N-nitro-N'-(2-nitro-benzylidenamino)-guanidine | 5347-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-nitro-N'-(2-nitro-benzylidenamino)-guanidine
• 英文别名: N-Nitro-N'-(2-nitro-benzylidenamino)-guanidin；2-nitro-1-[(E)-(2-nitrophenyl)methylideneamino]guanidine
• CAS: 5347-98-8
• 化学式: C₈H₈N₆O₄
• 分子量: 252.189
• InChiKey: BZOIYLYLHFBJGR-BJMVGYQFSA-N

物化性质

• 沸点：
  428.7±47.0 °C(Predicted)
• 密度：
  1.63±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  154
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  邻硝基苯甲醛 、 1-氨基-3-硝基胍 生成 N-nitro-N'-(2-nitro-benzylidenamino)-guanidine
  参考文献：
  名称：

  Kumler; Sah, Journal of the American Pharmaceutical Association (1912), 1952, vol. 41, p. 375

  摘要：

  DOI：

文献信息

• HYDROCARBYLIDENE NITROHYDROZINECARBOXIMIDAMIDES AND A METHOD FOR MAKING THE SAME, AS WELL AS THEIR USES AS AN INSECTICIDE
  申请人：Qin ZhaoHai

  公开号：US20110306639A1

  公开（公告）日：2011-12-15

  The present invention discloses hydrocarbylidene nitrohydrozinecarboximidamides and the use thereof as well as a method for making the same. The structural general formula of the compounds are shown in formula I, wherein, R1 is C1-C10 saturated and/or unsaturated aliphatic hydrocarbonyl, benzyl, substituted benzyl, halogenated picolyl, halogenated thiazolyl methyl, tetrahydrofuryl methyl or oxazolyl methyl; R2 is hydrogen, C1-C5 saturated and/or unsaturated aliphatic hydrocarbonyl, phenyl, substituted phenyl, pyridyl or substituted pyridyl; R3 is hydrogen, C1-C10 saturated and/or unsaturated aliphatic hydrocarbonyl, furyl, phenyl, substituted phenyl, benzyl or substituted benzyl. The tests of insecticidal activity show that the hydrocarbylidene nitrohydrozinecarboximidamides shown by formula (I) have high preventive efficiency against insect pests of plants, such as aphid, plant hopper, cotton bollworm, asparagus caterpillar, and the like, and can be used as plant insecticides.

  本发明公开了羟基甲烷基亚硝基羟肼羧酰胺及其用途，以及制备该化合物的方法。所述化合物的结构通式如式I所示，其中，R1为C1-C10饱和和/或不饱和脂肪烃基、苄基、取代苄基、卤代吡啶基、卤代噻唑基甲基、四氢呋喃基甲基或噁唑基甲基；R2为氢、C1-C5饱和和/或不饱和脂肪烃基、苯基、取代苯基、吡啶基或取代吡啶基；R3为氢、C1-C10饱和和/或不饱和脂肪烃基、呋喃基、苯基、取代苯基、苄基或取代苄基。杀虫活性测试显示，式(I)所示的羟基甲烷基亚硝基羟肼羧酰胺对植物害虫（如蚜虫、植食性跳蚤、棉铃虫、天冬毛虫等）具有很高的预防效果，并可用作植物杀虫剂。
• CONDENSED AMINO NITROGUANIDINE COMPOUNDS, SYNTHESIS AND USE AS BOTANICAL INSECTICIDES THEREOF
  申请人：Qin, ZhaoHai

  公开号：EP2216324A1

  公开（公告）日：2010-08-11

  The present invention discloses hydrocarbylidene nitrohydrozinecarboximidamides and the use thereof as well as a method for making the same. The structural general formula of the compounds are shown in formula I, wherein, R1 is C1 - C10 saturated and/or unsaturated aliphatic hydrocarbonyl, benzyl, substituted benzyl, halogenated picolyl, halogenated thiazolyl methyl, tetrahydrofuryl methyl or oxazolyl methyl; R2 is hydrogen, C1 - C5 saturated and/or unsaturated aliphatic hydrocarbonyl, phenyl, substituted phenyl, pyridyl or substituted pyridyl; R3 is hydrogen, C1 - C10 saturated and/or unsaturated aliphatic hydrocarbonyl, furyl, phenyl, substituted phenyl, benzyl or substituted benzyl. The tests of insecticidal activity show that the hydrocarbylidene nitrohydrozinecarboximidamides shown by formula (I) have high preventive efficiency against insect pests of plants, such as aphid, plant hopper, cotton bollworm, asparagus caterpillar, and the like, and can be used as plant insecticides.

  本发明公开了亚烃基硝基氢嗪脒及其用途以及制造方法。化合物的结构通式如式 I 所示，其中，R1 是 C1 - C10 饱和和/或不饱和脂肪烃基、苄基、取代苄基、卤代吡啶基、卤代噻唑基甲基、四氢糠基甲基或噁唑基甲基；R2 是氢、C1-C5 饱和和/或不饱和脂肪烃基、苯基、取代苯基、吡啶基或取代吡啶基； R3 是氢、C1-C10 饱和和/或不饱和脂肪烃基、呋喃基、苯基、取代苯基、苄基或取代苄基。杀虫活性测试表明，式（I）所示的亚烃基硝基羟嗪甲脒对植物害虫，如蚜虫、植物跳虫、棉铃虫、芦笋毛虫等具有很高的预防效率，可用作植物杀虫剂。
• Condensed amino nitroguanidine compounds, synthesis and use as botanical insecticides thereof
  申请人：Qin, ZhaoHai

  公开号：EP2216324B1

  公开（公告）日：2013-03-13