p-terphenyl-2'-carbonitrile | 860225-69-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-terphenyl-2'-carbonitrile
• 英文别名: 2,5-Diphenylbenzonitrile
• CAS: 860225-69-0
• 化学式: C₁₉H₁₃N
• 分子量: 255.319
• InChiKey: QZGGOOOBNFHABE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-terphenyl-2'-carbonitrile 在 氢氧化钾 、 乙二醇 作用下， 生成 2,5-diphenylbenzoic acid
  参考文献：
  名称：

  693.环己烷-1：3-二酮。第二部分 取代的对-三联苯的新合成

  摘要：

  DOI：

  10.1039/jr9570003480
• 作为产物：
  描述：

  2,5-二苯基环己酮 在 氢氧化钾 、 硫酸 、 乙酸酐 作用下， 生成 p-terphenyl-2'-carbonitrile
  参考文献：
  名称：

  693.环己烷-1：3-二酮。第二部分 取代的对-三联苯的新合成

  摘要：

  DOI：

  10.1039/jr9570003480

文献信息

• Metal-Free Generation of γ-Cyanoalkyl Radicals by N-Heterocyclic Carbene Catalysis: Assembly of 6-Cyanoalkyl Phenanthridines
  作者：Qianrong Li、Cong-Ying Zhou、Chengming Wang

  DOI：10.1021/acs.orglett.2c03808

  日期：2022.12.23

  number of γ-cyanoalkyl radicals were generated by sustainable N-heterocyclic carbene catalysis in tin-, transition-meal-, and light-free conditions, followed by insertion into biaryl isonitriles, thus leading to the rapid assembly of a variety of diversely functionalized 6-cyanoalkyl phenanthridines. A preliminary mechanism study revealed that a single-electron transfer radical process was possibly involved

  在无锡​​、过渡餐和无光条件下，通过可持续的 N-杂环卡宾催化产生了许多 γ-氰基烷基自由基，然后插入到联芳基异腈中，从而导致各种不同功能化的快速组装6-氰基烷基菲啶。初步的机理研究表明，可能涉及单电子转移自由基过程。
• Pleochroic dyes suitable for use in solution with liquid crystal materials for electro-optic device applications
  申请人：BDH Chemicals Limited

  公开号：EP0002104A1

  公开（公告）日：1979-05-30

  A liquid crystal material includes in solution therewith a pleochroic dye characterised in that the dye is an anthraquinone of general formula: where R2 is either hydrogen or a hydroxyl group and where R3 is an anilino or substituted or modified anilino group and where R, is hydrogen when R2 is a hydroxyl group and R, is an anilino or substituted or modified anilino group, preferably the same as R3, when R2 is hydrogen. A large number of alternatives for R3 are disclosed.

  一种液晶材料包括一种多色染料，其特征在于该染料是通式如下的蒽醌 其中 R2 是氢或羟基，R3 是苯胺基或经取代或修饰的苯胺基，当 R2 是羟基时，R 是氢，当 R2 是氢时，R 是苯胺基或经取代或修饰的苯胺基，最好与 R3 相同。已公开了大量 R3 的替代物。
• Organic compositions suitable for guest-host liquid crystal device
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0049036A1

  公开（公告）日：1982-04-07

  A material suitable for a guest-host liquid crystal device comprises a solution of a liquid crystal material and a pleochroic dye wherein the pleochroic dye comprises at least one compound having a formula: wherein one of X and Y is OH and the other is NHR wherein R is H or lower alkyl; each of R1 and R2 independently represents alkyl, aryl, aralkyl, alkoxy or -NR3R4 wherein each of R3 and R4 is independently H or lower alkyl, provided that R2 is always adjacent to an OH group.

  一种适用于客主液晶装置的材料包括液晶材料和褶染染料的溶液，其中褶染染料包括至少一种具有以下式子的化合物： 其中 X 和 Y 中的一个是 OH，另一个是 NHR，其中 R 是 H 或低级烷基；R1 和 R2 中的每一个独立地代表烷基、芳基、芳烷基、烷氧基或-NR3R4，其中 R3 和 R4 中的每一个独立地代表 H 或低级烷基，条件是 R2 始终与 OH 基团相邻。
• Liquid crystal materials comprising pleochroic dyes
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0059095A1

  公开（公告）日：1982-09-01

  A material suitable for a guest-host liquid crystal device comprises a solution of a liquid crystal material and a pleochroic dye where in the pleochroic dye comprises at least one anthraquinone compound free from water solubilising and ionic substituents and having the formula: wherein Q is NH2, OH, alkyl, aryl, N02 or halo; n is 0 to 4; each X independently is H, -SR, -NZ1Z2 or Q; each R independently is alkyl, aryl or cycloalkyl; Z1 & Z2 are independently H, alkyl, cycloalkyl or aryl; provided that there are at least two groups X which are different -SR groups.

  一种适用于客主液晶装置的材料包括液晶材料和褶染染料的溶液，其中褶染染料包括至少一种不含水溶性和离子取代基的蒽醌化合物，其式为： 其中 Q 是 NH2、OH、烷基、芳基、N02 或卤代；n 是 0 至 4；每个 X 独立地是 H、-SR、-NZ1Z2 或 Q；每个 R 独立地是烷基、芳基或环烷基；Z1 和 Z2 独立地是 H、烷基、环烷基或芳基；条件是至少有两个基团 X 是不同的-SR 基团。
• Dielectric materials
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0091226A2

  公开（公告）日：1983-10-12

  A material suitable for a guest-host liquid crystal device comprises a solution of a liquid crystal material and a pleochroic dye characterised in that the dye comprises at least one anthraquinone compound free from water-solubilising and ionic substituents and having the formula: wherein each of R and R' independently represents an n-alkyl group having from 4 to 7 carbon atoms inclusive and wherein each of R2 and R3 is independently selected from hydrogen and alkyl groups having from 1 to 4 carbon atoms inclusive.

  一种适用于客-主液晶装置的材料，包括液晶材料和多色染料的溶液，其特征在于染料包括至少一种不含水溶解性和离子取代基的蒽醌化合物，并具有以下式子：其中 R 和 R' 各自独立地代表一个具有 4 至 7 个碳原子的正烷基，R2 和 R3 各自独立地选自氢和具有 1 至 4 个碳原子的烷基。