2-[2-[4-(1,3-Dipyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-2-yl)phenyl]-3-pyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-1-yl]pyridine | 1279090-39-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-[2-[4-(1,3-Dipyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-2-yl)phenyl]-3-pyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-1-yl]pyridine
• 英文别名: 2-[2-[4-(1,3-dipyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-2-yl)phenyl]-3-pyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-1-yl]pyridine
• CAS: 1279090-39-9
• 化学式: C₄₂H₃₆N₄P₂
• 分子量: 658.722
• InChiKey: ABQWJKSNGSYODM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  48
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 2-[2-[4-(1,3-Dipyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-2-yl)phenyl]-3-pyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-1-yl]pyridine 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Folding of a Supramolecular Framework Based on a Tetrametallic Clip Driven by π−π Interactions

  摘要：

  Supramolecular extended frameworks based on a rotational molecular clip and having the same "primary structure" can exhibit either an unfolded or a folded framework. This process is driven by intramolecular pi-pi interactions, resulting in the formation of an infinite pi-stacked column within the folded supramolecular framework

  DOI：

  10.1021/ic200268c
• 作为产物：
  描述：

  1,4-双(二氯化磷)苯 、 1,8-bis(2-pyridyl)octa-1,7-diyne 在 正丁基锂 、 二氯二茂锆 作用下， 以51%的产率得到2-[2-[4-(1,3-Dipyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-2-yl)phenyl]-3-pyridin-2-yl-4,5,6,7-tetrahydroisophosphindol-1-yl]pyridine
  参考文献：
  名称：

  Folding of a Supramolecular Framework Based on a Tetrametallic Clip Driven by π−π Interactions

  摘要：

  Supramolecular extended frameworks based on a rotational molecular clip and having the same "primary structure" can exhibit either an unfolded or a folded framework. This process is driven by intramolecular pi-pi interactions, resulting in the formation of an infinite pi-stacked column within the folded supramolecular framework

  DOI：

  10.1021/ic200268c

文献信息

• Folding of a Supramolecular Framework Based on a Tetrametallic Clip Driven by π−π Interactions
  作者：Tomohiro Agou、Manuel Sébastian、Christophe Lescop、Régis Réau

  DOI：10.1021/ic200268c

  日期：2011.4.18

  Supramolecular extended frameworks based on a rotational molecular clip and having the same "primary structure" can exhibit either an unfolded or a folded framework. This process is driven by intramolecular pi-pi interactions, resulting in the formation of an infinite pi-stacked column within the folded supramolecular framework