N-(3,5-二氯-4-羟基苯基)苯磺酰胺 | 51767-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-(3,5-二氯-4-羟基苯基)苯磺酰胺
• 中文别名: O-[{[(2R)-2-(丁基桥氧基)-3-(丙基桥氧基)丙基]氧代}(羟基)磷基]-L-丝氨酸
• 英文名称: N-(3,5-dichloro-4-hydroxyphenyl)benzenesulfonamide
• 英文别名: 2,6-Dichlor-4-benzolsulfonamidophenol；4-Phenylsulfonyl-2,6-dichloraminophenol；benzenesulfonic acid-(3,5-dichloro-4-hydroxy-anilide)；4-Benzolsulfonylamino-2,6-dichlor-phenol；Benzolsulfonsaeure-(3,5-dichlor-4-hydroxy-anilid)；Benzenesulfonamide, N-(3,5-dichloro-4-hydroxyphenyl)-
• CAS: 51767-45-4
• 化学式: C₁₂H₉Cl₂NO₃S
• 分子量: 318.18
• InChiKey: KFPBEVFQCXRYIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.8
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2935009090

反应信息

• 作为反应物：
  描述：

  N-(3,5-二氯-4-羟基苯基)苯磺酰胺 在 lead(IV) acetate 作用下， 生成 2,6-dichloro-4-phenylsulfonylimino-1,4-benzoquinone
  参考文献：
  名称：

  Quinone Imides. IV. p-Quinone Monosulfonimides

  摘要：

  DOI：

  10.1021/ja01147a078
• 作为产物：
  描述：

  2,6-dichloro-4-phenylsulfonylimino-1,4-benzoquinone 在 二氢吡啶 作用下， 以 氯仿 为溶剂， 生成 N-(3,5-二氯-4-羟基苯基)苯磺酰胺
  参考文献：
  名称：

  Gustinya, D. V.; Markava, E. Ya.; Freimanis, Ya. F., Journal of general chemistry of the USSR, 1990, vol. 60, # 2.1, p. 246 - 251

  摘要：

  DOI：

文献信息

• Iron(III)‐Mediated Nucleophilic Halogenation of Phenols Using an Amido Directing Group
  作者：Ye Yuan、Dou Guo、Yibo Liu、Congcong Wan、Dongbiao Lu、Hongxiang Yang、Yufan Lu、Wei Meng、Hongling Wang、Xiang Zhang

  DOI：10.1002/ejoc.202200387

  日期：2022.5.6

  An amido-directing regioselective and nucleophilic halogenation reaction of electron-rich amidophenols was realized in the presence of Fe(III) reagents. Halides could be sequentially introduced to specific positions to form mono-, di- and mixed di- halogenated amidophenols mostly in one-pot manner.

  在 Fe(III) 试剂的存在下，实现了富电子氨基酚的酰胺定向区域选择性和亲核卤化反应。卤化物可以依次引入特定位置以形成单卤代、二卤代和混合二卤代氨基酚，主要以一锅法的方式进行。
• Immunochromatography kit
  申请人：Oyamada Takayoshi

  公开号：US20080166821A1

  公开（公告）日：2008-07-10

  An immunochromatography kit including organic silver salt particles, a reducing agent for silver ions, and a metal colloid label or a metal sulfide label. The immunochromatography kit uses an immunoreaction of an analyte and an antibody or antigen that can bind specifically thereto, and analyzes a signal from a label derived from an immune complex.

  一种免疫层析试剂盒，包括有机银盐颗粒、还原剂以还原银离子、以及金属胶体标记或金属硫化物标记。该免疫层析试剂盒使用分析物和能够特异性结合其的抗体或抗原之间的免疫反应，并分析源自免疫复合物的标记信号。
• Post-processing stabilizers for photothermographic articles
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0622666A1

  公开（公告）日：1994-11-02

  Post-processing stabilizers for photothermographic, silver imaging media are disclosed. The stabilizers are represented by the following general formulae: wherein: R¹, R², and R³ are independently H, halogen, an alkyl group, an alkoxy group, a thioalkyl group, a cycloalkyl group, a perhalogenated alkyl group, or taken together form a cycloaliphatic group. Compounds of formula (I) may be used as stabilizer precursors in photothermographic silver imaging media to provide post-processing stability without significantly adversely affecting desired properties of the photothermographic material.

  本发明揭示了用于光热成像的银成像介质的后处理稳定剂。这些稳定剂由以下一般式表示：其中：R¹，R²和R³独立地为H，卤素，烷基，烷氧基，硫代烷基，环烷基，全卤代烷基，或一起形成环脂肪族基。式（I）的化合物可用作光热成像银成像介质中的稳定剂前体，以在不显着不利影响光热成像材料所需特性的情况下提供后处理稳定性。
• Aqueous dispersion of fatty acid silver salt particles, method for redispersing fatty acid silver salt particles, photothermographic light-sensitive material, and method for producing the same
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0962812A1

  公开（公告）日：1999-12-08

  Fatty acid silver salt particles of an aqueous dispersion thereof which are formed by simultaneously adding into a reaction vessel (a) a silver ion-containing aqueous solution or a silver ion-containing water-organic solvent mixed solution and (b) an aqueous solution of an alkali metal salt of a fatty acid, a solution thereof in a water-organic solvent mixed solvent or a solution thereof in an organic solvent, in an amount of at least 10% of the total amount of silver to be added, and the fatty acid silver salt particles formed satisfies all the following characteristics: (1) The average equivalent-sphere diameter of the fatty acid silver salt particles is from 0.1 µm to 0.8 µm; (2) The average ratio of long sides/short sides in main planes of the fatty acid silver salt particles is from 1 to 4; (3) The average aspect ratio of the particle is from 2 to 30; and (4) The average thickness of the particles is from 0.01 µm to 0.20 µm.

  通过同时加入（a）含有银离子的水溶液或含有银离子的水-有机溶剂混合物和（b）脂肪酸的碱金属盐的水溶液，它在水-有机溶剂混合溶剂中的溶液或有机溶剂中的溶液，其添加量至少为要添加的总银量的10％，形成的水分散脂肪酸银盐颗粒，且满足以下所有特征：（1）脂肪酸银盐颗粒的平均等效球直径为0.1微米至0.8微米；（2）脂肪酸银盐颗粒主平面长边/短边的平均比率为1至4；（3）颗粒的平均纵横比为2至30；（4）颗粒的平均厚度为0.01微米至0.20微米。
• A method of forming an image, and an imaging element for inhibiting image formation with cobalt (III) complexes
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0003263A1

  公开（公告）日：1979-08-08

  An imaging element contains an energy-activatable image precursor composition comprising a cobalt III complex having releasable ligands which react with an image forming material to form a visible image. The element also contains a photoinhibitor which, on activating exposure, inhibits the release of ligands from the cobalt III complex or inhibits their image forming action. Images may be formed by imagewise activating the photoinhibitor, preferably with radiation longer than 300 nm, and thereafter activating the image precursor composition, for instance by heating. Images of a different sense may be formed by varying the exposure and activation treatments of the element.

  一种成像元件包含一种能量可激活的成像前体组合物，该组合物由钴 III 复合物组成，该钴 III 复合物具有可释放的配体，这些配体与成像材料反应形成可见图像。 该元件还包含一种光抑制剂，该光抑制剂在激活曝光时可抑制配体从钴 III 复合物中释放或抑制其成像作用。 可以通过成像激活光抑制剂（最好使用长于 300 纳米的辐射），然后激活成像前体组合物（例如通过加热）来形成图像。 可以通过改变元件的曝光和激活处理来形成不同意义的图像。