(E)-β-styryl butyrate | 73902-32-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-β-styryl butyrate
• 英文别名: [(E)-2-phenylethenyl] butanoate
• CAS: 73902-32-6
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: QVWPIWRIPFNGGS-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (E)-(2-phenylethenyl)mercury chloride 、 mercury(II) butyrate 在 palladium diacetate 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 以47%的产率得到(E)-β-styryl butyrate
  参考文献：
  名称：

  Mercury in organic chemistry. 17. A convenient stereospecific synthesis of enol esters from vinylmercurials

  摘要：

  DOI：

  10.1021/ja00526a035

文献信息

• Synthesis and structure of some ruthenium–rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene
  作者：Suming Ye、Weng Kee Leong

  DOI：10.1016/j.jorganchem.2005.11.061

  日期：2006.3

  Cp*(CO)Ru(μ-H)[μ-PhP(C6H4)CH2PPh2]Re(CO)3, was also obtained from the first reaction. All these heterodinuclear products have been characterised crystallographically. They also showed good catalytic activity for the addition of carboxylic acids to phenylacetylene to afford the anti-Markovnikov products selectively.

  Na [Re（CO）5 ]与Cp * Ru（dppm）Cl，CpRu（dppm）Cl或CpRu（CO）2 Cl的盐消除反应得到异核物质Cp * Ru（μ-CO）2（μ- dppm）Re（CO）3，Cp（CO）Ru（μ-dppm）Re（CO）4或Cp（CO）2 RuRe（CO）5的产率中等。正金属化物种Cp *（CO）Ru（μ-H）[μ-PhP（C 6 H 4）CH 2 PPh 2 ] Re（CO）3也从第一反应获得。所有这些异双核产物均已通过晶体学表征。他们还显示出良好的催化活性，可以将羧酸加到苯乙炔中，从而选择性地提供抗马尔科夫尼科夫产物。
• A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene
  作者：Kwong-Chak Cheung、Wing-Leung Wong、Ming-Him So、Zhong-Yuan Zhou、Siu-Cheong Yan、Kwok-Yin Wong

  DOI：10.1039/c2cc38454j

  日期：——

  A dinuclear ruthenium catalyst with a rigid anthracene spacer shows excellent regio- and stereo-selectivity in the atom-economic addition of aliphatic carboxylic acids to phenylacetylene, producing exclusively anti-Markovnikov enol-esters with high E/Z ratios of the isomers.

  在脂肪族羧酸与苯乙炔的原子经济加成反应中，一种带有刚性蒽间隔的二核钌催化剂显示出极佳的区域和立体选择性，可生成具有高 E/Z 异构体比的完全反马尔科夫尼科夫烯醇酯。
• POSITIVE PHOTOSENSITIVE RESIN COMPOSITION AND METHOD OF FORMING CURED FILM FROM THE SAME
  申请人：FUJIFILM Corporation

  公开号：EP2261737A1

  公开（公告）日：2010-12-15

  A positive photosensitive resin composition comprising a resin containing a specified acrylic acid besed-structural unit which generates a carboxyl group when its dissociative group is dissociated, which resin is insoluble in alkali or sparingly soluble in alkali but when its acid-dissociative group is dissociated, becomes soluble in alkali, a resin containing a structural unit derived from a radical-polymerizable monomer containing an epoxy group, a compound containing two or more epoxy groups in its molecule, provided that the resin containing the structural unit derived from a radical-polymerizable monomer containing an epoxy group is not included in this compound, and a compound that when exposed to actinic rays of 300 nm or longer wavelength, generates an acid, and a method of forming cured film from the positive photosensitive resin composition.

  一种正性感光树脂组合物，包括一种含有特定丙烯酸旁链结构单元的树脂，当其离解基离解时会产生一个羧基，该树脂不溶于碱或很少溶于碱，但当其酸离解基离解时会溶于碱；一种含有从含有环氧基的可自由基聚合单体衍生的结构单元的树脂、在其分子中含有两个或两个以上环氧基团的化合物，但该化合物中不包括含有由含有环氧基团的可自由基聚合单体衍生的结构单元的树脂，以及当暴露于波长为 300 nm 或更长的辐射线时会产生酸的化合物，以及用正性感光树脂组合物形成固化薄膜的方法。
• Regio- and stereoselective addition of carboxylic acids to phenylacetylene catalyzed by cyclopentadienyl ruthenium complexes
  作者：Suming Ye、Weng Kee Leong

  DOI：10.1016/j.jorganchem.2005.11.023

  日期：2006.3

  The direct addition of carboxylic acids to terminal alkynes Such as phenylacetylene in the presence of catalytic amount of [CpRu(CO)(2)CI] (1) or [CpRu(CO)(2)}(2)] (2) affords the anti-Markovnikov adducts with high selectivity. In most instances, the E-enol esters are the major products. (c) 2005 Elsevier B.V. All rights reserved.
• LAROCK R. C.; OERTLE K.; BEATTY K. M., J. AMER. CHEM. SOC., 1980, 102, NO 6, 1966-1974
  作者：LAROCK R. C.、 OERTLE K.、 BEATTY K. M.

  DOI：——

  日期：——