N,N-二甲基十七烷-1-胺 | 3002-57-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N-二甲基十七烷-1-胺
• 中文别名: (3S,4R,6S)-4-乙炔基-1,3-二甲基-6-苯基哌啶-3,4-二醇
• 英文名称: N, N-dimethylheptadecan-1-amine
• 英文别名: N,N-dimethaneylheptadecanamine；N,N-dimethyl-1-heptadecanamine；N,N-dimethyl-n-heptadecylamine；dimethylmono-n-heptadecylamine；N,N-dimethylheptadecanamine；N,N-dimethylheptadecylamine；heptadecanyldimethylamine；Dimethylheptadecylamine；heptadecyldimethylamine；1-Heptadecanamine, N,N-dimethyl-；N,N-dimethylheptadecan-1-amine
• CAS: 3002-57-1
• 化学式: C₁₉H₄₁N
• 分子量: 283.541
• InChiKey: WCVHUIPWSPEOIG-UHFFFAOYSA-N

物化性质

• 沸点：
  326.08°C (estimate)
• 密度：
  0.7830 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2921199090

反应信息

• 作为反应物：
  描述：

  氯乙酸甲酯 、 N,N-二甲基十七烷-1-胺 生成 heptadecyl-(2-methoxy-2-oxoethyl)-dimethylazanium;chloride
  参考文献：
  名称：

  EHPSHTEJN A. E.; LIMANOV V. E.; TELEGIN M. YU.; SKVORTSOVA E. K.; MAKSIMO+, XIM.-FARMATS. ZH., 1980, HO 5, 23-26

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲胺 、 1-溴十七烷 生成 N,N-二甲基十七烷-1-胺
  参考文献：
  名称：

  EHPSHTEJN A. E.; LIMANOV V. E.; TELEGIN M. YU.; SKVORTSOVA E. K.; MAKSIMO+, XIM.-FARMATS. ZH., 1980, HO 5, 23-26

  摘要：

  DOI：

文献信息

• USE OF NITROGEN COMPOUNDS QUATERNISED WITH ALKYLENE OXIDE AND HYDROCARBYL-SUBSTITUTED POLYCARBOXYLIC ACID AS ADDITIVES IN FUELS AND LUBRICANTS
  申请人：BASF SE

  公开号：US20160130514A1

  公开（公告）日：2016-05-12

  The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.

  该发明涉及将季铵化氮化合物用作燃料和润滑剂添加剂或煤油添加剂，特别是作为清洁剂添加剂，用于减少或预防直喷柴油发动机的喷射系统中的沉积物，在特定是在共轨喷射系统中，用于降低直喷柴油发动机的燃料消耗，特别是具有共轨喷射系统的柴油发动机，并用于减少直喷柴油发动机的功率损失，特别是在具有共轨喷射系统的柴油发动机中；该发明还涉及将其用作汽油添加剂，特别是用于DISI发动机的运行。
• Methylformate as replacement of syngas in one-pot catalytic synthesis of amines from olefins
  作者：Eduard Karakhanov、Anton Maksimov、Yulia Kardasheva、Elena Runova、Roman Zakharov、Maria Terenina、Corey Kenneally、Victor Arredondo

  DOI：10.1039/c3cy00862b

  日期：——

  general approach for the one-pot hydroaminomethylation of olefins using methylformate as formylating agent instead of synthesis gas (syngas) has been proposed. Herein we report that a Ru–Rh catalytic system demonstrates high activity in a tandem conversion of a series of n-alkenes into amines using methylformate with yields 58–92% (6 h). The selectivity for the normal amine reached 96% with catalysis by

  已经提出了一种新的通用方法，该方法使用甲酸酯甲酯作为甲酰化剂代替合成气（合成气）进行一锅法烯烃的氢氨基甲基化。本文中，我们报道Ru-Rh催化体系在使用甲酸甲酯的一系列正构烯烃串联转化为胺中表现出高活性，产率为58-92％（6小时）。在Ru羰基络合物Ru 3（CO）12的催化下，对正胺的选择性达到96％，在这种情况下，相对于胺，总产率为55％。在Ru催化体系中添加Rh络合物，可显着提高末端和内部烯烃的氢氨甲基化率，并将胺的收率提高至82-93％（6-12小时）。
• QUATERNARY AMMONIUM SALT-CONTAINING CATALYST FOR DISSOCIATION OF BLOCKING AGENT AND USE THEREOF
  申请人：TOSOH CORPORATION

  公开号：US20150344727A1

  公开（公告）日：2015-12-03

  A catalyst containing a quaternary ammonium salt represented by the following general formula (1) is used as a catalyst for dissociation of a blocking agent. [In the formula, each of R 1 to R 3 represents an aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group having 6 to 14 carbon atoms; R 4 represents an aliphatic hydrocarbon group having 9 to 20 carbon atoms; X represents at least one member selected from the group consisting of a phosphate group, a borate group, a hydrogencarbonate group, a monoalkylcarbonate group and a carbonate group; a is an integer in the range of 1 to 3; and b is an integer in the range of 1 to 3.]

  一种催化剂包含一个由以下通用公式（1）表示的季铵盐，用作分解阻塞剂的催化剂。【在公式中，R1至R3中的每一个代表具有1至8个碳原子的脂肪烃基或具有6至14个碳原子的芳香烃基；R4代表具有9至20个碳原子的脂肪烃基；X代表选择自磷酸盐、硼酸盐、碳酸氢盐、单烷基碳酸盐和碳酸盐组成的至少一种成员；a是在1到3范围内的整数；b是在1到3范围内的整数。】
• Novel polystyrene anion exchange polymers
  申请人：Smith Kline & French Laboratories Limited

  公开号：US04954339A1

  公开（公告）日：1990-09-04

  Polystyrene polymers having a quaternized ammonium group and their use in a method of treatment of hypercholesterolaemia. A particular compound of the invention is N,N-dimethyl-N-dodecylammoniomethyl-substituted polystyrene.

  聚苯乙烯聚合物具有季铵基团及其在治疗高胆固醇血症的方法中的应用。该发明的特定化合物是N,N-二甲基-N-十二烷基氨甲基取代的聚苯乙烯。
• Catalyst composition for production of rigid polyurethane foam and isocyanurate-modified rigid polysurethane foam and raw-material composition containing the same
  申请人：Tokumoto Katsuml

  公开号：US20070112085A1

  公开（公告）日：2007-05-17

  An object of the present invention is to provide a catalyst for producing a rigid polyurethane foam and an isocyanurate-modified rigid polyurethane foam excellent in storage stability in the case that water is contained as a blowing agent, and a raw material-blended composition using the same. In the present invention, a catalyst composition comprising the following amine compounds of (A) and (B) and/or (C) is used and further, a raw material-blended composition further containing a polyol component and water is used. (A) A quaternary ammonium salt represented by the following general formula (1): wherein each of R 1 to R 3 represents a hydrocarbon group having 1 to 12 carbon atoms, R 4 represents an alkyl group or an aromatic hydrocarbon group having 1 to 18 carbon atoms, and X represents an organic acid group having an acid dissociation constant (pKa) of 4.8 or less; (B) A hydrophobic amine compound; (C) A heterocyclic tertiary amine compound.

  本发明的目的是提供一种催化剂，用于生产含水为发泡剂的刚性聚氨酯泡沫和异氰酸酯改性的刚性聚氨酯泡沫，并具有良好的储存稳定性，以及使用相同的原料混合组合物。在本发明中，使用以下胺化合物（A）和（B）和/或（C）组成的催化剂组合物，并且还使用进一步包含聚醇组分和水的原料混合组合物。(A) 由以下通式（1）表示的季铵盐：其中，R1至R3分别表示具有1至12个碳原子的碳氢基团，R4表示具有1至18个碳原子的烷基基团或芳香族碳氢基团，X表示具有酸解离常数（pKa）小于4.8的有机酸基团；(B) 疏水胺化合物；(C) 杂环三级胺化合物。