N,N,N,N-四苯基-9H-咔唑-2,7-二胺 | 945261-94-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N,N,N-四苯基-9H-咔唑-2,7-二胺
• 英文名称: 2,7-bis(diphenylamino)carbazole
• 英文别名: N,N,N',N'-Tetraphenyl-9H-carbazole-2,7-diamine；2-N,2-N,7-N,7-N-tetraphenyl-9H-carbazole-2,7-diamine
• CAS: 945261-94-9
• 化学式: C₃₆H₂₇N₃
• 分子量: 501.63
• InChiKey: MAAAZGDLRLAFTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,7-二溴咔唑 、 二苯胺 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 lithium hexamethyldisilazane 、 tri tert-butylphosphoniumtetrafluoroborate 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以98%的产率得到N,N,N,N-四苯基-9H-咔唑-2,7-二胺
  参考文献：
  名称：

  （ジアリールアミノ）カルバゾールの製造方法

  摘要：

  提供一种在一步中高度选择性和高效率地制备（ジアリールアミノ）卡巴唑的方法。将由通式（1）（其中，X表示卤原子，n表示1到4的整数）表示的卤代卡巴唑与钯化合物、由通式（4）（其中，R表示碳数为1到6的烷基；1-甲基-2,2-二苯基环丙基；1,1-二苯基-1-丙烯-2-基；或被二胺基取代的碳数为6到16的芳香族烃基）表示的膦化合物，在反应溶剂和碱存在下与二芳基胺发生反应。【选择图】无

  公开号：

  JP2019137613A

文献信息

• ORDINARY-TEMPERATURE-PHOSPHORESCENT ORGANIC MATERIAL, REVERSIBLY THERMOSENSITIVE RECORDING MATERIAL, REVERSIBLY THERMOSENSITIVE RECORDING MEDIUM, AND METHOD OF RECORDING IN REVERSIBLY THERMOSENSITIVE RECORDING MEDIUM
  申请人：Watanabe Toshiyuki

  公开号：US20100328412A1

  公开（公告）日：2010-12-30

  The present invention provides an organic material that is characterized by including a rigid matrix and a dye having a phosphorescence lifetime of 0.1 seconds or more in a rigid medium at 77 K and that exhibits such a strong and long-lived phosphorescence as to be recognizable with the naked eyes even at ordinary temperature: namely, an ordinary-temperature-phosphorescent organic material.
• ORGANIC LIGHT-EMITTING DIODE MATERIALS
  申请人：President and Fellows of Harvard College

  公开号：US20170244049A1

  公开（公告）日：2017-08-24

  Described herein are molecules for use in organic light emitting diodes. Example molecules comprise at least one acceptor moiety A, at least one donor moiety D, and optionally one or more bridge moieties B. Each moiety A is covalently attached to either the moiety B or the moiety D, each moiety D is covalently attached to either the moiety B or the moiety A, and each moiety B is covalently attached to at least one moiety A and at least one moiety D. Values and preferred values of moieties A, D, and B are defined herein.
• COMPOSITION OF MATTER FOR USE IN ORGANIC LIGHT-EMITTING DIODES
  申请人：Kyulux, Inc.

  公开号：US20190173017A1

  公开（公告）日：2019-06-06

  The present disclosure relates to compounds of Formula (I) as compounds capable of emitting delayed fluorescence, and uses of the compounds in organic light-emitting diodes.
• COMPOUNDS FOR ORGANIC LIGHT EMITTING DIODE MATERIALS
  申请人：President and Fellows of Harvard College

  公开号：US20200321533A1

  公开（公告）日：2020-10-08

  Described herein are molecules for use in organic light emitting diodes comprising at least one moiety A, at least one moiety D, and at least one moiety B.
• US8243113B2
  申请人：——

  公开号：US8243113B2

  公开（公告）日：2012-08-14