组合物，其中组合物包含一种聚合物，该聚合物包含一种或多种构筑嵌段，其中聚合物中构筑嵌段总数的至少 25 摩尔%为具有烯烃低聚二氢双环戊二烯官能团的通式。
• CROSSLINKABEL POLYMERIC MATERIALS FOR DIELECTRIC LAYERS IN ELECTRONC Devices
  申请人：ALTANA AG

  公开号：EP3378109A1

  公开（公告）日：2018-09-26
• CURABLE COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160152774A1

  公开（公告）日：2016-06-02

  According to the present invention, a curable composition can be provided, said composition being characterized by comprising: (A) an episulfide compound; and (B) a photobase generator comprising an organoboron compound represented by general formula (1) below: (In general formula (1), R 1 , R 2 , R 3 , R 4 and R 5 may be the same as or different from one another and independently represent an alkyl group having 1 to 8 carbon atoms; and Ar 1 , Ar 2 and Ar 3 may be the same as or different from one another and independently represent a group selected from the group consisting of a phenyl group, a naphthyl group, an anthracenyl group and a phenanthryl group, each of which may have a substituent selected from the group consisting of an alkyl group, an aryl group, an alkenyl group, a cycloalkyl group and a heterocyclic group.)
• PHOTOCURABLE COMPOSITION AND OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20180265638A1

  公开（公告）日：2018-09-20

  According to the present invention, it is possible to provide a photocurable composition which comprises a cyclic compound (a) represented by formula (1), an episulfide compound (b), and a photopolymerization initiator (c). In a preferred embodiment, the proportion of the cyclic compound (a) in the photocurable composition is 5-80 mass %, the proportion of the episulfide compound (b) is 20-95 mass %, and the proportion of the photopolymerization initiator (c) is 0.1-10 parts by mass per 100 parts by mass of the sum of the cyclic compound (a) and the episulfide compound (b). In the formula, C represents a carbon atom, X represents S, Se, or Te, and a to f are integers of 0-3, provided that 8≥(a+c+e)≥1, 8≥(b+d+f)≥2, and (b+d+f)≥(a+c+e).