N,N-diallyl-3,5-dimethylaniline | 534619-14-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-diallyl-3,5-dimethylaniline
• 英文别名: 3,5-dimethyl-N,N-bis(prop-2-enyl)aniline
• CAS: 534619-14-2
• 化学式: C₁₄H₁₉N
• 分子量: 201.312
• InChiKey: KFVDWFVRRRGLEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-diallyl-3,5-dimethylaniline 在 naphthalene-1,8-diylbis(diphenylmethylium) diperchlorate 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以81%的产率得到N,N,N',N'-tetraallyl-2,2',6,6'-tetramethylbenzidine
  参考文献：
  名称：

  1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant:  Synthesis of Benzidines via Self-Coupling of N,N-Dialkylanilines

  摘要：

  1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines, in good to excellent yield. The dications were readily prepared from a cyclic ether precursor, derived from 1,8-dibromonaphthalene, via deoxygenation with a silylating reagent in 1,1,1,3,3,3-hexafluoro-2-propanol under anhydrous conditions.

  DOI：

  10.1021/ol048058w
• 作为产物：
  描述：

  丙烯酰碘 、 1-氨基-3,5-二甲苯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 N,N-diallyl-3,5-dimethylaniline
  参考文献：
  名称：

  1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant:  Synthesis of Benzidines via Self-Coupling of N,N-Dialkylanilines

  摘要：

  1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines, in good to excellent yield. The dications were readily prepared from a cyclic ether precursor, derived from 1,8-dibromonaphthalene, via deoxygenation with a silylating reagent in 1,1,1,3,3,3-hexafluoro-2-propanol under anhydrous conditions.

  DOI：

  10.1021/ol048058w

文献信息

• [EN] AMPHIPHILIC AND MESOGENIC ORGANIC DYES FOR TAILOR-MADE REFLECTIVE LOW-DIMENSIONAL MATERIALS<br/>[FR] COLORANTS ORGANIQUES AMPHIPHILES ET MÉSOGÈNES POUR MATÉRIAUX TRIDIMENSIONNELS RÉFLÉCHISSANTS FABRIQUÉS SUR MESURE
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2020008052A1

  公开（公告）日：2020-01-09

  The present invention relates to a compound of the following formula (I): (I). The invention also relates to uses thereof as dye or pigment, notably as a luster pigment. The invention relates also to a reflective or photonic or nanophotonic or optoelectronic device comprising a compound of the invention. The invention relates also to a metal-like reflective coating,a metal-like particle or an organic-based metal-like liquid film comprising a compound of the invention.

  本发明涉及以下式（I）的化合物：（I）。该发明还涉及其作为染料或颜料的用途，特别是作为光泽颜料。该发明还涉及包括本发明化合物的反射性、光子学、纳米光子学或光电子器件。该发明还涉及包括本发明化合物的类金属反射涂层、类金属颗粒或有机基类金属液膜。
• Highly efficient Ru(<scp>ii</scp>)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions
  作者：Mariam Y. Al-Enezi、Elizabeth John、Yehia A. Ibrahim、Nouria A. Al-Awadi

  DOI：10.1039/d1ra07428h

  日期：——

  Three novel phosphine-free Ru-alkylidenes (7a–7c) have been synthesized and utilized as efficient catalysts for ring closing metathesis (RCM) reaction. Spectroscopic data, i.e. NMR and HRMS, along with single crystal X-ray diffraction analysis, were used to confirm their chemical structures. The tosylated carbenoid 7b showed the highest efficiency in cyclizing different acyclic diene substrates. RCM

  已经合成了三种新型的不含膦的 Ru-亚烷基 ( 7a-7c )，并将其用作闭环复分解 (RCM) 反应的有效催化剂。光谱数据，即NMR 和 HRMS，以及单晶 X 射线衍射分析，用于确认它们的化学结构。甲苯磺酰化的类胡萝卜素7b在环化不同的无环二烯底物方面表现出最高的效率。与众所周知的 Grubbs 相比，仅使用催化量 (0.5–2.0 mol%) 的添加剂催化剂 ( 7b ) 就可以很好地耐受各种（未）取代的N、N-二烯丙基苯胺衍生物的 RCM 和不同大分子二烯的立体选择性 RCM (II) 和 Hoveyda-Grubbs (II) 催化剂。
• Direct Use of Allylic Alcohols for Platinum-Catalyzed Monoallylation of Amines
  作者：Masaru Utsunomiya、Yoshiki Miyamoto、Junji Ipposhi、Takashi Ohshima、Kazushi Mashima

  DOI：10.1021/ol071365s

  日期：2007.8.1

  A new direct catalytic amination of allylic alcohols promoted by the combination of platinum and a large bite-angle ligand DPEphos was developed in which the allylic alcohol was effectively converted to a pi-allylplatinum intermediate without the use of an activating reagent. The use of the DPEphos ligand was essential for obtaining high catalyst activity and high monoallylation selectivity of primary

  通过铂和大咬角配体DPEphos的结合促进了新的烯丙基醇的直接催化胺化反应，其中不使用活化剂就将烯丙基醇有效地转化为π-烯丙基铂中间体。DPEphos配体的使用对于获得高催化剂活性和伯胺的高单烯丙基化选择性至关重要，从而可以形成多种单烯丙基化产物，收率良好。
• Mechanistic Investigation of the Cobalt-Catalyzed Selective Conversion of Diallylanilines to Quinolines Involving C−N and C−H Activations
  作者：Ling Li、William D. Jones

  DOI：10.1021/ja070551q

  日期：2007.9.1

  2,3-Substituted quinolines were readily prepared from diallylanilines in good yields under mild conditions by using Co2(CO)(8) as catalyst. Regioselectivity has been explored by examining a series of electron-donating and electron-withdrawing functional groups at ortho, meta, and para positions of the diallylanilines. The results show that both steric and electronic effects influence the isolated yields

  通过使用 Co2(CO)(8) 作为催化剂，在温和的条件下，可以很容易地从二烯丙基苯胺以良好的产率制备 2,3-取代的喹啉。通过检查二烯丙基苯胺的邻位、间位和对位的一系列给电子和吸电子官能团来探索区域选择性。结果表明空间和电子效应都会影响分离的产率。吸电子基团抑制反应。还研究了溶剂效应、温度效应和催化剂负载。设计了同位素标记实验以描绘反应机制。
• Dental Restorative Materials Based on Polymerizable Azides and Alkynes
  申请人：Ivoclar Vivadent AG

  公开号：US20140171536A1

  公开（公告）日：2014-06-19

  The invention relates to a dental restorative material on the basis of at least one compound of Formula I A-[X-Q-(Y-CG) n ] m Formula I, wherein CG represents in each case independently an azide group N 3 or an alkyne group selected from the group consisting of —CR 1 R 2 —C≡CH, with the proviso that the dental restorative material comprises at least one compound of Formula I comprising an azide group and at least one compound of Formula I comprising an alkyne group. The invention also relates to the use of the dental restorative materials according to the invention for preparing dental composites, preferably composite blanks, which are suitable in particular for mechanical processing by means of computer-aided processing techniques such as milling and grinding processes, and which are suitable above all for preparing dental restoration materials such as inlays, onlays, crowns, bridges or veneering materials.

  该发明涉及一种牙科修复材料，其基础是至少一种化合物Formula IA-[X-Q-(Y-CG)n]mFormula I，其中CG在每种情况下独立地表示一个偶氮基团N3或从一组中选择的炔基团，该组由—CR1R2—C≡CH组成，但是牙科修复材料至少包括一种包含偶氮基团的Formula I化合物和一种包含炔基团的Formula I化合物。该发明还涉及根据该发明的牙科修复材料用于制备牙科复合材料，优选为复合坯料，特别适用于通过计算机辅助加工技术（如铣削和磨削工艺）进行机械加工，并且特别适用于制备牙科修复材料，如嵌体、套环、冠、桥梁或贴面材料。