N,N'-bis(2-methylphenyl)-1,4-dithiooxamide | 663611-33-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(2-methylphenyl)-1,4-dithiooxamide
• 英文别名: N,N'-di-o-tolyl-dithiooxalamide；N,N'-Di-o-tolyl-dithiooxalamid；1.2-Dithio-oxalsaeure-di-o-toluidid；N~1~,N~2~-Bis(2-methylphenyl)ethanebis(thioamide)；N,N'-bis(2-methylphenyl)ethanedithioamide
• CAS: 663611-33-4
• 化学式: C₁₆H₁₆N₂S₂
• 分子量: 300.448
• InChiKey: OUAYJOOBTIZBMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  88.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2-methylphenyl)-1,4-dithiooxamide 、 1,2-二溴乙烷 在 potassium carbonate 作用下， 以 二甲基亚砜 为溶剂， 反应 4.0h， 生成 2,3-bis(2-methylphenylimino)-1,4-dithiacyclohexane
  参考文献：
  名称：

  2,3-Bis(2-methylphenylimino)-1,4-dithiacyclohexane

  摘要：

  一种 N,N′-二取代二硫代草酰氨衍生物与 1,2-二溴乙烷反应生成了标题化合物 C18H18N2S2，这是一种带有双席夫碱的杂环。在晶体结构中，标题化合物的分子位于双倍轴上。弱 C-H...π 相互作用是主要的分子间作用力，促成了平行于 ab 平面的层的形成。每个分子作为供体和受体参与了两个这样的接触。

  DOI：

  10.1107/s0108270103021000
• 作为产物：
  描述：

  N,N',N''-Tris-(2-methyl-phenyl)-α-amino-acetamidin 在 sulfur 作用下， 生成 N,N'-bis(2-methylphenyl)-1,4-dithiooxamide
  参考文献：
  名称：

  The Paradox of Participation and the Hidden Role of Information: A Case Study

  摘要：

  This article examines the complex and often indirect role of participation and information in an integrated planning context. The case study is based in a diverse urban-rural estuarine setting where an integrated resource management program was established to help manage environmental and economic planning issues. The results of the research suggest that the use of participation by those not in government as a measure of success in achieving program objectives must be approached with caution-and research resourcefulness-in order to form an accurate image of impact: and origin. The work supports the idea in planning theory that information has a transformative function that can alter perceptions and mindsets in advance of a decision phase, and affects planning systems at all stages. Dichotomies in opinion of program success and performance may be linked to information access. Consensus building among government agencies and nongovernmental organizations also requires broad access to information. The research indicates that participation by proxy can also be a significant: source of influence.

  DOI：

  10.1080/01944360008976123

文献信息

• The Paradox of Participation and the Hidden Role of Information: A Case Study
  作者：Kevin S. Hanna

  DOI：10.1080/01944360008976123

  日期：2000.12.31

  This article examines the complex and often indirect role of participation and information in an integrated planning context. The case study is based in a diverse urban-rural estuarine setting where an integrated resource management program was established to help manage environmental and economic planning issues. The results of the research suggest that the use of participation by those not in government as a measure of success in achieving program objectives must be approached with caution-and research resourcefulness-in order to form an accurate image of impact: and origin. The work supports the idea in planning theory that information has a transformative function that can alter perceptions and mindsets in advance of a decision phase, and affects planning systems at all stages. Dichotomies in opinion of program success and performance may be linked to information access. Consensus building among government agencies and nongovernmental organizations also requires broad access to information. The research indicates that participation by proxy can also be a significant: source of influence.
• 2,3-Bis(2-methylphenylimino)-1,4-dithiacyclohexane
  作者：Yi-Zhi Li、Wei-Wei Liu、Yan-Jie Li、Guo-Jun Pan、Hong-Wen Hu

  DOI：10.1107/s0108270103021000

  日期：2003.11.1

  An N,N′-disubstituted dithiooxamide derivative reacts with 1,2-dibromoethane to produce the title compound, C₁₈H₁₈N₂S₂, a heterocycle with a double Schiff base. In the crystal structure, the molecule of the title compound lies on a twofold axis. Weak C—H...π interactions are the principal intermolecular forces, mediating the formation of layers parallel to the ab plane. Each molecule participates as donor and acceptor in two such contacts.

  一种 N,N′-二取代二硫代草酰氨衍生物与 1,2-二溴乙烷反应生成了标题化合物 C18H18N2S2，这是一种带有双席夫碱的杂环。在晶体结构中，标题化合物的分子位于双倍轴上。弱 C-H...π 相互作用是主要的分子间作用力，促成了平行于 ab 平面的层的形成。每个分子作为供体和受体参与了两个这样的接触。