N,N,2,3,4,5,6-七氟苯胺 | 58749-37-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N,N,2,3,4,5,6-七氟苯胺
• 英文名称: Difluoraminopentafluor-benzol
• 英文别名: Perfluoranilin；Perfluoroaniline；N,N,2,3,4,5,6-heptafluoroaniline
• CAS: 58749-37-4
• 化学式: C₆F₇N
• 分子量: 219.062
• InChiKey: AWXHDJSWFBWERK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,3,4,5,6-五氟苯胺 、 fluorine 以 乙腈 为溶剂， 生成 N,N,2,3,4,5,6-七氟苯胺
  参考文献：
  名称：

  Fluorination of nitroaromatic amines in liquid hydrogen fluoride and acetonitrile

  摘要：

  DOI：

  10.1021/jo01268a019

文献信息

• Hydrogen Bond Directed Photocatalytic Hydrodefluorination and Methods of Use Thereof
  申请人：The Board of Regents for Oklahoma State University

  公开号：US20200399196A1

  公开（公告）日：2020-12-24

  Methods of synthesizing compounds comprising fluorinated aryl groups are disclosed, wherein said methods utilize hydrogen bond directed photocatalytic hydrodefluorination.

  揭示了合成含氟芳基化合物的方法，其中所述方法利用氢键定向的光催化脱氟化反应。
• COATING AGENTS AND COATED ARTICLES
  申请人：Wen Jie

  公开号：US20120258313A1

  公开（公告）日：2012-10-11

  The invention describes novel coating agents that include a polymer, one or more latent reactive groups and one or more noncovalent linking groups, the noncovalent linking groups selected to interact with a substrate to which the coating agent is applied. The coating agents are useful for providing a coating that can be further functionalized (for example, by application of additional coating layers), or for providing desirable properties to a surface.

  这项发明描述了一种新型的涂层剂，包括一个聚合物、一个或多个潜在的反应基团和一个或多个非共价连接基团，所述非共价连接基团被选择用于与涂层剂所施加的基底相互作用。这些涂层剂可用于提供可进一步功能化的涂层（例如，通过施加额外的涂层层），或为表面提供理想的特性。
• ORGANIC ELECTRONIC DEVICE COMPRISING AN INVERSE COORDINATION COMPLEX AND A METHOD FOR PREPARING THE SAME
  申请人：Novaled GmbH

  公开号：EP3503234A1

  公开（公告）日：2019-06-26

  The present invention relates to an organic electronic device comprising at least one inverse coordination complex, the inverse coordination complex comprising: (i) a core consisting of one atom or of a plurality of atoms forming together a covalent cluster; (ii) a first coordination sphere consisting of at least four electropositive atoms having each individually an electronegativity according to Allen of less than 2.4; and (iii) a second coordination sphere comprising a plurality of ligands; wherein the first coordination sphere is closer to the core than the second coordination sphere; and all atoms of the core have a higher electronegativity according to Allen than any of the electropositive atoms of the first coordination sphere and a method for preparing the same.

  本发明涉及一种由至少一个反配位配合物组成的有机电子器件，该反配位配合物包括：(i) 由一个原子或多个原子组成共价团簇的核心；(ii) 由至少四个电性原子组成的第一配位球，根据艾伦定律，每个原子的电负性均小于2.4；和(iii)由多个配位体组成的第二配位球；其中第一配位球比第二配位球更靠近核心；根据Allen，核心的所有原子的电负性高于第一配位球的任何电阳性原子，以及制备该配位球的方法。
• Coating agents and coated articles
  申请人：Innovative Surface Technologies, Inc.

  公开号：US10266620B2

  公开（公告）日：2019-04-23

  The invention describes novel coating agents that include a polymer, one or more latent reactive groups and one or more noncovalent linking groups, the noncovalent linking groups selected to interact with a substrate to which the coating agent is applied. The coating agents are useful for providing a coating that can be further functionalized (for example, by application of additional coating layers), or for providing desirable properties to a surface.

  本发明描述了新型涂层剂，它包括聚合物、一个或多个潜伏反应基团和一个或多个非共价连接基团，非共价连接基团经选择可与涂有涂层剂的基底相互作用。涂层剂可用于提供可进一步功能化的涂层（例如，通过应用额外的涂层），或为表面提供理想的特性。
• Active OLED display, method for preparing an active OLED display and compound
  申请人：Novaled GmbH

  公开号：US11201306B2

  公开（公告）日：2021-12-14

  The present invention relates to a display device comprising—a plurality of OLED pixels comprising at least two OLED pixels, the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers—is arranged between and in contact with the cathode and the anode, and—comprises a first electron transport layer, a first hole transport layer, and a first light emitting layer provided between the first hole transport layer and the first electron transport layer, and—a driving circuit configured to separately driving the pixels of the plurality of OLED pixels, wherein, for the plurality of OLED pixels, the first hole transport layer is provided in the stack of organic layers as a common hole transport layer shared by the plurality of OLED pixels, and the first hole transport layer comprises (i) at least one first hole transport matrix compound consisting of covalently bound atoms and (ii) at least one electrical p-dopant selected from metal salts and from electrically neutral metal complexes comprising a metal cation and at least one anion and/or at least one anionic ligand consisting of at least 4 covalently bound atoms, wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Mn, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (IV) or less, a method for preparing the display device and a chemical compound for use therein.

  本发明涉及一种显示装置，包括-多个 OLED 像素，该多个 OLED 像素包括至少两个 OLED 像素，该 OLED 像素包括阳极、阴极和有机层堆叠，其中有机层堆叠-布置在阴极和阳极之间并与阴极和阳极接触，并且-包括第一电子传输层、第一空穴传输层和设置在第一空穴传输层和第一电子传输层之间的第一发光层，以及-驱动电路，该驱动电路被配置为分别驱动多个 OLED 像素中的像素，其中、对于多个 OLED 像素，第一空穴传输层作为多个 OLED 像素共享的共用空穴传输层被设置在有机层堆叠中、第一空穴传输层包括：(i) 至少一种由共价结合原子组成的第一空穴传输基质化合物；(ii) 至少一种选自金属盐和电中性金属复合物的电 p-掺杂剂，电中性金属复合物包括金属阳离子和至少一种阴离子和/或至少一种由至少 4 个共价结合原子组成的阴离子配体，其中电 p-掺杂剂的金属阳离子选自碱金属碱土金属、Pb、Mn、Fe、Co、Ni、Zn、Cd；氧化态（II）或（III）的稀土金属；Al、Ga、In；以及氧化态（IV）或更低的Sn、Ti、Zr、Hf、V、Nb、Ta、Cr、Mo和W。