lithium salt of salicylidene aniline | 50615-94-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: lithium salt of salicylidene aniline
• 英文别名: Lithium 2-phenyliminomethyl phenolate；lithium;2-(phenyliminomethyl)phenolate
• CAS: 50615-94-6
• 化学式: C₁₃H₁₀NO*Li
• 分子量: 203.169
• InChiKey: NADIMWSVJTWZKI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.49
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  亚水杨基苯胺 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 生成 lithium salt of salicylidene aniline
  参考文献：
  名称：

  Bis-Schiff base ligand-containing mono-metallocene olefin polymerization catalyst, its preparation process and application

  摘要：

  具有以下结构式（I）的烯烃聚合催化剂：其中R1选自氢、C1-C12烷基、C1-C12烷氧基或C6-C12芳基，R2和R2'分别选自氢和C1-C4烷基，R3选自氢、C1-C12烷基、C1-C12烷氧基和C6-C12芳基，M选自Ti、Zr和Hf。该催化剂适用于烯烃聚合，可产生高分子量和共聚单体高插入率的聚合物产品。

  公开号：

  US20030096927A1

文献信息

• Electroluminescent device using azomethine-lithium-complex as electron injection layer
  申请人：Kathirgamanathan Poopathy

  公开号：US08883325B2

  公开（公告）日：2014-11-11

  In OLEDs, improved efficiency is obtained by compounds which can form inter alia electron injection layers of the formula (I) wherein R1 is a 1-5 ring aryl (including polycyclic), aralkyl or heteroaryl group which is optionally substituted with one or more C1-C4 alkyl, alkoxy or cyano; R2 and R3 together form a 1-5 ring aryl (including polycyclic), aralkyl or heteroaryl group which is optionally substituted with C1-C4 alkyl, alkoxy or cyano; R4 is hydrogen, C1-C4 alkyl or aryl; and Ar is monocyclic, bicyclic or tricyclic aryl or heteroaryl which is optionally substituted with one or more C1-C4-alkyl or alkoxy groups, or an oligomer thereof.

  在OLED中，通过可以形成电子注入层的化合物（I）来获得改进的效率，其中R1是1-5环芳基（包括多环），芳基烷基或杂芳基基团，可以用一个或多个C1-C4烷基，烷氧基或氰基进行取代；R2和R3共同形成一个1-5环芳基（包括多环），芳基烷基或杂芳基基团，可以用C1-C4烷基，烷氧基或氰基进行取代；R4是氢，C1-C4烷基或芳基；Ar是单环，双环或三环芳基或杂芳基，可以用一个或多个C1-C4烷基或烷氧基进行取代，或其寡聚物。
• ELECTROLUMINESCENT DEVICE USING AZOMETHINE-LITHIUM-COMPLEX AS ELECTRON INJECTION LAYER
  申请人：Merck Patent GmbH

  公开号：US20150065725A1

  公开（公告）日：2015-03-05

  In OLEDs, improved efficiency is obtained by compounds which can form inter alia electron injection layers of the formula (I) wherein R 1 is a 1-5 ring aryl (including polycyclic), aralkyl or heteroaryl group which is optionally substituted with one or more C 1 -C 4 alkyl, alkoxy or cyano; R 2 and R 3 together form a 1-5 ring aryl (including polycyclic), aralkyl or heteroaryl group which is optionally substituted with C 1 -C 4 alkyl, alkoxy or cyano; R 4 is hydrogen, C 1 -C 4 alkyl or aryl; and Ar is monocyclic, bicyclic or tricyclic aryl or heteroaryl which is optionally substituted with one or more C 1 -C 4 -alkyl or alkoxy groups, or an oligomer thereof.

  在OLED中，通过化合物(I)形成可以形成电子注入层的改进效率，其中R1是1-5环芳基（包括多环），芳基烷基或杂环芳基基团，可以选择地用一个或多个C1-C4烷基，烷氧基或氰基取代；R2和R3共同形成1-5环芳基（包括多环），芳基烷基或杂环芳基基团，可以选择地用C1-C4烷基，烷氧基或氰基取代；R4是氢，C1-C4烷基或芳基；Ar是单环、双环或三环芳基或杂环芳基，可以选择地用一个或多个C1-C4烷基或烷氧基取代，或其寡聚物。
• Bis-Schiff base ligand-containing mono-metallocene olefin polymerization catalyst, its preparation process and application
  申请人：——

  公开号：US20030096927A1

  公开（公告）日：2003-05-22

  A catalyst for olefin polymerization having the following structural formula (I): 1 wherein R 1 is selected from the group consisting of hydrogen, C 1 -C 12 alkyl, C 1 -C 12 alkoxy, or C 6 -C 12 aryl, R 2 and R 2 ′ are respectively selected from hydrogen and C 1 -C 4 alkyl, R 3 is selected from the group consisting of hydrogen, C 1 -C 12 alkyl, C 1 -C 12 alkoxy and C 6 -C 12 ary1, and M is selected from Ti, Zr, and Hf The catalyst is suitable for olefin polymerization to yield polymerized products with high molecular weight and high insertion rate of comonomers.

  具有以下结构式（I）的烯烃聚合催化剂：其中R1选自氢、C1-C12烷基、C1-C12烷氧基或C6-C12芳基，R2和R2'分别选自氢和C1-C4烷基，R3选自氢、C1-C12烷基、C1-C12烷氧基和C6-C12芳基，M选自Ti、Zr和Hf。该催化剂适用于烯烃聚合，可产生高分子量和共聚单体高插入率的聚合物产品。