3-Allyl-2-chloro-pyridine | 134040-00-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3-Allyl-2-chloro-pyridine
• 英文别名: 2-Chloro-3-prop-2-enylpyridine
• CAS: 134040-00-9
• 化学式: C₈H₈ClN
• mdl: MFCD18802471
• 分子量: 153.611
• InChiKey: UHNMIWZQTJRUKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.125
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-氯吡啶 、 丙烯酰碘 在 正丁基锂 、 碘苯 、 二异丙胺 作用下， 生成 3-Allyl-2-chloro-pyridine
  参考文献：
  名称：

  Le phényl-lithium: nouvel agent de métallation du cycle pyridinique

  摘要：

  Nucleophilic addition was the sole reaction of phenyl-lithium with a pyridinic ring; now the novel catalysed metallation, with phenyl-lithium, of many substituted pyridine compounds giving various derivatives in high yields with many different reagents, has been achieved

  DOI：

  10.1016/0022-328x(91)83170-9

文献信息

• Preparation of Highly Functionalized Pyridylmagnesium Reagents for the Synthesis of Polyfunctional Pyridines
  作者：Laurent Bérillon、Anne Leprêtre、Alain Turck、Nelly Plé、Guy Quéguiner、Gérard Cahiez、Paul Knochel

  DOI：10.1055/s-1998-17871

  日期：1998.12

  Functionalized iodopyridines bearing either a chloride, ester or nitrile function were converted to the corresponding organomagnesium derivatives at -40 °C or -78 °C by treatment with i-PrMgBr (1.1 equiv, 0.5 h, > 90% yield). The resulting functionalized Grignard reagents react with aldehydes, TosCN directly or with allylic bromides and benzoyl chloride after transmetalation with CuCN leading to polyfunctional pyridines.

  功能化的碘吡啶，带有氯、酯或腈基，通过与i-PrMgBr（1.1当量，0.5小时，> 90%产率）反应，在-40°C或-78°C下转换为相应的有机镁衍生物。所得到的功能化格氏试剂与醛、TosCN直接反应，或在与CuCN进行跨金属反应后，与烯丙基溴化物和苯甲酰氯反应，从而生成多官能团吡啶。
• Aqueous coating composition and floor polishing composition
  申请人：JSR Corporation

  公开号：EP1253173A2

  公开（公告）日：2002-10-30

  An aqueous coating composition useful as a floor polishing agent is disclosed. The composition comprises (A) an aqueous dispersion of a copolymer obtained by the emulsion polymerization of (a) an ethylenically unsaturated carboxylic acid monomer, (b) a (meth)acrylic acid alkyl ester monomer, and (c) other monomers polymerizable with the monomers (a) and (b), (B) an unsaturated monomer curable with energy rays, and (C) a photoinitiator. The floor polishing agent containing the aqueous coating composition exhibits excellent delamination properties and dry buff applicability.

  本发明公开了一种可用作地板抛光剂的水性涂料组合物。该组合物包括：(A) 由以下单体乳液聚合而成的共聚物的水性分散体：(a) 乙烯基不饱和羧酸单体；(b) (甲基)丙烯酸烷基酯单体；(c) 可与单体(a)和(b)聚合的其他单体；(B) 可用能量射线固化的不饱和单体；(C) 光引发剂。含有该水性涂料组合物的地板抛光剂具有优异的分层性能和干磨适用性。
• Reaction product of aqueous copolymer emulsion and polyvalent metal compound and polishing composition containing same
  申请人：JSR Corporation

  公开号：EP1396507A1

  公开（公告）日：2004-03-10

  A reaction product of (I) an aqueous emulsion of a copolymer of (a) 5-50 wt% of an ethylenically unsaturated carboxylic acid monomer and/or the salt thereof, (b) 0.05-20 wt% of ethylenically unsaturated sulfonic acid monomer and/or the salt thereof, and (c) other ethylenically unsaturated monomers polymerizable with the monomers (a) and (b), provided that the total of monomers (a), (b), and (c) is 100 wt%, the copolymer having a Tg from -30°C to +20°C, and (II) a polyvalent metal compound. The reaction product is useful as a floor polish excelling in durability, adhesion to substrates, and recoatability that are well balanced with removability with an alkali, and decreased TVOC due to absence or low content of a low boiling point coalescent agent and plasticizer.

  以下物质的反应产物：(I) 共聚物的水乳液：(a) 5-50 wt%的乙烯基不饱和羧酸单体和/或其盐，(b) 0.05-20重量％的乙烯基不饱和磺酸单体和/或其盐，和(c)可与单体(a)和(b)聚合的其它乙烯基不饱和单体，条件是单体(a)、(b)和(c)的总和为100重量％，共聚物的Tg为-30℃至+20℃，和(II)多价金属化合物。该反应产物可用作地板上光剂，在耐久性、对基材的附着力和重涂性方面表现出色，并能很好地平衡碱的去除性，以及由于不含或少含低沸点凝聚剂和增塑剂而降低的 TVOC。
• EMULSION FOR AQUEOUS INKJET INK
  申请人：JSR Corporation

  公开号：EP1840175A1

  公开（公告）日：2007-10-03

  This invention relates to an aqueous ink jet ink emulsion obtained by emulsion polymerization of (b) an ethylenic unsaturated bond-containing monomer under the presence of (a) a hydrophilic group-, hydrophobic group- and radical reactive group-containing reactive emulsifier, and there is provided an additive (polymer emulsion) having an effect of improving print quality (print density, abrasion resistance and glossiness) of printed matter by adding the emulsion to an aqueous ink.

  本发明涉及一种水性喷墨油墨乳液，它是由含乙烯不饱和键单体（b）在含亲水基团、疏水基团和自由基反应基团的反应性乳化剂（a）存在下进行乳液聚合而得，并提供了一种添加剂（聚合物乳液），通过将该乳液添加到水性油墨中，可提高印刷品的印刷质量（印刷密度、耐磨性和光泽度）。
• AQUEOUS DISPERSION FOR CHEMICAL MECHANICAL POLISHING, CHEMICAL MECHANICAL POLISHING METHOD, AND KIT FOR PREPARING AQUEOUS DISPERSION FOR CHEMICAL MECHANICAL POLISHING
  申请人：JSR Corporation

  公开号：EP1962334A1

  公开（公告）日：2008-08-27

  A chemical mechanical polishing aqueous dispersion includes (A) abrasive grains having a pore volume of 0.14 ml/g or more, and (B) a dispersion medium.

  一种化学机械抛光水性分散液包括 (A) 孔隙度为 0.14 毫升/克或更大的研磨粒和 (B) 一种分散介质。