2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]hexafluoropropane | 94525-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]hexafluoropropane
• 英文别名: 4-[4-[2-[4-[4-amino-2-(trifluoromethyl)phenoxy]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]-3-(trifluoromethyl)aniline
• CAS: 94525-07-2
• 化学式: C₂₉H₁₈F₁₂N₂O₂
• 分子量: 654.455
• InChiKey: FQEHXKKHEIYTQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  45
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  马来酸酐 、 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]hexafluoropropane 以80%的产率得到
  参考文献：
  名称：

  MARUTA, TOSIMITI;FUKUI, AKIXIRO

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2-bis[4-(4-nitro-2-trifluoromethylphenoxy)-phenyl]1,1,1,3,3,3-hexafluoropropane 在 palladium 10% on activated carbon 、 氢气 作用下， 以 乙醇 为溶剂， 80.0 ℃ 、800.01 kPa 条件下， 反应 2.0h， 以98.9%的产率得到2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]hexafluoropropane
  参考文献：
  名称：

  芳香二醚二胺的制备方法

  摘要：

  本发明属于二胺单体合成技术领域，具体的涉及一种芳香二醚二胺的制备方法。将双酚AF、卤代硝基苯化合物和催化剂在溶剂中混合，进行成醚反应，得到芳香二醚二硝基化合物；将芳香二醚二硝基化合物以氢气为还原剂，在催化剂作用下进行还原反应，得到芳香二醚二胺。采用本发明所述的芳香二醚二胺的制备方法制备的二胺单体在不需要重结晶等提纯手段的前提下就可得到白色的二胺单体，为制备下游产品创造了更好的条件；制备得到的二胺的收率大于92％，纯度大于99％；采用氢气为还原剂，代替具有较强腐蚀性的水合肼，降低了还原反应对设备和工艺条件的要求。

  公开号：

  CN111039802A

文献信息

• NOVEL FLUORINE-CONTAINING DICARBOXYLIC ACIDS AND THEIR NOVEL POLYMER COMPOUNDS
  申请人：Narizuka Satoru

  公开号：US20090030173A1

  公开（公告）日：2009-01-29

  Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.

  本发明公开了一种含氟的二羧酸，其化学式表示为（1），其中n表示1-4的整数，两个羧基不相邻于芳环上。通过将含氟二羧酸与共聚单体（例如，二氨基二醇）反应，可以获得线性聚合物化合物。通过热环化，这种线性聚合物化合物可以转化为具有优异特性的另一种聚合物化合物。
• Multilayer printed circuit board and production thereof
  申请人：Hitachi, Ltd.

  公开号：US05352762A1

  公开（公告）日：1994-10-04

  A multilayer printed circuit board comprising a plurality of alternately laminated layers of insulating layers and circuit conductor layers having a signal transmission delay time of 6.0 ns/m or less, excellent in heat resistance, adhesive, fire retardance, etc. can be produced by forming insulating layers using a fluorine-containing thermosetting resin composition.

  一种多层印刷电路板，包括多个交替层压的绝缘层和电路导体层，其信号传输延迟时间为6.0纳秒/米或以下，具有优异的耐热性、粘附性、阻燃性等，可以通过使用含氟热固性树脂组成的绝缘层来制造。
• Fluorine-containing polymerizable monomer and polymer compound using same
  申请人：Saegusa Hiroshi

  公开号：US20090023886A1

  公开（公告）日：2009-01-22

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula [1], a represents an integer of 1-4.) By having a plurality of polymerizable amines in a molecule while containing a hexafluoroisopropyl group, this fluorine-containing polymerizable monomer exhibiting water repellancy, oil repellency, low water absorbency, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties, and the like, and thus can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示：[1]（在化学式[1]中，a代表1-4的整数）。该含氟可聚合单体分子中含有多个可聚合胺基，并含有六氟异丙基基团，因此具有耐水性、耐油性、低吸水性、耐热性、耐候性、耐腐蚀性、透明度、光敏性、低折射率、低介电性等特性，可应用于高级聚合物材料领域。
• Fluorine-Containing Polymerizable Monomer and Polymer Compound Using Same
  申请人：Saegusa Hiroshi

  公开号：US20080234460A1

  公开（公告）日：2008-09-25

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula, A represents a single bond, an oxygen atom, a sulfur atom, CO, CH 2 , SO, SO 2 , C(CH 3 ) 2 , NHCO, C(CF 3 ) 2 , a phenyl or an alicyclic ring; a and b independently represent an integer of 0-2; and 1≦a+b≦4.) Such a fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer exhibiting water repellency, oil repellency, low water absorbency, heat re-sistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties and the like. Consequently, the fluorine-containing polymeriz-able monomer can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示[1]。（在公式中，A代表单键，氧原子，硫原子，CO，CH2，SO，SO2，C（CH3）2，NHCO，C（CF3）2，苯基或脂环烷基; a和b分别表示0-2的整数; 1≦a+b≦4。）这种含氟可聚合单体可以用作有效的可聚合单体，表现出耐水性，耐油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明度，光敏性，低折射率，低介电性等特性。因此，这种含氟可聚合单体可以应用于先进聚合材料领域。
• Fluorinated Diamine and Polymer Formed Therefrom
  申请人：Narizuka Satoru

  公开号：US20100029895A1

  公开（公告）日：2010-02-04

  There is provided a fluorine-containing diamine represented by formula (1). In this formula, R 1 represents a condensed polycyclic type aromatic hydrocarbon group, and at least one —C(CF 3 ) 2 OH group and at least one —NH 2 group are in a relation such that they are attached to adjacent carbons of carbon atoms constituting the condensed polycyclic type aromatic hydrocarbon group. Polymer compounds derived from this fluorine-containing diamine have superior low dielectric property and low water-absorbing property, and, in addition to that, shows low thermal expansion property and high glass transition temperature.

  提供一种由公式（1）表示的含氟二胺。在此公式中，R1表示一种紧凑的多环芳香族碳氢化合物基团，并且至少一个-C（CF3）2OH基团和至少一个-NH2基团处于这样一种关系，即它们附着在构成紧凑的多环芳香族碳氢化合物基团的相邻碳原子上。从这种含氟二胺衍生的聚合物化合物具有优异的低介电性能和低吸水性能，此外，还表现出低热膨胀性能和高玻璃转移温度。