N.N-Diisopropyl-thioformamid | 29528-44-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硫代羧酸及其衍生物
• 英文名称: N.N-Diisopropyl-thioformamid
• 英文别名: N,N-diisopropylthioformamide；N,N-di(propan-2-yl)methanethioamide
• CAS: 29528-44-7
• 化学式: C₇H₁₅NS
• 分子量: 145.269
• InChiKey: VQIOTRKAHJOMFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  35.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N.N-Diisopropyl-thioformamid 在 吡啶 、 二氯化硫 作用下， 以 二氯甲烷 为溶剂， 生成 N,N-Diisopropyl-thio-carbamidsaeurechlorid
  参考文献：
  名称：

  Hasserodt,U., Chemische Berichte, 1968, vol. 101, p. 113 - 120

  摘要：

  DOI：
• 作为产物：
  描述：

  (chloromethylene)diisopropylammonium chloride 在 双(三甲基硫化硅) 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 N.N-Diisopropyl-thioformamid
  参考文献：
  名称：

  Conversion of amides and lactams to thioamides and thiolactams using hexamethyldisilathiane

  摘要：

  Amides and lactams were converted to their corresponding thioamides and thiolactams employing a new protocol using hexamethyldisilathiane (TMS(2)S). Oxophilic promoters were employed to generate Vilsmeier-type intermediates, the most efficient reagents being phosphorus oxychloride, triphosgene, and oxalyl chloride. Thionation of intermediate chloro iminium ions was accomplished in situ with TMS(2)S. Yields were good to excellent for secondary and tertiary amides and lactams while yields for primary systems were poor.

  DOI：

  10.1021/jo00081a011

文献信息

• Heteroaroyl-Substituted Serine Amides
  申请人：Witschel Matthias

  公开号：US20100099568A1

  公开（公告）日：2010-04-22

  The present invention relates to heteroaroyl-substituted serinamides of the formula (I) in which the variables A and R 1 to R 6 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

  本发明涉及异芳酰基取代的丝氨酰胺的化学式(I)，其中变量A和R1至R6如描述中所定义，并涉及它们在农业上有用的盐，用于它们的制备过程和中间体，以及利用这些化合物或包含这些化合物的组合物来控制不受欢迎的植物。
• PYRAZOLE-3-CARBOXYLIC ACID AMIDE DERIVATIVE AND PEST CONTROL AGENT
  申请人：KUMIAI CHEMICAL INDUSTRY CO., LTD.

  公开号：US20200199096A1

  公开（公告）日：2020-06-25

  Embodiments provide a harmful organism control agent containing a pyrazole-3-carboxylic acid amide derivative or a salt thereof as an active ingredient, having an excellent harmful organism controlling effect. A pyrazole-3-carboxylic acid amide derivative represented by general formula [I]: (wherein, R 1 , R 2 , R 3 , R 4 , and R 5 represent a hydrogen atom, halogen atom, C 1 -C 6 alkyl group or the like, R 6 represents a C 1 -C 12 alkyl group, C 1 -C 12 haloalkyl group or the like, R 7 and R 8 represent a hydrogen atom, C 1 -C 12 alkyl group or the like) or an agriculturally acceptable salt thereof, and a harmful organism control agent containing the pyrazole-3-carboxylic acid amide derivative or an agriculturally acceptable salt thereof as an active ingredient.

  实施例提供了一种含有吡唑-3-羧酸酰胺衍生物或其盐作为活性成分的有害生物控制剂，具有出色的有害生物控制效果。一种由通式[I]表示的吡唑-3-羧酸酰胺衍生物：（其中，R1、R2、R3、R4和R5代表氢原子、卤原子、C1-C6烷基或类似物，R6代表C1-C12烷基、C1-C12卤代烷基或类似物，R7和R8代表氢原子、C1-C12烷基或类似物）或其农业可接受的盐，以及一种含有吡唑-3-羧酸酰胺衍生物或其农业可接受的盐作为活性成分的有害生物控制剂。
• Benzoyl-substituted phenylalanineamides
  申请人：Witschel Matthias

  公开号：US20070142230A1

  公开（公告）日：2007-06-21

  The present invention relates to benzoyl-substituted phenylalanineamides of the formula I in which the variables R 1 to R 15 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

  本发明涉及式I的苯甲酰基取代苯丙氨酰胺，其中变量R1到R15如描述中所定义，以及它们在农业上有用的盐，用于它们的制备的过程和中间体，以及这些化合物或含有这些化合物的组合物用于控制不受欢迎的植物。
• Heteroaroyl-Substituted Alanines with a Herbicidal Action
  申请人：Witschel Matthias

  公开号：US20090186766A1

  公开（公告）日：2009-07-23

  The present invention relates to heteroaroyl-substituted alanines of the formula I in which the variables A and R 1 to R 8 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

  本发明涉及公式I的杂环芳基取代的丙氨酸，其中变量A和R1至R8如描述中定义，并涉及它们的农业有用盐，用于其制备的过程和中间体，以及这些化合物或包含这些化合物的组合物用于控制不受欢迎的植物。
• Heteroaroyl-substituted phenylalanineamides
  申请人：Witschel Matthias

  公开号：US20070060480A1

  公开（公告）日：2007-03-15

  Pyrazolylcarbonyl-substituted phenylalanineamides of the formula I in which the variables A and R 1 to R 10 are as defined in the description, and their agriculturally useful salts, processes and intermediates for their preparation; and the use of these compounds or of compositions comprising these compounds for controlling unwanted plants are described.

  公式I中的吡唑基羰基取代的苯丙氨酰胺，其中变量A和R1到R10如描述中所定义，以及它们的农业有用盐、制备它们的过程和中间体；以及描述了这些化合物或含有这些化合物的组合物用于控制不受欢迎的植物。

表征谱图