N,N-di(propanoic acid)-4-aminobiphenyl | 241492-11-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-di(propanoic acid)-4-aminobiphenyl
• 英文别名: 3-[4-[4-(2-carboxyethyl)-N-(4-phenylphenyl)anilino]phenyl]propanoic acid
• CAS: 241492-11-5
• 化学式: C₃₀H₂₇NO₄
• 分子量: 465.549
• InChiKey: FLYAHHRZEYMCRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  35
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  77.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N,N-di(propanoic acid)-4-aminobiphenyl 在 potassium isopropoxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.5h， 以100%的产率得到N,N-[3-carboxypropyl phenyl]-4-aminobiphenyl dipotassium salt
  参考文献：
  名称：

  Process for arylamine production

  摘要：

  提供了一种合成丙烯酰胺化合物的过程。该过程包括通过将二羧酸芳胺与烷基盐反应以产生二羧酸芳胺盐来产生芳胺分子的二羧酸盐。

  公开号：

  US20060222977A1
• 作为产物：
  描述：

  N,N-bis(4-(2-(methoxycarbonyl)ethyl)phenyl)-biphenyl-4-amine 在 sodium hydroxide 、 乙二醇 、 盐酸 作用下， 以 水 为溶剂， 反应 5.0h， 以98%的产率得到N,N-di(propanoic acid)-4-aminobiphenyl
  参考文献：
  名称：

  Process for arylamine production

  摘要：

  通过提供碘代有机化合物来形成4-氨基联苯衍生物芳胺化合物；用羧酸基取代碘代有机化合物以提供酯保护基；进行乌尔曼缩合反应将步骤（ii）的产物转化为芳胺化合物；并进行铃木偶联反应，在与氮相对的4位上向芳胺化合物中添加额外的苯基。

  公开号：

  US20060111582A1

文献信息

• Process for arylamine production
  申请人：Goodbrand Bruce H.

  公开号：US20060111582A1

  公开（公告）日：2006-05-25

  4-aminobiphenyl derivative arylamine compounds are formed by providing an iodinated organic compound; substituting the iodinated organic compound at carboxylic acid groups thereof to provide ester protecting groups; conducting an Ullman condensation reaction to convert the product of step (ii) into an arylamine compound; and conducting a Suzuki coupling reaction to add an additional phenyl group to the arylamine compound in the 4-position relative to the nitrogen.

  通过提供碘代有机化合物来形成4-氨基联苯衍生物芳胺化合物；用羧酸基取代碘代有机化合物以提供酯保护基；进行乌尔曼缩合反应将步骤（ii）的产物转化为芳胺化合物；并进行铃木偶联反应，在与氮相对的4位上向芳胺化合物中添加额外的苯基。
• ARYLAMINE PROCESSES
  申请人：Saban Marko D.

  公开号：US20080076049A1

  公开（公告）日：2008-03-27

  Continuous and batch processes for selectively hydrogenating double and/or triple bonds in organic molecules include providing at least one organic molecule containing a double and/or triple bond, providing at least one hydrogen donor molecule, and hydrogenating the double and/or triple bond in the presence of at least one catalyst. Continuous and batch processes for preparing arylamine molecules include selectively hydrogenating double bonds in arylamine compounds by providing at least one organic molecule containing a multiple bond, providing at least one hydrogen donor molecule, and hydrogenating the multiple bond in the presence of at least one catalyst. The continuous and batch processes provide efficient, cost-effective and safe methods for conducting selective hydrogenation reactions in the synthesis of organic molecules, such as charge-transport molecules.

  连续和分批工艺可用于有机分子中选择性加氢双键和/或三键，包括提供至少一种含有双键和/或三键的有机分子，提供至少一种氢供体分子，并在至少一种催化剂的存在下加氢双键和/或三键。 连续和分批工艺可用于制备芳基胺分子，包括通过提供至少一种含有多重键的有机分子，提供至少一种氢供体分子，并在至少一种催化剂的存在下选择性加氢芳基胺化合物中的双键。 连续和分批工艺提供了在有机分子的合成中进行选择性加氢反应的高效，经济和安全的方法，例如用于电荷输运分子的合成。
• METHOD FOR FORMING REACTIVE SILANE ESTERS
  申请人：Coggan A. Jennifer

  公开号：US20070238847A1

  公开（公告）日：2007-10-11

  Methods are provided for preparing reactive silane ester compounds, such as aromatic reactive silane ester compounds. The methods include providing a carboxylic acid-containing starting material, reacting the carboxylic acid-containing starting material with a base to form a salt, and reacting the salt with a halo-alkylene-silane to form a reactive silane ester compound. Compositions prepared by these methods, protective layers that include hydrolysis and condensation products of such compositions, electrophotographic photoreceptors that include such protective layers, and image forming apparatus that include such electrophotographic photoreceptors are also provided.
• NOVEL REACTIVE COMPOUND, CHARGE TRANSPORTING FILM, PHOTOELECTRIC CONVERSION DEVICE, ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND METHOD OF PRODUCING THE SAME, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
  申请人：SASAKI Tomoya

  公开号：US20130052573A1

  公开（公告）日：2013-02-28

  Provided is a reactive compound represented by the following General Formula (I): wherein in General Formula (I), F represents a charge transporting skeleton, D represents a group represented by the following General Formula (III), and m represents an integer of from 1 to 8: wherein in General Formula (III), L1 represents a divalent linking group including one or more —C(═O)—O— groups.
• US7262314B2
  申请人：——

  公开号：US7262314B2

  公开（公告）日：2007-08-28