N,N-bisglycidyl-m-toluidine | 38051-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bisglycidyl-m-toluidine
• 英文别名: 3-methyl-N,N-bis(oxiran-2-ylmethyl)aniline
• CAS: 38051-04-6
• 化学式: C₁₃H₁₇NO₂
• 分子量: 219.283
• InChiKey: RCSBZARYQGKGAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  28.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-甲基苯胺 、 环氧氯丙烷 在 环氧乙烷 、 盐酸 作用下， 生成 N,N-bisglycidyl-m-toluidine
  参考文献：
  名称：

  Tertiary amines, a process for their preparation and their use as

  摘要：

  本发明涉及从双酚，双环氧化物和芳香族二级胺衍生的新型三级胺，以及它们的制备过程和作为乙烯基不饱和冷固丙烯酸和聚酯树脂硬化促进剂的用途。

  公开号：

  US05684202A1

文献信息

• EPOXY RESIN COMPOSITION, FIBER-REINFORCED COMPOSITE MATERIAL AND METHOD FOR PRODUCING THE SAME
  申请人：Toray Industries, Inc.

  公开号：EP2256163A1

  公开（公告）日：2010-12-01

  Disclosed herein are an epoxy resin composition for fiber-reinforced composite materials which has low viscosity, high Tg, high elastic modulus, and excellent fracture toughness and a fiber-reinforced composite material using such an epoxy resin composition which has excellent thermal properties, compressive strength, impact resistance, fatigue resistance, and open-hole tensile strength and which is suitable for producing structural parts of aircraft and the like. The epoxy resin composition comprises at least a given bifunctional epoxy resin as a component (A), a liquid aromatic diamine curing agent as a component (B), and core-shell polymer particles as a component (C), wherein the core-shell polymer particles as the component (C) contain epoxy groups in their shell and have a volume-average particle size of 50 to 300 nm.

  本文公开了一种用于纤维增强复合材料的环氧树脂组合物，该组合物具有低粘度、高 Tg、高弹性模量和优异的断裂韧性；还公开了一种使用这种环氧树脂组合物的纤维增强复合材料，该材料具有优异的热性能、抗压强度、抗冲击性能、抗疲劳性能和开孔拉伸强度，适用于生产飞机等的结构部件。该环氧树脂组合物至少包括作为组分（A）的给定双官能环氧树脂、作为组分（B）的液态芳香族二胺固化剂和作为组分（C）的芯壳聚合物颗粒，其中作为组分（C）的芯壳聚合物颗粒在其外壳中含有环氧基团，其体积平均粒径为 50 至 300 纳米。
• EPOXY RESIN COMPOSITION, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP3702389A1

  公开（公告）日：2020-09-02

  The purpose of the present invention is to provide an epoxy resin composition which has excellent viscosity stability, and when cured, can provide a resin cured product which has high flame retardancy and excellent mechanical properties, and a prepreg and fiber-reinforced composite material using the epoxy resin composition. An embodiment of the epoxy resin composition according to the present invention which achieves the purpose contains all components [A]-[C]. [A]: A reactive diluent having a specific structure and a viscosity of 2 Pa·s or less at 25°C. [B]: An epoxy resin having three of more functional groups. [C]: An amine-based curing agent having a specific structure.

  本发明的目的是提供一种环氧树脂组合物，该组合物具有优异的粘度稳定性，固化时可提供具有高阻燃性和优异机械性能的树脂固化产品，以及使用该环氧树脂组合物的预浸料和纤维增强复合材料。根据本发明，实现上述目的的环氧树脂组合物的一个实施方案包含所有组分[A]-[C]。[A]:具有特定结构的活性稀释剂，25°C 时粘度为 2 Pa-s 或更低。[B]:具有三个或三个以上官能团的环氧树脂。[C]:具有特定结构的胺基固化剂。
• EPOXY RESIN COMPOSITION, PREPREG AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP4105257A1

  公开（公告）日：2022-12-21

  The purpose of the present invention is to provide: an epoxy resin composition which enables the achievement of a resin cured product that has high flame retardancy and excellent mechanical characteristics; and a prepreg and a fiber-reinforced composite material, each of which uses this epoxy resin composition. One embodiment of the epoxy resin composition according to the present invention, said epoxy resin composition having achieved the above-described purpose, contains the components (A) and (B) described below. (A): a bifunctional glycidyl amine type epoxy compound (B): an epoxy compound having a specific structure and/or an epoxy compound having another specific structure

  本发明的目的是提供：一种环氧树脂组合物，该组合物能够获得具有高阻燃性和优异机械特性的树脂固化产品；以及一种预浸料和一种纤维增强复合材料，每种预浸料和复合材料都使用这种环氧树脂组合物。根据本发明的环氧树脂组合物的一个实施例（所述环氧树脂组合物已达到上述目的）包含下述组分（A）和（B）。(A): 双官能缩水甘油胺型环氧化合物 (B): 具有特定结构的环氧化合物和/或具有另一种特定结构的环氧化合物
• Umsetzungsprodukte aus Anilinen und Bisphenolbisglycidylethern, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Härtungsbeschleuniger
  申请人：BAYER AG

  公开号：EP0701997B1

  公开（公告）日：2000-02-16
• EPOXY RESIN COMPOSITION, FIBER-REINFORCED COMPOSITE MATERIAL, AND METHOD FOR PRODUCING THE SAME
  申请人：Kamae Toshiya

  公开号：US20110097568A1

  公开（公告）日：2011-04-28

  Disclosed herein are an epoxy resin composition for fiber-reinforced composite materials which has low viscosity, high Tg, high elastic modulus, and excellent fracture toughness and a fiber-reinforced composite material using such an epoxy resin composition which has excellent thermal properties, compressive strength, impact resistance, fatigue resistance, and open-hole tensile strength and which is suitable for producing structural parts of aircraft and the like. The epoxy resin composition comprises at least a given bifunctional epoxy resin as a component (A), a liquid aromatic diamine curing agent as a component (B), and core-shell polymer particles as a component (C), wherein the core-shell polymer particles as the component (C) contain epoxy groups in their shell and have a volume-average particle size of 50 to 300 nm.