bis(phosphoranylidene)ammonium tetrakis(4-chlorophenyl)borate | 154793-62-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(phosphoranylidene)ammonium tetrakis(4-chlorophenyl)borate
• 英文别名: bis(triphenylphosphoranylidene)ammonium tetrakis(4-chlorophenyl)borate；BTPPATPBCl；Bis(triphenylphosphoranylidene) ammonium tetrakis(4-chlorophenyl)borate；bis(triphenyl-λ5-phosphanylidene)azanium;tetrakis(4-chlorophenyl)boranuide
• CAS: 154793-62-1
• 化学式: C₂₄H₁₆BCl₄*C₃₆H₃₀NP₂
• 分子量: 995.602
• InChiKey: HUUVQJXIGSLOQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.09
• 重原子数：
  68
• 可旋转键数：
  10
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  双(三苯基正膦基)氯化铵 、 四双(4-氯苯基)硼酸钾 生成 bis(phosphoranylidene)ammonium tetrakis(4-chlorophenyl)borate
  参考文献：
  名称：

  Coordination Chemistry of 2,5,8-Trithia[9],(2,9)-1,10-phenanthrolinophane (L) toward Rhodium(III) at the Polarised Water/1,2-Dichloroethane Interface − A Possible New Approach to the Problem of Separating RhIII from Chloride Media

  摘要：

  DOI：

  10.1002/1099-0682(200207)2002:7<1816::aid-ejic1816>3.0.co;2-y
• 作为试剂：
  描述：

  在 bis(phosphoranylidene)ammonium tetrakis(4-chlorophenyl)borate 、 lithium chloride 作用下， 以 水 、 1,2-二氯乙烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and electrochemical properties of a novel calix[4]arene derivative for facilitated transfer of alkali metal ions across water/1,2-dichloroethane micro-interface

  摘要：

  The alkali metal ion transfers facilitated by a novel calix[4]arene derivative (OPEC) across the water/1,2-dichloroethane (1,2-DCE) micro-interface supported at the tip of a micropipette were presented. The well-defined voltammetric behaviours except Cs+ was obtained by cyclic voltammetry and differential pulse voltammetry. The bulk concentration of metal ions was much higher than that of OPEC in the performed measurements. The diffusion coefficient of OPEC in the 1,2-DCE phase was calculated as 5.18 +/- 0.70 x 10(-6) cm(2) s(-1). On the basis of the changes of the half-wave transfer potentials, the logarithms of the association constants having 1:1 ionophore-ion complex stoichiometry for Li+, Na+, K+ and Rb+ in 1,2-DCE were determined as 4.80, 4.62, 4.98 and 5.32, respectively. The facilitated ion transfers were also evaluated by the Randles equivalent circuit used for ac-impedance data analysis.

  DOI：

  10.1080/10610278.2011.575466

文献信息

• Coordination Chemistry of 2,5,8-Trithia[9],(2,9)-1,10-phenanthrolinophane (L) toward Rhodium(III) at the Polarised Water/1,2-Dichloroethane Interface − A Possible New Approach to the Problem of Separating RhIII from Chloride Media
  作者：Alexander J. Blake、M. Helena M. Caçote、Francesco A. Devillanova、Alessandra Garau、Francesco Isaia、Vito Lippolis、Carlos M. Pereira、Fernando Silva、Lorenzo Tei

  DOI：10.1002/1099-0682(200207)2002:7<1816::aid-ejic1816>3.0.co;2-y

  日期：2002.7