dodecyl 2-(methoxycarbonyl)phenyl disulfide | 101309-92-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dodecyl 2-(methoxycarbonyl)phenyl disulfide
• 英文别名: methyl 2-(dodecyldithio)benzoate；methyl 2-(1-dodecyldithio)benzoate；Methyl 2-(dodecyldisulfanyl)benzoate；methyl 2-(dodecyldisulfanyl)benzoate
• CAS: 101309-92-6
• 化学式: C₂₀H₃₂O₂S₂
• 分子量: 368.605
• InChiKey: VYVSBNXUMGMHJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  24
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  76.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  n-dodecanesulfenyl chloride 生成 dodecyl 2-(methoxycarbonyl)phenyl disulfide
  参考文献：
  名称：

  Modena; Pavanetto; Montanari, Farmaco, Edizione Scientifica, 1985, vol. 40, # 11, p. 803 - 807

  摘要：

  DOI：

文献信息

• N -Trifluoroacetyl arenesulfenamides, effective precursors for synthesis of unsymmetrical disulfides and sulfenamides
  作者：Ming Bao、Masao Shimizu

  DOI：10.1016/j.tet.2003.09.080

  日期：2003.11

  unsymmetrical disulfides (4) and sulfenamides (5). Reactions of 3 with a variety of aromatic thiols at room temperature were generally complete within 5 min and gave unsymmetrical diaryl disulfides in high yields. Aralkyl disulfides were isolated in high yields from the reaction of 3 with aliphatic thiols. The nucleophilic substitution reactions of 3 with amines proceeded smoothly and provided N-substituted

  N-三氟乙酰基芳烃亚磺酰胺（3）是合成不对称二硫化物（4）和亚磺酰胺（5）的有效前体。的反应3与多种在室温下芳族硫醇的是在5分钟内完成通常和以高收率得到二芳基不对称二硫化物。从3与脂族硫醇的反应中高收率分离出芳烷基二硫化物。3与胺的亲核取代反应进展顺利，并以良好至极好的收率提供了N-取代的次磺酰胺。
• Reactions of N-sulfenyl-1,2-benzisothiazolin-3-ones with nucleophiles
  作者：Ming Bao、Masao Shimizu、Shigeru Shimada、Jun'ichi Inoue、Takeo Konakahara

  DOI：10.1016/j.tet.2004.09.093

  日期：2004.12

  Reactions of N-[2-(alkoxycarbonyl)benzenesulfenyl]-1,2-benzisothiazolin-3-ones (1) with various nucleophiles were examined. Anions of active methylene compounds attacked the sulfur atoms of the suffenyl moieties of I to afford sulfide compounds, while thiols attacked the sulfur atoms of the benzisothiazolinone moieties of 1 to afford ring-opened products. Grignard reagents attacked both the above sulfur atoms to give ring-opened products along with sulfide compounds. (C) 2004 Published by Elsevier Ltd.
• Modena; Pavanetto; Montanari, Farmaco, Edizione Scientifica, 1985, vol. 40, # 11, p. 803 - 807
  作者：Modena、Pavanetto、Montanari、Mazza、Conti

  DOI：——

  日期：——