N-[(2,4-dihydroxyphenyl)methylideneamino]-2-hydroxy-2,2-diphenylacetamide | 201541-69-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[(2,4-dihydroxyphenyl)methylideneamino]-2-hydroxy-2,2-diphenylacetamide
• CAS: 201541-69-7
• 化学式: C₂₁H₁₈N₂O₄
• 分子量: 362.385
• InChiKey: CUWYSMUJCLQTJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  102
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N-[(2,4-dihydroxyphenyl)methylideneamino]-2-hydroxy-2,2-diphenylacetamide 、 水 、 copper diacetate 以 乙醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF NEW Cu(II) COMPLEXES DERIVED FROM BENZILIC AND MANDELIC HYDRAZONES

  摘要：

  Two new sets of Cu(II) complexes with newly synthesised benzilic and mandelic hydrazone derivatives were prepared in the mole ratios 1:1 and 1:2 (Cu:L). The structure of the complexes was identified on the basis of the data obtained from elemental and thermal analyses as well as IR, UV-visible, ESR spectra, and X-ray diffraction. The results indicate that the ligands are tightly bound to the metal ion through the phenolic OH oxygen, the azomethine nitrogen, and the enolic OH oxygen in case of the 1:1 complexes while for the 1:2 complexes the enolic OH group did not participate in bonding. The complexes have elongated octahedral as well as square-planar symmetries.[GRAPHICS]

  DOI：

  10.1081/sim-100001935

文献信息

• SYNTHESIS AND CHARACTERIZATION OF NEW Cu(II) COMPLEXES DERIVED FROM BENZILIC AND MANDELIC HYDRAZONES
  作者：R. M. Issa、S. A. Abdel-Latif、H. A. Abdel-Salam

  DOI：10.1081/sim-100001935

  日期：2001.3.29

  Two new sets of Cu(II) complexes with newly synthesised benzilic and mandelic hydrazone derivatives were prepared in the mole ratios 1:1 and 1:2 (Cu:L). The structure of the complexes was identified on the basis of the data obtained from elemental and thermal analyses as well as IR, UV-visible, ESR spectra, and X-ray diffraction. The results indicate that the ligands are tightly bound to the metal ion through the phenolic OH oxygen, the azomethine nitrogen, and the enolic OH oxygen in case of the 1:1 complexes while for the 1:2 complexes the enolic OH group did not participate in bonding. The complexes have elongated octahedral as well as square-planar symmetries.[GRAPHICS]